1、 D7754-16 STANDARD TEST METHOD FOR DETERMINATION OF TRACE OXYGENATES IN AUTOMOTIVE SPARK-IGNITION ENGINE FUEL BY MULTIDIMENSIONAL GAS CHROMATOGRAPHY 2017 ():01.12.2017:3330-17/ASTM -,.9,119049.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)100 rr
2、Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)1
3、00 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified transl
4、ations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D7754-16 1 D7754-16 1 D7754;,.().1.*1.1 .1,2-.:-(MTBE),-(ETBE),(DIPE),-(TAME),-,-,-,-,-,-1 ASTM D02 ,D02.04.0L .1 2016.2016.2011.2011.D
5、7754-111.DOI:10.1520/D7754-16.ASTM D7754-16 2.,.,(ILS),10/2000/.,C5-(2-1-,2-2-),.1.2 ,1%15%.,.X1.1.3,.1.3.1 .ASTM D7754-16 3 2.2.1 ASTM:2 D4057 D4307 D4815 ,TAME,DIPE,1 4 D6304 ,3.3.1 ,:3.1.1 -.3.1.2-(FID),.3.1.3 ,-,.(Dean).3.1.4 /,2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary
6、ASTM.ASTM D7754-16 4 .3.1.4.1 ,-,:=(S+C)/C(1):S-,-.3.1.5 1,6.3.1.6 ,(,.),()(),(,.).3.1.7 WCOT-,(100%-,5%-).3.1.7.1 ,.3.1.7.2-PLOT-,-(/).ASTM D7754-16 5 4.4.1 ,1,2-(1,2-DME),4-.()WCOT-,.DME -.DME -.-.4.2 .1 -.(.1),(.2),.DME.,.ASTM D7754-16 6 1.WCOT/PLOT(,.2)A -(RT),-(Wt)BP(C)-ETBE 12,7 102,2 70-72 1,
7、919 0,02 0,999 MTBE 12,8 88,2 55-56 1,689 0,01 0,999 DIPE 12,9 102,2 68-69 2,124 0,06 0,999 TAME 13,6 102,2 85-86 2,023 0,02 0,999 15,6 32,0 65 0,779 0,09 0,997 18,7 46,1 78 1,352 0,19 0,999-22,2 60,1 81-83 1,504 0,06 0,999-22,2 60,1 97 -23,8 74,1 82 1,951 0,12 0,999-23,8 74,1 98 -23,8 74,1 117 -24,
8、4 74,1 118 1,906 0,05 0,999-25,1 88,1 102 2,148 0,04 0,998 1,2-DME 26,0 90,1 85 A .1 S/SL AUX 3 AUX 3 S/SL FID FID ASTM D7754-16 7 .2 4.3 ,-(.3 4).(ZDV),-.,(),PLOT-.,.,.5.5.1 S/SL S/SL AUX 3 AUX 3 FID FID FID FID ASTM D7754-16 8 ,.,.3 6.6.1 -,.,.2.,.1 2(),.3 4.-(EPC).1.S/SL 5,4/7,0/1,6/CFT-ASTM D775
9、4-16 9 2.-1,0 1,0 :/()/()250C 250C 10:1 10:1 A 51,7,17,8,30 0,53 5,0 PDMS 7,5/60C 15 0,53 1,5 5%-PDMS :5,4/60C 1,5 :90/-5/10 0,53 10,-10 0,53 10,-7,5/60C 7,0/:60C 60C 6,0 6,0 1 10C/10C/150C 150C 5,0 5,0 2 10C/10C/220C 220C 3,0 3,0 30 30 :FID FID 275C 275C 40/40/450/450/(N2)10/10/150C 73,1 10,3 76 0,
10、16 (.)0,25 (.)SS ():0,50 4,50 A ,9.2,34,5.ASTM D7754-16 10 6.1.1 B -,()./5:1 1/,.6.1.2-,9.2,.1.,.3 4.4 6.1.2.1 :1,6 0,75.6.1.2.2 ,.4.3,.2 .3 4.,S/SL -4/7,0/11,0/ASTM D7754-16 11 .6.1.2.3 ,.,.6.1.2.4 ,.6.1.3 ,(),.6.1.3.1 .6.2 :6.2.1 ,.6.2.2 ,ASTM D7754-16 12 .6.3 :6.3.1 (),.,.6.3.1.1 WCOT-30 0,53,5 .
