1、中EAEPAbHOE ATEHTCTBOnO TEXHYECKOMY PErYJPOBAHH METPOJOrNHAUOHAbHbIFOCT PCTAHAAPTPOCCMCKO56869-中EAEPAL2016TA3bI YIEBOOPOAHbIE CKKEHHbIE CMEC PONAH-PONEHOBbIEOnpeeneHne yrneBoopogoB ra3oBonxpoMaTorpanenM3aHne opnunanbHoeMocKBaCTaHAapTMHoPM2016FOCT P 56869-2016peAncnoBne1 NOATOTOBNEH 中egepanbHbiM rocyA
2、apcTBeHHLIM yHNTapHbIM npeAnpnATnem Bcepoccnckn Ha-yqHo-nccneoBaTenbcKn nHcTnTyT cTaHAaptn3aynn matepnanoB n TexHonorn(中Yl BHM CMT)HaocHoBe co6cTBeHHoro ayTeHTHoro nepeBoga Ha pycckn A3biK cTaHAapTa,yka3aHHoro B nyHKTe 42 BHECEH TexHn4ecKnM KoMnTeTom no cTaHAapTn3aynn TK 52 门pnpoAHbI n cxneHHble ra3
3、bi3 YTBEPKAEH BBEAEH B AENCTBME pnKa3oM egepanbHoro areHTCTBa no TexHM4ecKoMy pe-rynupoBaHnio n MeTponornn oT 25 eBpang 2016 r.Ne 72-cT4 HacToAuwn cTaHAapt nAeHtn4eH cTaHAapry ACTM A 2163-14e1 CTaHAapTHbN meToA onpege-neHMA yrneBogopogoB B cxXeHHbIX HeTAHbIx(LP)ra3ax n nponaH-nponneHOBbIX CMecAx ra3
4、oBoM xpo-Marorpanei(ASTM D 2163-14e1 Standard test method for determination of hydrocarbons in liquefiedpetroleum(LP)gases and propane/propene mixtures by gas chromatography).HanMeHOBaHMe HacTowero cTaHgapTa n3MeHeHO OTHOcnTeNbHO HanMeHOBaHnA yKa3aHHoro cTaHAap-Ta ACTM An npuBeAeHnA B cooTBeTcTBue c
5、 OCT P 1.5-2012(noApa3gen 3.5).门pn npuMeHeHn HacToqero cTaHAapTa peKoMeHAyeTcA ncnoNb3OBaTb BMeCTO CCbiNo4HbIX CTaHAap-TOB COOTBeTCTByoe nM HanoHanbHbe cTaHAapTbI POccnckon Pegepaynn n MexrocyAapcTBeHHble cTaH-Aaptbl,cBeehng o kotopbix npuBegeHbi B gononHntenbHom npnnoeHn AA5 BBEAEH BNEPBbIEpasuna n
6、puMeHeHuA Hacmoye2o cmaHdapma ycmaHoeneHLI e FOCT P 1.0-2012(pa30en 8).o6 K hacmogueMy cmaHdapmy B exeaodHoM(no Ha1 sHeaps mekywe2o 2oda)uHpopMauoHHoM yka3amene HaquoHanLHbIe cmaHdapmbI,a opuquanbHbIimexcm u3MeHeHu u nonpaeok-e exeMecR4HoM uHpopMaquOHHoM yka3amene HauuoHanLHbIecmaHdapmbI.Bcnyae nepe
7、cMompa(3aMeHLi)unu omMeHLI Hacmoue2o cmaHdapma coomeemcmeyioueeyeedomneHue 6ydem ony6nukoeaHo e 6nuxaiuem ebinycke exeMecA4Ho2o uHpopMayuOHHo20 yka3amengHayuoHanLHbie cmandapmbI.Coomeemcmeyiowa uHpopMayu,yeedoMneHue u mexcmbi pa3Mewaomcamakke e uHpopMayuoHHou cucmeme o6we2o noNb3oeaHuR-Ha ouyuanLHom
8、 calime OedepanLHo20azeHmcmea no mexHu4eckoMy pezynupoeaHuio u Memponozuu e cemu HmepHem(www.gost.ru)CTaHAapTnHopM,2016HacTou cTaHgapt he Moket ObITb nONHOCTbo nn yact4HO BOcnpon3BegeH,TupaxnpoBaH n pac-npocTpaHeH B ka4ecTBe onynanbHoro n3AaHn 6e3 pa3peweHnA PeAepanbHoro areHTcTBa no TexHnYecko-My p
