1、MEXTOCYAAPCTBEHHbIM COBET No CTAH,AAPTN3ALN,METPONOrnN CEPTNONKALN(MrC)INTERSTATE COUNCIL FOR STANDARDIZATION,METROLOGY AND CERTIFICATION(ISC)FOCTMETOCYAAPCTBEHHbI32391-CTAHAAPT2013MACJIA MOTOPHbIEOnpegeneHne ucnapgeMocTu MeToAom kanunngpHonra3oBo XpoMaTorpannM3gaHne opnunanbHoeMockBaCTaHAaPTHOPM201
2、4OCT32391-2013npencnoBneLen,ocHoBHble npnHynti n nopAoK npoBegeHn paoT no mexrocyAapcTBeH-HoM cTaHAapT3a-ynn ycTaHoBneHbi OCT 1.0-92 MexrocyAapcTBeHHaA ccTeMa cTaHAapTn3aynn.OCHOBHbie nonoeHnAn OCT 1.2-2009 MexrocyAapcTBeHHa ccTeMa cTaHAapTn3aynn.CTaHAapTbi MexTocyAapCTBeHHble,npaBna n pekomeHgaunn
3、no mexrocygapcTBeHHo cTaHAapTn3aynn.paBnna pa3pa6oTkn,npMHATnA,npeHeH,HBneH OTeHbCBeAeHA o cTaHAapTe1 NOAOTOBNEH OTKpbITbIM aKynOHePHbIM 06WeCTBOM BcepoccncKn Hay4HO-nccnegoBaTenbcKn HcTTyT no nepepa6oTke HeT(OAO BHMM H)Ha OcHOBe co6cTBeHHoTo ay-TeHTM4Horo nepeBoga ha pyccK 3biK cTaHapta,yka3aHHoro
4、B nyHKTe 42 BHECEH egepanbHbIm areHTCTBoM no TexHnueckomy perynupoBaHnio n MeTponornn3 NIPMHAT MexrocyAapcTBeHHbIM CoBeTom no cTaHgaptn3aynn,meTponornn n cepTu中nKaynn(npoTokon oT 5 Ho6p 2013 r.N 61-)3a npHaTe nporonocoBann:KpaTKoe HanMeHoBaHne cTpaHbIKoA cTpaHbICokpaLeHHoe HanMeHoBaHne Ha-no MK(MCO
5、3166)004-97no MK(MCO 3166)004-97LoHanbHoro opraHa no cTaHAapT-3aunnApMeHAAMMnH3KOHOMnKn Pecny6nnKn Ap-MeHABenapycbBYFoccTaHAapT Pecny6nnkn bena-pycbKpr3KGKbiprb3cTaHAapTMongoBaMDMonAoBa-CTaHAapTPOCCARUPoccTaHAapTTaAKKMcTaHTJTaAKCTaHAapTy36ekncTaHUzy3cTaHAapT4 HacToAwn craHAapT nAeHTn4eH craHAapry AS
6、TM D 6417-09 Standard test method for estima-tion of engine oil volatility by capillary gas chromatography(CTaHAapTHLI MeToA oeHKn ucnapAeMOCTMoTopHoro Macna MeTogoM KannnpHo ra3oBon xpoMaTorpaon).CTaHAapt nogroToBneH KoMnTeToM ASTM D02 HepTenpoAyKTbi n CMa304Hble MaTepnanbi n He-nocpeAcTBeHHyIo OTB
7、eTCTBeHHOCTb 3a MeToA HeceT noAKoMMTeT D02.04.0H no MeToAaM xpoMaTorpae-cKoro pa3geneH.epeBog c aHrnckoro a3bika(en).HanMeHoBaHne HacToero MexrocyAapcTBeHHoro cTaHAapTa 3MeHeHO OTHOCTenbHO HanMeHO-BaHn yka3aHHoro cTaHgapta An npBeeHn B cooTBeTcTBne c OCT 1.5-2001(noApa3gen 3.6).OuanLHble 3K3eMnnpbi
