1、药药名名成成分分结结构构式式固固定定相相流流动动相相丁公藤东 莨 菪 内 酯(Scopoletin,C10H8O4)ODS甲醇-水-冰醋酸(32:68:0.16)人参人参皂苷Rg1,Re,Rb1(Ginsenoside,C42H72O14)(Ginsenoside,C48H82O18)(Ginsenoside,C54H92O23)ODS乙氰,水人参叶人参皂苷Rg1,Re(C42H72O14,C48H82O18)ODS乙氰-0.05%磷酸(100:400)儿茶儿茶素,表儿茶素(C15H14O6)ODS0.04mol/l 枸 橼 酸-N,N-二甲基甲酰胺-四氰呋喃(45:8:2三七人参皂苷Rg1,
2、Rb1,三七皂苷R(Notoginsnoside,C42H80O18)ODS乙氰,水土贝母土贝母苷甲(C63H98O29)ODS65%甲醇土荆皮土 荆 皮 乙 酸(Pseudolaricacid,C23H28O8)辛烷基硅烷键合硅胶甲醇-1.0%醋酸溶液(50:50)大青叶靛玉红(C16H10N2O2)ODS甲醇-水(75:25)大黄芦荟大黄素(C15H10O5)大黄酸(C15H8O6)大黄素(C15H10O5)大黄酚(C15H10O4)大黄素甲醚(C16H12O5)ODS甲醇-0.1%磷酸(85:15)大蓟柳 穿 鱼 叶 苷(Pectolinarin,C28H34O15)ODS乙氰-0.1%
3、磷酸(21:79)山茱萸马钱苷(Loganin,C17H26O10)ODS乙氰-水(15:85)山银花绿原酸(C16H18O9)ODS乙氰-0.4%磷酸(12:88)川射干射干苷(C22H24O11)ODS甲醇-0.05mol/l磷酸二氢钾(磷酸调PH3.0,32:68)OHOH3COOHHOOOHOHHOHOOHOOHOHOHOHOHOOOHOHOHHOOHOHOHOHHOHHOOHOHOHOHHOHHHOHHOCH2OHOHOOOHOHCH3CH3CH3H3HCCH3OHOHHOOHOOOOOOHOOHOOHOHOHOHOHOOHOHOHOOOOOOHOOHOHHOHHHHHNHNHOOO
4、OOHOHOHOOOHOHOHOOOHOHOOOHOHOOOOHOHOOHOOOHOHOHOHOHOOHOOOHOHOHOHOHHOOOHOOHOHOOOHOHOHOH3COOHOCH3OOCH3OHOHOHOHOHOHOHOHOOHOHOHOHOOHOHOHOHOHHHOHOHHOOOHOHHOHOOHOOHOHOHOHOHOOOHOHOHHHOCH2OHOHHOCH2OHOHOOOHOHOOHOHOOHOHCH3CH3CH3H3HCCH3OHOHHOOOHOHHHOHOOHOHOHOHOOHOHOHOHOHHHOHO马钱子士的宁(C21H22N2O2)马钱子碱(C23H26N2O4)ODS
5、乙 氰-0.01%mol/l 庚 烷黄酸纳+0.02mol/l磷酸二氢钠(10%磷酸调PH2.8)(21:79)马钱子粉士的宁(C21H22N2O2)马钱子碱(C23H26N2O4)同马钱子ODS乙 氰-0.01%mol/l 庚 烷黄酸纳+0.02mol/l磷酸二氢钠(10%磷酸调PH2.8)(21:79)天山雪莲无水芦丁(C27H30O16),绿原酸(C16H18O9)ODS甲醇-0.4%磷酸(38:62)天麻天麻素(C13H18O7)ODS乙氰-0.05%磷酸(3:97)木香木香烃内酯(Costunolide,C15H20O2),去氢木香内酯(DehydrocostusIactone,C1
6、5H18O2)ODS甲醇-水(65:35)木贼山奈素(C15H10O6)ODS乙氰-0.4%磷酸(50:50)木通齐墩果酸(C30H48O3),常春藤皂苷元(C30H48O4)ODS甲醇-水-冰醋酸-三乙胺(87:13:0.04:0.02)五味子五味子醇甲(C24H32O7)ODS甲醇-水(13:7)五倍子没食子酸(C7H6O5),鞣质ODS甲醇-0.1%磷酸(15:85)瓦松槲皮素(C15H10O7),山奈素(C15H10O6)ODS甲醇-0.5%磷酸(47:53)牛蒡子牛蒡苷(Arctiin,C27H34O11)ODS甲醇-水(1:1.1)升麻异阿魏酸(Isoferulicacid,C10