9、erynupoBaHo n MeTponornnOCTP56869-2016CoAepxaHne1 O6nacTb npMeHeH.12 HopMaTBHbIe CCbinK.13 TepMMHbI onpegeneH.24 CyHOCTb MeToga.25 Ha3Ha4eHne n npnMeHeHne.26 Annaparypa.37 PeaKTBbI MaTepanbi.58 logroroBka annaparypbi.69 Kann6poBka n cTaHapTn3ayn.910 lpoBegeHe cnbITaH.1011 Bb4cneHA.1112 poToKoN ucnbI
10、TaH.1213 门pe3MOHHOCTb CMeeHne.12门punoxeHne X1(cnpaBo4Hoe)Ko3pneHTbI oTKnnKa,ycTaHoBNeHHble TeopeTn4eckn.13门punoxeHne AA(cnpaBo4Hoe)CBeAeHnA o cOOTBeTCTBnn cCbino4HbIX cTaHAapToB ACTMHauoHanbHbIM cTaHAapTam PoccncKon Pegepaunn(n gecTByIOnM B 3Tom KayecTBeMexrocyAapcTBeHHbIM cTaHAapTaM).16OCTP 56869-2
11、016HAUMOHAbHbI CTAHAAPT POCCCKO EAEPAUTA3bI yEBOAOPOAHbIE CKKEHHbIE CMEC NPoNAH-nPONEHOBbIEOnpegeneHe yrneBogopogoB ra3oBon xpoMaTorpa中nenLiquefied petroleum gases and propane-propene mixtures.Determination of hydrocarbons by gas chromatographyAaTa BBeAeH-2017-01-011 06nacTb npMeHeHA1.1 HacToAwM cTa
12、Hgapt ycTaHaBnnBaet Konn4ecTBeHHoe onpegeneHne HAnBngyanbHbix yrneBogo-pOA0B C1-C5 B CxxeHHbix yrneBoAopoAHbix ra3ax(LPG)u cMecqx nponaHa u nponnneHa,3a ncknio4e-Hnem nponnneHa BbicoKo ncToTbi.CogepxaHne KoMnoHeHToB onpegenioT B Auana3oHe oT 0,01%06.Ao100%06.1.2 Hactoqw metog He no3Bonger gocToBepho
13、 onpegenat yrneBogopoAbi taxenee C n HeyrneBo-gopogHble matepanti,no3tomy An nonHo xapakTepucTuKn LPG moryT noTpe6oBaTbc gonoNHTenbHbleCnbiTaHA.1.3 3HayeHn B eAnHnyax CM cunTaloTcA cTaHAapTHbiMn.3Ha4eHnA B ckookax npnBeAeHbi Ang H-opMaunn.1.4 B HacToAueM cTaHgapTe He npeAycMoTpeHO paccMoTpeHe Bcex B
14、onpocoB o6ecne4eHA Ge30-nacHOCT,CBg3aHHbix c ero npnMeHeHneM.onb3oBaTenb HacToquero cTaHgapTa HeceT OTBeTCTBeHHOCTb 3aycTaHoBneHne cooTBeTcTByioux npaBn no TexHnKe 6e3onacHocTn n oxpaHe 3AopoBb,a Takke onpegena-eT Lenecooopa3HoctL npmeHeHn 3aKoHogaTenbHbix orpaHeH nepe ero cnonb3oBaHneM.2 HopMaTBHbl
15、e ccbInKnB HacTOAuem cTaHAapte ncnonb30BaHbi HOpMaTNBHble ccbinkn Ha cneAyioune cTaHAapTbi:2.1 CTaHAapTbI ACTM1)ACTM A 1265 CTaHAapTHa npakTuka or6opa npo6 cnxeHHbix yrneBoAopoAHbix(LP)ra3oB,py4HoiMerog ASTM D 1265,Standard practice for sampling liquefied petroleum(LP)gases,manual methodACTM A 1835
16、CTaHAapTHa cnen中nKayna ha cxnxeHHble yrneBogopoAHble(LP)ra3bi ASTM D 1835,Standard specification for liquefied petroleum(LP)gasesACTM A 2421 CTaHAapTHa npaktuka nepecuera pe3ynLTatoB onpegeneHn C n 6onee nerknx yrne-BogopogoB B 06bem ra3a,06bem xnAkocn unn Maccy(ASTM D 2421,Standard practice for int
17、erconversionof analysis of Cg and lighter hydrocarbons to gas-volume,liquid-volume,or mass basis)ACTM A 2598 CTaHAapTHa npaKTnKa BbI4nCneHnA HeKoTopbIx On3n4ecknX cBOMcTB CHMKeHHOToyrneBogopogHoro(LP)ra3a no KoMnoHeHTHoMy cocTaBy ASTM D 2598,Standard practice for calculation ofcertain physical prope
