1、 2385-2014 (ASTM D3246-14,)(2385-2014:,-665.723.033.52:543.551.063.2(083.74)(476)75.160.20 03,.1 -()2 15 2014.543 ASTM D3246-14 Standard Test Method for Sulfur in Petroleum Gas by Oxidative Microcoulometry().ASTM ASTM D02 ,D02.03 .:ASTM D 1.5-2004(04100).().,.-()4 ,2015 ,II 2385-20141 .12 .13 .24 .2
2、5 .26.27 .38 .59 .510 .511 (QA).712 .713 .714 .815 .8 ().9 X().11III 2385-2014 Petroleum gases Determination of sulfur content by oxidative microcoulometry method 2015-07-011 1.1 ,1,5 100/1().1 -.1.2,.,.1.3 ,.,.2 2.1 ASTM:1)ASTM D1265-11 .ASTM D1193-06(2011)ASTM D3120-08 ASTM D6299-10e2 ASTM F307-13
3、 2.2 :G-4 and G-4-1 2).1)-ASTM www.astm.org serviceastm.org.ASTM Document Summary -.2 ,1235 Jefferson Davis Hwy.,Arlington,VA 22202.1 2385-20143 3.1 ,800,80%20%(,.).,-,.(),.3.2,:+S02+20 S03+2+.(1)-,:1 3 +2.(2)3.3 (),.3.4 .4 4.1 ,.,.4.2 ,.5 5.1 ,10,1%.5.2 (,Ni,V,.),500/.2-.6 3 4)6.1 ,.,.3),6.1-6.5,Te
4、kmar-Dohrmann,7143.Kemper Rd.,Cincinnati,524549.Determination of Sulfur,Nitrogen,and Chlorine in Petroleum by Microcoulometry(,),Harry V.Drushel,Preprints-Division of Petroleum Chemistry,American Chemical Society,Vol 1,No.3,Sept.7-1 2,1969,p.B232.4 1 ,Tekmar-Dohrmann.-ASTM International.,.2 2385-201
5、46.1.1 ,:700;1000;()800.6.2 ,.6.3 ,-.,.,.(-,.)6.4 ,-.6.5 0,1/25 12 25/.,.6.6 10,1 10 ,75 24 .3-,(0,1 0,2/).6.7 ,5 3 .25 28 .6.8 .7 7.1 .,5).,.5 ,Washington,DC.,.:AnalaR ,BDH Ltd.,Poole,Dorset,U.,Inc.(USPC),Rockville,MD.3 2385-20147.2 /.ASTM D1193.4-,.7.3 (1,05).(-.1.1).7.4,(HP Grade),-.99,995%.(-.1.
6、2.)7.5 0,5 (KI)0,6 (NaN3)500,5 1000.5-3 .7.6 -.7.7 (2)20 ,.(-.1.3.)7.8 (2,2,4-),.(-,.)6-,.:80 (176 F),(2,2,4-)99,3 (211 F)287,5 (549,5 F).7.9-(CH3CH2CH2CH2)2S7.10 (HP Grade)5,-.(-.1.5.)7.11 (KI).7.12 (NaN3).(-.(),.)7.13 (30/)10 (7.14)100 .7-,.7.14 300/(1)(ppm).0,5000 -500.s=-,0,2187 10/|(-+),7.15 ,.
7、()10.4 2385-20147.16 (QC),.12.8 8.1,ASTM D1265 ASTM F307,.8.2 -.9 9.1 -.9.2 .3,2 6,4 (1/8 1/4).9.3 .9.4 ,25 (1),.9.5 .(),.().1.2 .9.5.1 .9.6 ,.1.1 -(),3/160-(Ar,N),3/40,:700 800 800 :,160(200)10 10.1 ,.,7.13,7.14,.10.2 (9.6).8-80%20%.5 2385-201410.3 .80%.10.3.1 ,8 (),1 ,.(),1 ,.10.3.2 .(0,0 1),.10.4
8、 0,1-0,2/.(/),0,1-0,2/.10.5 .9-,SO2.SO3,.,-,.75%.,.,75%90%.10.6 ,.1 ,0,1/0,5/:=(1,9 9)/(R s0 VL/1000)100,%,(4)-,2;R-,;S0-,/;VL-,.10.6.1 :=(1,9 9 103)/(R xSx vLl 1000)100,%,(5)-.1.10.6.2 :=100,%,(6)(),-;-,/.10-ASTM D3120.10.6.3 ,.10.7 ,S02,75%,.,.10.8 F,S/cm2,F=(S 0 x VL/1000)/.(7)6 2385-201411.1 ().
