1、MEXTOCyAAPCTBEHHbI COBET no CTAHAAPTM3AUMN,METPONOrN CEPTONKALM(MrC)INTERSTATE COUNCIL FOR STANDARDIZATION,METROLOGY AND CERTIFICATION(ISC)FOCTMEXTOCyAAPCTBEHHbI33586-CTAHAAPT2015yrOJnb AKTMBMPOBAHHbIMCTaHAapTHbI MeToA NcbITaHHa acop6unio n3 ra3oBon a3bM3AaHne onnanbHoeMocKBaCCTaH,AapTHOpM2016FOCT33
2、586-2015npeAncnoBneLenn,ocHoBHble npnhyunbi n ocHoBHo nopagok npoBegeHn pa6ot no MexrocygapctBeHHon cTaH-AapTn3aun ycTaHoBneHbi OCT 1.0-92 MexrocyAapcTBeHHaA cncTeMa cTaHgapTn3aunn.OcHOBHblenonoeHMA n OCT 1.2-2009 MexrocygapcTBeHHaA ccTeMa cTaHAapTn3aun.CTaHAapTbi Mexrocy-AapcTBeHHble,npaBnna n peko
3、MeHAaunn no MexrocyAapcTBeHHon cTaHAapTn3aunn.paBnna pa3pa6oTkn,nHT,nMeHeHg,HBneH OTMeHbICBeAeHn o cTaHAapTe1 NOAFOTOBNEH egepanbHbiM rocyAapcTBeHHLIM yHNTapHbIM npeAnpnATneM BcepoccnickniHayqHo-nccnegoBatenbckn nHcTntyT cTaHgaptn3aynn MatepnanoB TexHonorn(中YN BHMM CMT)Ha ocHoBe co6cTBeHHoro ayTeHtn
4、4Horo nepeBoga Ha pycckn 3biK cTaHgapta,yka3aHHoro B nyHKTe 42 BHECEH egepanbHbIM areHTCTBoM no TexHn4eckoMy perynnpoBaHnio n MeTponornn(PoccTaH-AapT)3 7IPMHAT MexrocyAapcTBeHHbIM coBeToM no cTaHAaptn3aunn,MeTponornn u ceptu中nkaunn(npoToKon oT 27 oKT6p 2015r.Ne 81-)3a npHATe nporonocoBan:KpaTKoe Han
5、MeHoBaHne cTpaHbIKoA cTpaHblCokpaueHHoe HanMeHoBaHne HaLOHanbHoro opraHano MK(MCO 3166)004-97no MK(MCO 3166)004-97no cTaHapT3auBenapycbBYFoccTaHAapT Pecny6nnkn BenapycbKa3axcTaHFoccTaHAapT Pecny6nKn Ka3axcTaHKpr3AKbiprb3cTaHAapTPOCCHARUPoccTaHAapTTaKcTaHTJTaAKCTaHAapT4 puka3oM egepanbHoro areHTcTBa
6、no TexHn4eckoMy perynnpoBaHnio n MeTponornn oT 17 MapTa2016 r.Ne 173-ct mexrocygapctBeHhbii ctaHAapt OCT 335862015 BBeAeH B AeictBne B Ka4ectBe HaLno-HanbHoro cTaHAapTa Pocccko egepaunn c 1 anpen 2017 r.5 HacToAun cTaHAapt nAeHtn4eH cTaHAapty ASTMD 5160-95(Reapproved 2008)Standard Guidefor Gas-Phase
7、 Adsorption Testing of Activated Carbon(CTaHAapTHoe pykoBoAcTBo no ncnbITaHnio aKTBnpo-BaHHbx yrnen Ha acop6o 3 ra3oBo a3b).CTaHAapt pa3pa6oTaH KoMnTeToM ASTM D28 AKTnBnpoBaHHbi yronb,n HenocpeAcTBeHHyo OTBe-TCtBeHHOCTb 3a pa3pa6oTky MeToga Hecet nogKoMnteT D28.04 MeToAbi aHann3a ra3oBon pa3bi.epeBo
8、g c aHrnckoro 3bika(en).HanMeHoBaHne HacTo山ero ctaHAapTa n3MeHeHO oTHOcnTenbHO HanMeHoBaHnA yka3aHHoro cTaHAap-Ta ng npuBegeHug B cootBeTctBne c OCT 1.5-2001(nopa3gen 3.6).O中nunanbHble 3k3eMnngpbi cTaHgapta ASTM,Ha ocHoBe koToporo nogrotoBneH Hactogun Mexrocy-AapctBehhbi ctahgapt ASTM,u ctahAaptoB,H