18、rties of liquefied petroleum(LP)gases from compositional analysisACTM A 3700 CTaHAapTHa npaktuka or6opa o6pa3yoB LPGc ucnonb3oBaHem nnaBaiouwero nopw-HA(ASTM D 3700,Standard practice for obtaining LPG samples using a floating piston cylinder)ACTM A 6729 CTaHAapTHbi meTog onpegeneHn nhAnBngyanbHbiX K
19、OMNOHeHTOB MOTOpHbIX TONnMBAna ABuratenen c ncKpoBbiM 3axnraHnem c CnonL3oBaHNeM BLIcOKo3中中eKTBHo ra3oBon xpoMaTorpapnn1)yTo4HNTb ccbInKn Ha cTaHAapTbi ACTM MoXHO Ha calite ACTM www.astm.org unu B cnyx6e noAAepxknKnMeHToB ACTM:serviceastm.org.B nHpopMaLNOHHOM ToMe exerogHoro coopHnKa cTaHAapToB(Annu
20、al Book ofASTM Standards)cneAyeT o6pauaTLcA K cBoAKe cTaHAapToB exeroAHoro copHnKa cTaHAapToB Ha cTpaHne caTa.M3AaHne opnunanbHoeFOCT P 56869-2016Ha 100-MerpoBo kanunnapHoi KonoHke(ASTM D 6729,Standard test method for determination of individualcomponents in spark ignition engine fuels by 100 metre
21、capillary high resolution gas chromatography)ACTM E 355 CTaHAapTHag npaktuka no TepMHaM n onpegeneHnAM B ra3oBo xpoMaTorpa中nn(ASTM E 355,Standard practice for gas chromatography terms and relationships)ACTM E 594 CTaHAaptHhag npaktuka tectupoBaHng nnaMeHHo-noHn3aynoHHbix geTektopoB,ncnonb-3yeMbIx B
22、ra30Bo nn cBepxKpnTn4ecKo xAKocTHo xpoMaTorpapn(ACTM E 594,Standard practice fortesting flame ionization detectors used in gas or supercritical fluid chromatography)ACTM E 1510 CTaHAapTHaA npakTnKa ycTaHoBKn oTKpbITbIx KBapyeBbix kannnngpHbix KonoHoK B ra-3oBbie xpoMaTorpapui(ACTM E 1510,Standard pr
23、actice for installing fused silica open tubular capillary col-umns in gas chromatographs)2.2 06wn cTaHAapT KaHaAbI2)CAN/CGSB 3.0 Ne 14.3 CTaHAapTHbi meTog ncnbiTaHn An nAeHTnOnKaynn yrneBogopoAHbiXKOMNOHeHTOB B aBTOMO6MNbHbIX 6eH3nHaX c CNONb30BaHMeM ra3oBoM xpomaTorpa中nn(CAN/CGSB 3.0Ne 14.3,Standar
24、d test method for the identification of hydrocarbon components in automotive gasoline usinggas chromatography)2.3 CTaHAapT Accounaunn nepepa6oTnKoB ra3a3)GPA Std 2145-03 Ana rexcaHa(GPA Std 2145-03 for hexane)3 TepMHbI onpegeneHgB HacTOAueM cTaHAapTe npnMeHeHbI cneAyoue TepMHbI C COOTBeTCTByiounMn o
25、npeAeneHnAMn:3.1 06wne TepMHbI onpeeneH3.1.1 AononHnTenbHble TepMHbi no ra3oBon xpoMatorpapnn npBeAeHbi B ACTM E 355.3.1.2 cxnxeHHble yrneBogopoAHble ra3bI(LPG)liquefied petroleum gas LPG):YrneBoAopoAHbiera3bl,KoTopble MoryT xpaHTbcA nNM cnoNb30BaTbc B XAKOM cocToAHnn npn cxatn n/nnn oxnakgeHnn.3.1.
