1、 6228-2011 ASTM D6228-10 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Flame Photometric Detection(IDT)ASTM D 6228-10 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatogra
2、phy and Flame Photometric Detection,100 ,19428,.()6228-2011 II 1 Kaz Business Solutions.2 4 2011 517-.3 ASTM D 6228-10 Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Flame Photometric Detection(.),100 ,19428,.ASTM D 6228-10 D03.0
3、5 ASTM D03 .(en).(IDT).4 2016 5 5 ,-.(),.6228-2011 1 2012-07-01 1 0,02/3 (20,0,014 ppmv)20/3(20000,14 ppmv)0,01 3 (GC)(FPD)(FPD).FPD FPD.,.2 :1.9-2007 .,.ASTM D 1265-05*Standard Practice for Sampling Liquefied Petroleum(LP)Gases(Manual Method)().ASTM D 1945-03(2010)*Standard Test Method for Analysis
4、 of Natural Gas by Gas Chromatography().ASTM D 3609-00(2010)*Standard Practice for Calibration Techniques Using Permeation Tubes().ASTM D 4468-85(2006)*Standard Test Method for Total Sulfur in Gaseous Fuels by Hydrogenolysis and Rateometric Colorimetry().ASTM D 4626-95(2010)*Standard Practice for Ca
5、lculation of Gas Chromatographic Response Factors().ASTM D 5287-08*Standard Practice for Automatic Sampling of Gaseous Fuels()._*1.9 6228-2011 2 ASTM D 5504-08*Standard Test Method for Determination of Sulfur Compounds in Natural Gas and Gaseous Fuels by Gas Chromatography and Chemiluminescence().AS
6、TM 840-95(2005)*Standard Practice for Using Flame Photometric Detectors in Gas Chromatography().-15*Determination of Hydrogen Sulfide,Carbonyl Sulfide and Carbon Disulfide Emissions from Stationary Sources,40 CFR,Chapter 1,Part 60,Appendix A(,40 CFR,1,60,).-16*Semicontinuous Determination of Sulfur
7、Emissions from Stationary Sources,40 CFR,Chapter 1,Part 60,Appendix A(,40 CFR,1,60,).,.(),().,.3 :3.1 .,n-C10,i-C14.3.2 ,-MeSH,-DMS,-COS,-DtB-TS -THT .4 4.1 .,().,.().24 .,(.ASTM D 1265 ASTM D 5287)._*1.9 6228-2011 3 4.2 .1 3 ,.4.3 (FPD PFPD).,.().,.4.4 .(FPD PFPD).(GC),.4.5 GC.GC,(.ASTM D 5504),(.A
8、STM D 4468),.5 5.1 ,.,.5.2 ,1/4 (1/4 m),.,.5.3 .,(.ASTM D 1945).GC .6 6.1.,.6.1.1 .,50 ,.TFE()-,(FEP),316,.1,0 3 6228-2011 4 ,316 .,-.6.1.1.1 .FPD 1/2-,.6.1.1.2 .PFPD ,(,50:1).6.1.2 .6.1.3 .30 200,0,1 30.0,05 (3).6.1.4 .,.,1%.,69 .,552 .6.1.5.(FPD)(PFPD),.,4.4,(.ASTM 840).(PFPD)FPD.,.6.1.5.1 .,S2 62