11、()30,0,53 -1,5 5%-.6.3.2 ,6.3.1,.5 6.6.3.2.1 LowOx GS OxyPLOT-PLOT-10 0,53,10.,.14.7.7.1:7.1.1,-,99,995%.WCOT-.ASTM D7754-16 13 .5 ,WCOT-7.1.2 FID 99,9995%(),99,995%.(,).7.2 ,.().,-0,956-1,170-1,383-1,584-1,845-2,346 -2,559-DIPE 2,753-3,010-3,430 -ASTM D7754-16 14 (MTBE),-(ETBE),(DIPE),-(),-,-,-,-,-
12、,-(98%-99%).1 250/,7,5%200/.6 ,WCOT/PLOT,.2 7.3 2,2,4-.,-,-,-,-ASTM D7754-16 15 ,.,(.X1).(,.).7.4 1,2-(1,2-DME ).8.8.1 ,./.,D4057,.,.8.2 .9.9.1 ASTM D7754-16 16 ,.4.2.(.2),-.9.1.1 .1 2 -.9.1.2 .3 4 .9.2 ():9.2.1 .1.(6.3.1)(9.2.4),.,;.9.2.2 ,PLOT-.,.70,0,16 0,254 .9.2.3 .2,ASTM D7754-16 17 .,FID,31,0
13、,6,8/60.-,PLOT-,FID.9.2.4 ,.9.2.5 1 300/.20 ,10.3,5 .,.5 .,0,5 ,0,5 TAME .9.2.6 PLOT-.1 .2,.,.,PLOT-.9.2.5 9.2.5.,ASTM D7754-16 18 9.2.5,PLOT-.9.3 B():9.3.1 WCOT-PLOT-,.2,.,;.9.3.2 ,PLOT-.,(.2).70,0,16 0,254 .9.3.3 .2.200C.9.3.4 ,.9.3.5 .1 300/.20 ,10.3,5 .ASTM D7754-16 19 ,.5 .,0,5 ,0,5 TAME .9.4 C
14、():9.4.1 (CFT)(.3).EPC 5,4/,Aux EPC 1,6/CFT,7,0/.1,5.9.4.2 ,.TAME .9.4.3 EPC 4/(.4),AUX EPC 11/.,.,.7.9.5 5/,/ASTM D7754-16 20 5.8.(5/)2.1 .2./.7 WCOT/PLOT-,9.6 PLOT-,.220C,-138 .PLOT-,-,-,-,-ASTM D7754-16 21 60C,.25.(.13),.8 /,5/1,0%-(.2)10.10.1 D4307.-,-,-,-ASTM D7754-16 22 ,10/1000/250/.:8,3%-(),
15、10000/(),1000/(),2500/(D).,.10.2 .,99,9%.,D6304.10.3 3 12,7.2,50 ,0,1.1,2-DME .8,3%.2.=i-()/()100(2)10.4 1000/,500/250/.100 12 ,10.3,0,1,.3(10000/):ASTM D7754-16 23 ,I,/=W%i (Mi/Mt)104(3):W%i-i-10.3,(%),Mi-10.4,(),Mt-10.4,().10.5 100/,50/10/.100 1,2 ,10.3,0,1,.3(1000/).10.6 D 5%-5 1,2-DME 100,0,1,.1
16、,2-DME 4.100 4 ,.D 5(2500/).DME(M%DME)=DME()/Mt()100(4):M%DME-5%-DME,10.5,DME-DME ,Mt-.D,/=%DME (MDME/MDMET)104(5):%DME-5%-DME,MDME -5%-DME,(),ASTM D7754-16 24 MDMET-,().10.7 :10.7.1 .3 ,10/,50/,100/,250/,500/1000/.,1,0%,2,5%,5,0%,7,5%,10%15%.(/),.10.7.2 6 (/),.,.3.i-=Ci (MI/Mt)(6)Ci-i-,/,MI-,(),Mt-,().3./EtOH ()()EtOH()I-C8()()1000/15%11,00 15,00 74,00 100 500/10%5,50 10,00 84,50 100 250/7,5%2,75 7,50 89,75 100 100/5%11,00 5,00 84,00 100 50/2,5%5,50 2,50 92,00 100 10/1,0%1,10 1,00 97,90 100 AST