26、2.1 loAcHeHne-LPG 06bI4H0 COCTOAt 3 C3 n C4 ankaHoB n anKeHoB unn uX Cmecen n cogep-xat He 6onee 10%o6.yrneBogopogoB c 60nbwnm konn4ecTBoM aToMoB yrnepoga.AaBneHne HacbIeHHbIXnapoB 06bI4HO He npeBbiwaeT 2000 Ka np TeMnepaType 40 C.3.2 TepMMHbI,xapakTepHble An HacTowero cTaHgapTa:3.2.1 nponaH-nponnne
27、HoBbie cMecn(propane/propene mixtures):CMec,cocTOAuMe B OCHOBHOM n3nponaHa n nponwneHa,B KoTopbix cogepxaHne ogHoro n3 yKa3aHHbIX KoMnoHeHToB,KaK npaBnno,cocTaBna-er o 30%Macc.go 85%Macc.,a cogepxaHne Apyroro KomnoHeHTa cocTaBneT 6onbwyio actb OcTatka.ToBaphbi nponaH no ACTM A 1835 BngeTcA Tunn4Hbim
28、 npeAcTaBnTenem Bbiweyka3aHHO CMecn npo-AyKTOB.3.2.1.1 loAcHeHne-CogepxaHne Apyrux npncyTcTByiounx KomnOHeHTOB-He 6onee 10%Macc.4 CyuHOCTb MeTogaAHann3pyioT o6pa3ey cxn*eHHoro yrneBogopogHoro ra3a MeTogoM ra3oBon xpoMaTorpann,BBo-A npo6y B xnAKom nn ra3oo6pa3Hom cocToAHnn c noMOubo KpaHa-go3aTopa.Cp
29、aBHnBaoT nony4eHHblepe3ynbTaTbi c cOoTBeTcTByHoMn pe3ynbTaTaMn,nony4eHHbIMn An KoMnOHeHTOB cTaHAapTHOM CMecn n3-BecTHoro cocTaBa nn c cnonb3oBaHneM 4ncTbix yrneBogopogoB,pa3geneHHbix npn oAnHaKoBbix ycnoBngx.CpaBHMBaoT BpeMA yAepxnBaHng n nnowagn nnkoB xpoMaTorpaMMbI o6pa3ua c pe3ynbTaTaMn,nony4eHHb
30、i-M An cTaHAapTHon cMec n 4cTbix yrneBoopoAoB.5 Ha3Ha4eHne n npnMeHeHe5.1 OnpegeneHne cogepxaHn yrneBogopoAHbix KoMnOHeHTOB B cnxeHHbix yrneBoAoPoAHbIX ra3axn nponaH-nponnneHoBbix cMecAx Heooxognmo Ang npakt4eckoro npnMeHeHnA n peann3aynn Matepnana.2)(MeeTc B CGSB,Canadian General Standards Board,Gatineau,Canada K1A 1G6.CM.cair CGSBwww.pwgsc.gc.ca/cgsb.3)MoxHo npno6pecTn B Gas Processors Association(GPA),6526 E.60th St.,Tulsa,OK 74145,cM.2