9、28-2011 5(.1 2).,()(.3).6.1.5.2 (FPD)(FPD)393-,.FPD,106:1 .6.1.5.3 (FPD)FPD ,.,FPD.FPD 106,.(,).222SOnCOORS+(1)2222442SOHHSO+(2)hvSS+22 (3),hv-.6.1.5.4 .,.(RD)(S)(4)(5).n 2,0.RD Sn (4)Log S 1/n Log R (5),n-(1,7 2,0).6.1.5.5.1 103.6.2.,.6.2.1 FPD.60 0,53 ,5 .6.2.2 FPD.0.32-(,30 60).2,0/.6.2.3 ,7.3.,F
10、PD,1.,FPD 2.,.6.3 :6.3.1 ,0 1,2.6228-2011 6 6.3.2.:6.3.2.1 .6.3.2.2 .6.3.2.3 .7 7.1 .,.0,1 ,.,0,1%(.ASTM D 3609).7.2 .,.,.7.3 .,(99,999%).,.,.(.6.1.4).7.3.1 FPD FPD .,FPD 2,0/().7.3.2 ,;.7.3.3 PFPD.7.4.(99.999%).6228-2011 7 1-GC FPD 1,0 120 60 0,53 .5 ,11,0/,4 2,1.30 1,5,15/200,8 (FPD)H2/,250,20/,2-
11、GC PFPD 1 2 1,0 1500 1,0 1500 ;50:1 ;50:1 GS-GasPro PLOT,30 0.32 .J&W ,60 0,32 .2/2/60 2,20/260,5,17 50 5,5/200,0,1,35,1 (FPD)H2/,250,2 ,BG-12,R1924 PMT (FPD)H2/,200,2 ,BG-12,R1924 PMT .7.5 .(99.999%).,.6228-2011 8 8 8.1 .1(FPD)2(FPD).8.2 .,.8.2.1 (FPD)FPD ,.FPD .8.2.2 (FPD),.8.3 1,0 3 .13,3 133.,(6
12、):Sn=(Ps/Po)Cn (6),Sn-;Ps-;Po-;Cn-.8.4 .,8.3.(.D4626)(7):Fn=(Sn/An)Ln (7),Fn-;Sn-;An-;Ln ,.6228-2011 9 .(Fn)10%Fn .Fn 5%.,Fn .3 ,.3-%,37,78 H2S 34,08 94,09-60,3 COS 60,08 53,37-50,2 MeSH 48,11 66,65 6,2 214 EtSH 62,13 51,61 35,0 112 DMS 62,13 51,61 37,3 103 CS2 76,14 84,23 46,5 IPrSH 76,16 42,10 52,
13、6 61 TBM 90,19 35,55 64,0 41 NPrSH 76,16 42,10 67,0 35 MES 76,16 42,10 67,0 36 THT 88,17 36,37 120 4,6 di-EtS 90,19 35,55 92,0 DMDS 94,20 68,08 109,7 di-Et-DS 122,25 52,46 154,0 8.5.,.8.5.1 .,SO2.,.(FID)(TCD).FPD (),2 3.,.8.5.1.1.,(3),.,.,.,.8.6.1,2 3().6228-2011 10 1 4.,.,5%.9 9.1 :9.1.1 .3 .24 .9.
14、2 .GC,1(FPD)2(FPD).9.3 .(.8.6),(4)(.8.4).,24 5%.1-,FPD ,1.6228-2011 11 2-,FPD ,2,1.3-,FPD ,2,2.6228-2011 12 4-,1.RT,RT,RT,2.09 5,50 CS2 11,23 M-iPr-DS 2.20 5,80 iPrSH 11,62 DEDS 2.45 H2S 6,45 TBM 11,74 M-nPr-DS 2.55 COS 6,70 nPrSH 11,90 M-tB-DS 2.65 6,80 MES 12,35 DMTS 3.00 i-7,80 12,87 E-nPr-DS 3.4
15、0 n-8,25 DES 12,98 DiPr-DS 3.52 MeSH 9,00 DMDS 13,50 iPr-tB-DS 4.50 i-9,42 M-13,65 iPr-nPr-DS 4.75 EtSH 9,95 THT 14,35 DtB-DS 4.90 n-10,37 MEDS 14,55 DEt-TS 5.10 DMS 11,00 C27 17,15 DtB-TS 9.4 .,8.3 8.4 .9.5 .1,0 -8,3.,.,1(FPD)2(FPD).(),.,.5%.9.6 .,.10 10.1 (.(7),.6228-2011 13 ,.Cn=(An/Fn)(Po/Ps)/Ln
16、 (8),Cn-;An-;Fn-;Po-;Ps-;Ln ,.11 11.1 mv.ppmv().12 12.1 :12.1.1 ,.FPD 5 5-(FPD)ppmv COS 2,07 0,06 DMS 3,63 0,12 NPM 3,72 0,12 DMDS 2,00 0,06 THT 6,44 0,16 12.1.2 FPD().,.FPD 6.6228-2011 14 6-(PFP)()1 2 ppmv ppmv COS 4,16 0,05 5,37 0,11 H2S 3,59 0,10 4,64 0,11 DMS 3,63 0,09 5,14 0,10 1-3,22 0,05 3,86 0,07 662.753.1.001.4:006.354 75.160.20 :;,