8、cTaHgapTa ASTM,Ha ocHoBe KoToporo nogroToBneH HacToun Mex-rocygapcTBeHHbin cTaHAapt,n cTaHAapToB,Ha KoTopble gaHbi ccbInkn,MeloTcA B eAepanbHoM Hop-MaLOHHOM oHAe TexHnecKnX pernaMeHTOB n cTaHAapToB.CBeAeHnA o cooTBeTCTBn MexrocyAapcTBeHHbIX CTaHAapTOB CCbIno4HbIM cTaHAapTaM npnBeAeHbIB AononHTenbHoM
9、 npnoeH A.CTeneHb COoTBeTCTBnA-AeHTHa(IDT)5 lpuka3om 中egepanbHoro areHTcTBa no TexHn4eckoMy perynnpoBaHnio n MeTponornn oT 22 HO-g6p 2013r.Ne 692-cT mexrocyAapcTBeHHbi cTaHAapt OCT 32391-2013 BBeAeH B AeicTBne B KauecTBeHauoHanbHoro cTaHAapTa PoccncKon 中egepaunn c 1 HBapa 2015 r.6 BBE,AEH BNEPBbIEFO
10、CT32391-2013o6 K hacmoguemy cmaHdapmy g exeaodHoM-quOHHOM yKa3amene HaquoHanLHbe cmaHapmbi,a meKcm u3MeHeHu u nonpaeok-e exeMeCRHHOMuHpopMaquOHHOM yka3amene HayuoHanLHbIe cmaHapmbI.B cnyuae nepecMompa(3aMeHbi)unu om-MeHbI Hacmogue2o cmaHdapma coomeemcmeyiouwee yeedomneHue 6ydem ony6nukoeaHo e exeMec
11、4-HOM uHopMaquOHHOM yKa3amene HayuoHanbHbIe cmaHapmbI.Coomeemcmeyiowa uHpopMauus,yeedomneHue u mekcmbI pa3Mewalomc makke e uHpopMayuoHHo cucmeMe o5we2o nonb3oeaHuA-HaopuuuanLHoM calime PedepanLHo2o a2eHmcmea no mexHu4eckoMy pe2ynupoeaHuio u mempono2uu ecemu HmepHem.CTaHAapTnHopM,2014B Poccnckon Pege
12、paynn HacToAn cTaHAapt He MOkeT ObITb nOnHOCTbo n yact4HO BOC-npon3BeAeH,TpaxnpoBaH n pacnpocTpaHeH B Ka4ecTBe onyManbHoro n3AaHnA 6e3 pa3peweHnA 中eAe-panbHoro areHTcTBa no TexHneckoMy perynnpoBaHo n MeTponornn0CT32391-2013M E X r O C y A P C T B E HH bI N C T A HA P TMACnA MOTOPHbIEOnpeneneHne ncna
13、paeMoCTn MeTonoM KanwnnapHonra3oBon xpoMatorpadnnEngine oils.Test method for determination of volatility by capillary gas chromatographyAaTa BBeneHwa-2015-01-011 O6nacTb npNMeHeHNA1.1 HacToawnn cTaHnapT ycTaHaBnnBaeT MeTon KonnyeCTBeHHon oueHKN ncnapseMOCTn MOTop-HbIX Macen npn TeMnepaType 371 C(700
14、 F)MeTOnOM KannnnapHon ra3oBoN xpoMatorpadnen.1.1.1 npn Heo6xoNMOCTN HacToawnn MeTon wcnblTaHnN Takke MOXKHO wcnonb3oBaTb an konnye-CTBeHHon oueHKn ncnapgeMoCTn Macna B Anana3oHe TeMnepaTyp OT 126 C Ao 371 C.1.2 HacToawnn MeTon npnMeHAIOT B AMana3oHe TeMnepatyp oT TeMnepaTypbl Hayana knneHnABblwe 12