7、H10O4)ODS乙氰-0.1%磷酸(13:87)化橘红柚 皮 苷(Narengin,C27H32O14)ODS甲醇-醋酸-水(35:4:61)NONOHHHHHNONOHHHHHOOOHOOHOHOHOHOOCH3CH3HHOOOOOHHOOHOHOHOH3CCH3HCOOHH3CCH3HHCH3CH3CH3OCH3H3COH3COH3COOCH3CH3OHCH3H3COCOOHHOOHOHOOHOHOHOOHHOOOHHOOHOHOOOCH2OH2CHOH2COHOHH3COHOH3COHHOH3COOOOOOHOH2CHOOHCH3OHOHOHOHOHOH丹参丹参酮|A(Tanshino
8、ne,C19H18O3)丹酚酸B(C36H30O16)ODS甲醇-水(75:25)/甲醇-乙氰-甲酸-水(30:10:1:59)乌药乌药醚内酯(C15H16O4)ODS乙氰-水(56:44)水飞蓟水飞蓟宾(Silymarin,C25H22O10)ODS甲醇-水-冰醋酸(48:52:1)功劳木盐 酸 小 檗 碱(Berberinehydrochloride,C20H17NO4.HCl)ODS乙氰-0.05mol/l磷酸二氢钾(磷酸调PH3.0)(30:70)甘草甘草酸(Glycyrrhizic,C46H62O16)/甘草苷(Liquiritin.C21H22O9)ODS甲醇-0.2mol/l醋酸
9、胺-冰醋酸(67:33:1)/乙氰-0.5%冰醋酸(1:4)石韦绿原酸(Chlorogenicacid,C16H18O9)ODS乙氰-0.5%磷酸(11:89)龙胆龙胆苦苷(Gentiopicrin,C16H20O9)ODS甲醇-水(3:7)仙茅仙茅苷(C22H26O11)ODS乙氰-0.1%磷酸(21:79)白芍芍药苷(Paeoniflorin,C23H28O11)ODS乙氰-0.1%磷酸(14:86)白芷欧前胡素(Imperatorin,C16H14O4)ODS甲醇-水(55:45)白鲜皮梣 酮(fraxinellone,C12H14O3)ODS甲醇-水(62:38)炒瓜蒌子3,29-二苯
10、甲酰基栝楼仁三醇(C44H58O5)ODS甲醇-水(93:7)冬虫夏草腺苷(Adenosine,C10H13N5O4)ODS0.01mol/l 磷 酸 二 氢 钠68.5ml,.01mol/l 磷 酸氢二钠31.5ml混合液-甲醇(17:3)玄参哈巴俄苷(Harpagoside,C24H30O11)ODS乙氰和1%醋酸按1:41:1的变化比例洗脱OCH3H3COOCH3OHOHOOHOOCH3OHOHCH2OHOOOOOH3CCOOHCH3HCH3HCH3HH3CCH3COOHHOOHHOOCOHOHOOOOHOHHOH2CHOOHOOOHOOOHOHOHOHOHOOOOOHCCH2CH2OH
11、OHOHOHOOOHHOHOOOHOHOHHOOOOOOCH2CHC(CH3)2NOOOOOOOHHOHOOOHOHOHHOOOOHOHHCCOOgalCH3OHC母丁香丁香酚(Eugenol,C10H12O2)ODS甲醇-水(65:40)地肤子地 肤 子 皂 苷 Ic(Kochioside,C41H64O13)ODS甲醇-水-冰醋酸(85:15:0.2)地黄梓醇(Catalpol,C15H22O10)ODS乙氰-0.1%磷酸(1:99)地锦草槲 皮 素(Quercetin,C15H10O7)ODS乙氰-0.5%磷酸(50:50)西红花西 红 花 苷-I(Crocin1,C44H64O24)O