9、11.2 ()(.7.16).11.2.1 ()/(QA),.11.2.2 QC/QA ,QC/QA ,.2.11 (QA)12 12.1 ,(;.1.7).,.,.12.2 .(-.1.8.)12.3 ,.5 3.12.4 .5,0 3 ,15.,10.2-10.7.12.5 .12.6 .13 13.1 ,/(ppm),=*F)IW,/,(8)-(),2;W-,;F-,S/cm2.:V 273W=-9-,(9)(273+)760 x22410 v Vg-,3;-,.;-,/;-,.23 760 .:W=Vg 0,001154.(10)7 2385-2014:W=VL/1000 d,(11)
10、VL-,;d-,/.13.2 ,1 (ppm),.14 14.1 0,1/.15 15.1 ,.15.1.1 ,.0 10/0,4/15.1.2 ,.0 10/15.2 -,.5/8 2385-2014.1 .1.1 .1.1.1 -.,.1.2 (,).1.2.1 -.,.,.1.3.1.3.1 -.,.1.4.1.4.1 -.,.,.1.5.1.5.1 -.,.,.()9 2385-2014 ./.(Compressed Gas Association)G-4 G-4.1.1.6 .1.6.1 -.,.,.1.7 .1.7.1 -().,.,.10 2385-2014 X().1.1 .1
11、.1 ,.1 ,13.1 100 X-1-.1.1-1.2 -.1.2.3 1 II i I /-.1.2-.1.3 .1.3.1 (),(13 +).()Q.1.3.2 ,/()()Q(),.Q=/.,Q/F,F-,95500 .11 2385-2014.1.3.3,Q(C)16 5-FC ,gm/v.=-=-(.1.1),0,1 2 60 103 16 106MKrS=2 /*-(.1.2)_ _ 96500 ,v R -xf 2-,;0,1/-;2/-;60/-;103 /-;16/-;106/-;R()-,V/R=I(),(.1.3):0,1 2 60 103 Q =2 -(.1.4)
12、ROM F-96500/,(-);/-;f-(S,1 (ppm)S,1 (ppm),).,.16 g 106 12x10 3-MKrS=-3!-(15)f?x96 5004f_ 1210316106/w._.MKrS=,(.1.6)96 500 f_ 1,99/v.7.MKrS=-1 .(.1.7)R x f x 1 (ppm)=/:41,99 ppm S=-(.1.8).-3 _ Rx f x ,10 ,-1 1,99x103 /V i m ppm S=-.(.1.9)Rxfx =1 (ppm)S=(1,99)/(f).(.1.10).1.3.4 (.1.7).,2 =3,1 2=1000.
13、,103 (5):S=(1,99 103)/(/).(.1.11)12 2385-2014.1,99 ppm S=-,(.1.12)Rx,xf1 (ppm)S=(1,99 103)/(R ,f).1.1-=100 .2 .2.1 ,(QC-).2.2 QC-.ASTM D6299 MNL 7 6).2.3 .QC-,.ASTM D6299 MNL 7 6).QC-,.2.4 QC-,.QC-.QC-,.,QC-.QC-.ASTM D6299 MNL 7 6).2.5,QC-.QC-.2.6 ASTM D6299 MNL 7 6).:6)MNL 7 Manual on Presentation of Data Control Chart Analysis,6th Ed.,Section 3(,6-,3),ASTM International.13 .13.01.2015.19.02.2015.60 x84/8.Arial.1,97.-.1,27 2.137 :-(),1/303 22.04.2014.,3,.406,220113,.