15、6 C(259 F)wnw nepBon Kann6poBOyHON TOuKM Ao TeMnepaTypbl KOHua knneHna HuxKe 615 C(1139 F)wnn nocneAHnx 3nionpyeMbIX H-ankaHoB B Kann6poBouHoM CMecn 06pa3uoB,conepxkawnx 6a30-Bble CMa304Hble Macna.OonacTb npnMeHeHN HacToawero MeTona NcnblTaHNA MOXKHO pacwnpNTb npnncnonb30BaHnn apyrnx npnoopoB N kono
16、HOK1.3 B HacToaweM MeTone NcnblTaHna Ncnonb3yIOT npNHunnbl MeTona NMNTNpoBaHHON ANCTNnnA-UNM.1.4 HaCToAwMN MeTon NcnbITaHNM MOXKHO Ncnonb3oBaTb Kak n ba30BbIX CMa304Horo Macna,TakCMa304HbIX Macen,conepkawnx Habop npncanok.Habop npncanoK 06blYHo conep/KnT BbicokoKnnawe KOMnOHeHTbI C BbIcoKon Monekyna
17、pHon Mac-CoN,KOTopble He 3nonpyIOT N3 xpoMatorpadnyeckon KonoHKN B ycnoBnAX NcnbITaHNA.Vcnonb3yeMa BHacTogweM MeTone ncnbITaHnn npouenypa BblyNcneHNA npennonaraeT,YTo Bce KOMnOHeHTbI npoobl3nlonpyIOT N3 KONOHKN N neTeKTNpyIOTCA C OANHaKoBoN YyBCTBMTenbHOCTbIO.3To npennonoxkeHne He cne-nyeT pacnpocTp
18、aHaTb Ha o6pa3ubl C BbIcoKoKNnAWNMN npncankaMn,T.K.MOXKHO nonyyMTb 3aBblweHHblepe3ynbTaTbl no cpaBHeHnO c npeanonaraeMbIMN.Io3TOMy pe3ynbTaTbl,nonyyeHHble no HacToaweMy Me-Tony NcnbITaHNA,3anNcblBalOT Kak npoueHT nnowan nwka Macna.1.5 3HayeHnA B CncTeMe eAnHny CM paccMaTpnBaloT KaK CTaHnapTHble.3Hay
19、eHnA B CncTeMeAoMM-yHT npMBeneHbl ana NH中opMaunn.1.6 B HacroaweM CTaHAapTe He npenyCMoTpeHo paccMoTpeHne Bcex BonpocoB obecneyeHna6e3onaCHOCTM,CBA3aHHbIX c ero npnMeHeHneM.nonb3oBatenb HacToawero cTaHnapTa HeceT OTBeTCTBeH-HOCTb 3a ycTaHoBneHMe COOTBeTCTByownx npaBnn no TexHnKe be3onaCHOCTn n oxpaHe
20、 3nopoBbA,a TakkeonpenenaeT uenecooopa3HOCTb npnMeHeHNA 3aKoHonaTenbHbIX orpaHnyeHnn nepen ero ncnonb3oBaHn-eM.2 HopMaTNBHble cCbinKnna npnMeHeHNA HacToawero cTaHnapta HeooxoNMbl cnenylowne ccbinoyHble nokyMeHTbI.AngnaTNpoBaHHbIX CCbinoK npNMeHAIOT TonbKO yKa3aHHoe N3naHne CCbinoyHoro nokyMeHTa,Hena
21、Tnpo-BaHHbIX CCbinoK npNMeHAHOT nocne Hee N3naHne CCblnoyHoro nokyMeHTa(BKnOHa Bce ero N3MeHeHNA).2.1 CTaHnapTbI ASTM1)ASTM D 2887 Standard test method for boiling range distribution of petroleum fractions by gaschromatography(CTaHnapTHbIN MeTon pa3geneHna HedTAHbix dpakunn no TeMnepaTypam KnneHn Me
22、To-AoM ra3oBon xpoMaTorpadnn)ASTM D 4626 Standard practice for calculation of gas chromatographic response factors(CTaH-napTHa npaktnka BblyNcneHnA ra3oxpoMatorpadnyecknx Ko3oonuneHTOB oTKnNKa)ASTM D 5800 Standard test method for evaporation loss of lubricating oils by the Noack method(CTaHnapTHbIn