12、DS甲醇-水(45:55)西红花苷-II(Crocin2,C38H54O19)西洋参人参皂苷Rg1,Re,Rb1(C42H72O14,C48H82O18,C54H92O23)同人参ODS乙氰和0.1%磷酸按洗脱 时 间 以 19:8160:40比例洗脱当归阿 魏 酸(Ferulic,acid,C10H10O4)ODS乙氰-0.085%磷酸(17:83)肉苁蓉毛蕊花糖苷(C29H36O15)松果菊苷(C35H46O20)ODS乙氰-甲醇-1%醋酸(10:15:75)管花肉苁蓉 松果菊苷(C35H46O20)ODS甲醇-0.1%甲酸(28.5:71.5)肉桂桂皮醛(Cinnamaldebyde,C
13、9H8O)ODS乙氰-水(35:75)朱砂根岩 白 菜 素(Bergenin,C14H16O9)ODS甲醇-水(25:75)延胡索延胡索乙素(Tetrahydropalmatine,C21H25NO4)ODS甲醇-0.1%磷酸(三乙胺调PH6.0)(55:45)血竭血竭素(Drcorhodin,C17H14O3)ODS乙氰-0.05mol/l磷酸二氢钠(50:50)决明子大黄酚(Chrysophanol,C15H10O4)ODS甲醇-0.1%磷酸(85:15)关黄柏盐酸小檗碱(C20H17NO4.HCl)ODS乙氰-0.1%磷酸(50:50)(含十二烷基磺酸钠0.1g/100ml)灯盏细辛野黄
14、芩苷(Scutellarin,C21H18O12)ODS甲醇-0.1%磷酸(40:60)NOOOCH3H3COOHOCH3CH2CHCH2OOHOOHHHHOH2COCH2OHOHOHOHOOHOHOHOOHHOOHHOOOCHCHCHOOOOHH3COHOHOHOHOHCH2OHNH3COOCH3HOCH3OCH3OOOHOHOOOHOOCHOOHOHHOOHOOHOOCCOOR1R西红花苷I RR1龙胆二糖基西红花苷I R龙胆二糖基,R1D葡萄糖基OOCH3H3CO防己粉防己碱(Tetrandrine,C38H42N2O6)防己诺林碱(Fangchinoline,C37H40N2O6)OD
15、S乙氰-甲醇-水-冰醋酸(40:30:30:1)防风升麻素苷(C22H27O11)5-O-甲基维斯阿米醇苷(C22H28O10)ODS甲醇-水(40:60)红花羟 基 红 花 黄 色 素A(C27H30O15)/山奈素(Kaempferol,C15H10O6)ODS甲醇-乙氰-0.7%磷酸(20:2:72)/甲醇-0.4%磷酸(52:48)红参人参皂苷Rg1,Re,Rb1(C42H72O12,C48H82O12,C54H92O23)同人参ODS按 乙 氰 和 水 的 19:8140:60的比例按时间变化红景天红景天苷(Rhodioloside,C14H20O7)ODS甲醇-水(15:85)远志
16、远志酸(Polygalacicacid,C29H44O6)ODS甲醇-0.2%磷酸(73:30)赤芍芍药苷(Paeoniflorin,C23H28O11)ODS甲醇-0.05mol/l磷酸二氢钾(40:65)芥子芥子碱(Sinapine,C16H24NO5)苯基键合硅胶乙氰,3%醋酸按时间,以20:8030:70的不同比例梯度洗脱芦荟芦荟苷(Aloin,C21H22O9)(库拉索芦荟)ODS乙氰-水(25:75)苏合香肉桂酸(Cinnamic,C9H8O2)ODS甲醇-冰醋酸(50:50)杜仲松脂醇葡萄糖苷(C32H42O16)ODS甲醇-水(25:75)杜仲叶绿原酸(Chlorogenicacid,C16H18O9)ODS乙氰-0.4%磷酸(13:87)两头尖竹 j 节 香 附 素 A(RaddeaninC47H76O16)ODS乙氰,和1.0%磷酸进行梯度洗脱连翘连 翘 苷(Forsythin,C29H36O15)ODS乙氰-水(25:75)NNNNNH2OOHOHOHNNH3COOCH3OCH3OCH3H3CCH3HHOONNH3COOCH3OHOCH3H3CCH3HHOOOOO