23、MeTon onpeneneHna noTepb OT NcnapeHna CMa304HbIX Macen MeTOnOM Hoak)1)CcbinKn Ha CTaHgapTbl ASTM MOXKHO yTOuHMTb Ha canTe ASTM website,www.astm.org nnn Bcnyxkoe nonnepxkkn knneHTOB ASTM serviceastm.org,a Takxke B MHdopMauNoHHOM TOMe exkeronHorocoopHnKa cTaHnapToB ASTM(Website standards Document Summ
24、ary).M3 naHne o中nunanbHoeFOCT 32391-2013ASTM E 355 Standard practice for gas chromatography terms and relationships(CTaHgapTHannpaktuka An TepMHoB B ra30Bon xpoMaTorpan n X B3anMOCBA3b)ASTM E 594 Standard practice for testing flame ionization detectors used in gas or supercritical fluidchromatograph
25、y(CTaHgapTHa npakTnka An npoBepkn nnaMeHHO-MOH3ayOHHbIX AeTeKTopOB,cNonL-3yeMbIx B ra30Bo nn BbicoKo3中中eKTnBHO nAKocTHOn xpoMaTorpa中un)ASTM E 1510 Standard practice for installing fused silica open tubular capillary columns in gaschromatographs(CTaHAapTHaR npakTuKa An ycTaHoBK oTKpbITbIX KBapyeBbix
26、KannnngpHbIX KONOHOK Bra3oBbIX xpoMaTorpaax)2.2 CTaHAapT EBponenckoro KoopAHaMOHHoro coBeTaCEC L-40-93 Evaporation loss of lubricating oils(Noack evaporative tester)lorepn or ncnapeHnCMa304HbIX Macen(cnapTenbHbI annapaT HoaK).2)3 TepMHbI,onpegeneHng n cokpaweHg3.1 B Hactoquem ctaHAapte npnmeHeHbi Te
27、pMNHbi n onpegenehng,npnBeAeHHble B ASTM E 355,ASTM E 594 n ASTM E 1510,a Take cnegyiowne TepMHbI C COOTBeTCTByouMn onpegeneHnAM:3.2.1 nnowagb nuka(area slice):lnowagb,nonyeHHa B pe3ynbTate HterpupoBaHnA curHanaxpomaTorpapneckoro geTexTopa B npegenax 3agaHHoro HTepBana BpeMeHn yAepnBaHMA.B pexnMen3M
28、epeHng nnouwagn nnka(cM.6.5.2)napameTpbi geTeKTpoBaHnA nnKa He cnonb3yOT,a CyMMapHbIMcnrhan getekTopa 3anncbiBaiot kak nnowaAb nnKoB,cOoTBeTcTByiounx nocneAoBaTenbHbIM OKCPoBaH-HbIM HTepBanaM BpeMeHM.3.2.2 ckoppekTpoBaHHa nnowagb nnka(corrected area slice):lnowag nuka,ckoppekTupo-BaHhag c y4eTom CMe
29、eHn a3oBon nnHn nyTem BbI4TaHA CooTBeTcTByouen nnowaAn nnKa,n3Me-peHHou no pe3ynbtatam paHee BbinonHeHHoro xonoctoro ncnbiTaHnA.3.2.3 cyMMapHag ckoppeKTupoBaHHag nnowaAL nnka(cumulative corrected area):O6a cym-Ma ckoppeKTpoBaHHbix nnowagen nnKoB,n3MepeHHbIX B Te4eHne 3agaHHoro BpemeHn yAepxnBaHng(RT
30、)6e3 nnouagu nnkoB np xonocTom CnbITaH(Hanpumep,nnouagL nnka pacTBopuTeng).3.2.4 ckopoCTL 3MepeHnA nnowagn nuka(slice rate):poMexyToK BpeMeHn,ncnonb3yeMbiAn HTerppoBaHg nocTogHHoro(aHanoroBoro)curHana xpomatorpan4eckoro getektopa npn ncnLiTa-H.CKOpOCTL 3Mepehna nnowann nnKa BbipaaoT B repyax(Hanpnme
31、p,KonM4ectBo onepau HTerp-poBaH n KonecTBo 3MepeH nnouagn nnka B cekyHAy).3.2.5 BpeM n3MepeHn nnowagu nuka(slice time):CyMMapHa cKopocTb 3MepeHnA nnowaAnka(BpeMa npoBegeHn cnbTaH)B 3aBCMocT oT nnowan kaxoro nnka np xpoMaTorpaoe-cKom aHann3e.Bpemg 3MepeHn nnowagn nnka-3To Bpema go 3aBepwehn 3mepehng
32、nnowagn Ka-Aoro nnka.3.2.6 o6wa nnowagL nuka npo6bi(total sample area):CyMMapHa ckoppeKTupoBaHHa nno-wab nuka oT hayanbhon go KoHeyHo Toykn xpoMaTorpaMMbI.3.3 CokpaeHn门pMHATbIm Cnoco6om cokpaweHnA HanMeHoBaHnA yrneBogopoAHbix coegHeH ABngetcA 060-3Ha4eHne uncna aTomoB yrnepoga B coeAnHeHnn.penKc ncn
33、onb3yoT An yka3aHn opMbi yrnepoAHonyeno4kn,HnHn nHAexc o6o3Hayaet yncno atomoB yrnepoga(HanpnMep,HopManbhLiM AekaH-H-C10,30TeTpageKaH-i-C14).4 CyHOCTb MeToAa4.1 An 3nopoBaHn yrneBogopoAHbix KoMnoHeHToB npoobi no Bo3pacTaHno TeMnepaTypbi Knne-H cnonb3yoT oTKpbiTyio HenonpHyo KannnpHyo ra3oxpoMaTorpao
34、M4eckyo KonoHKy.4.2 An chXeHA B3Koct anuKBoTy npo6bi pa36aBnAHoT pacTBOpTeneM BBoAAT B XPOMaTo-rpapn4eckyo cucTeMy.Hepa36aBneHHble npo6bi cnbITbiBann B oHon na6opaTopnn.pey3MOHHOCTbMeToga 6bina onpegeneHa c cnonb3oBaHem pa36aBneHHbix npo6.Nepeg npoBegeHMeM CNbITaHMA He-pa36aBneHHon npoobi gonho Obit
35、 nogtBepgeHe nony4eHn pe3ynbTaToB,aHanorn4Hbix nonyeHHbIMnp cnbiTaHn pa36aBneHHo apeHe npo6bi o6ecne4nBaoT HarpeBaHneM nnH BBoAa npo-6bI nM HarpeBaHneM KonoHKM B TepMOcTaTe.4.3 Temnepatypy konoHkn B TepmocTate noBbiwaot c Bocnpon3BoAnMon nHeHOn ckopOctbio Anapa3geneHng yrneBogopoAHbiX KOMnoHeHToB B
36、nopqAKe Bo3pacTaHnA TeMnepatypbi KnneHn.GnonpoBaHneKOMnOHeHToB npoob KonM4eCTBeHHo onpeAeneTcA c cnonb3oBaHeM nnaMeHHO-MOHn3auoHHoro AeTeK-2)MoxHo nony4Tb B EBponeicKom KoopAnHayOHHOm CoBeTe(CEC),C/o Interlynk AdministrativeServices,Ltd.,P.O.Box 6475,Earl Shilton,Leicester,LE9 9ZB,UK,http:/www.cectests.org.2