9、a KoTopble gahbi ccbinkn,MelotcA B hayoHanbHbIX opraHaxno cTaHAapTn3au.CBeAeHA o cooTBeTCTBnN MexrocygapcTBeHHbIX cTaHAapToB ccbIno4HbIM cTaHAapTaM npnBeAeHbI BAononHTenbHoM npnoeHA.CTeneHb cooTBeTctBng-AeHT4Ha(IDT)6 BBEAEH BNEPBbIEFOCT33586-2015MHpopMauu o6 u3MeHeHuAX K HacmouweMy cmaHdapmy ny6nuky
10、emc e exe2odHOM uHopMauuoH-HoM yKa3amene HaquoHanLHbIe cmaHdapmbi,a meKcm u3MeHeHuuu nonpaeoke exeMecA4HoM uHpop-MaquOHHOM yKa3amene HaquoHanLHbie cmaHdapmbi.B cny4ae nepecMompa(3aMeHbi)unu omMeHbIHacmouwe2o cmaHdapma coomeemcmeyiowee yeedoMneHue 6ydem ony6nukoeaHo e exeMecA4HOMuHpopMayuOHHOM yKa3am
11、ene HauoHanLHbIe cmaHapmbi.CoomeemcmeyioaR uHpopMayuA,yee-doMneHue u mekcmbi pa3Meuaiomc makke e uHpopMayuOHHOu cucmeMe o5we2o nonb3oeaHu Ha ocpu-quanLHoM caume PedepanLHo2o a2eHmcmea no mexHu4eckoMy pe2ynupoeaHuio u Memponozuu e cemuHmepHem CTaHAapTHopM,2016B Poccnicko egepaynn hactou ctaHAapt he m
12、oxet 6bitb nohoctbio unn yactn4ho Bocnpon3Be-AeH,TpaxnpoBaH n pacnpocTpaHeH B ka4ecTBe onnanbHoro n3gaHnA 6e3 pa3peweHnA eAepanbHoroareHTcTBa no TexHnueckoMy perynupoBaHo MeTponornnFOCT 33586-2015ME KTOC YA APC TBEHHbIMC TAHAAPTyrOnb AKTMBMPOBAHHbIMCTaHAapthbIN MetoA ucnbitahun ha agcop6unio n3 ra3o
13、Bon 中a3biActivated carbon.Standard method for gas-phase adsorption testingAaTa BBeAeHn-2017-04-011 06nacTb npMeHeHg1.1 HactoAwn ctaHgapt otHocntcA K agcop6ynn aKtnBnpoBaHHbIM yrneM KOMnOHeHTOB n3 ra3oo6-pa3Hoi cpeAbi n yctaHaBnnBaet Metog onpegeneHng gnHaMnyecko aKtuBHoctu(N,)u npeAenbHo AnnHbicnog
14、aKtBpoBaHHoro yrng(d),cnonb3yemoro Ang yAaneHng onpegeneHHoro agcopoata 3 ra3oBoronoToka B ycnoBx,ycTaHaBnBaeMbix nonb3oBaTeneM.1.2 B HacTogeM cTaHgapte Bce eAHnLbI 3MepeHnA npuBegeHbi B cncTeMe CM.Apyrne eAnHnbi3MepeH B HacTo cTaHAapT He BKno4eHbI.1.3 B HacToAueM cTaHAapTe He npeAycMoTpeHo paccMoTp
15、eHe Bcex BonpocoB o6ecne4eHnA 6e3onac-HOCTM,cBA3aHHbix c ero nchonb3oBaHNeM.NoNb3oBaTeb ctaHgapta HeceT OTBeTCTBeHHOCtb 3a o6ecneye-HMe cooTBeTCTByHOX Mep 6e3onacHOcT n oxpaHbI 3AopoBbA onpegengeT Lenecoo6pa3HOcTbnpMeHeHng 3aKoHogaTenbHbiX orpaH4eHn nepeg ero cnonb3oBaHeM.XapaKTepHbie onacHOCTnpBege
16、Hbl B pa3gene 7.2 HopMaTBHble ccbInKnAng npnMeHeHng Hactogwero ctaHgapta Heo6xognMbi chegyiowe ccbino4Hble gokyMeHTbi.AnHeAaTpoBaHHbIX ccbinoK npMeHgioT nocneAHee 3AaHne ccbino4Horo gokyMeHTa(BKno4ag Bce ero3MeHeH).2.1 CTaHAapTbI ASTM1)ASTM D 2652 Terminology Relating to Activated Carbon(TepMnHonorn
17、g,oTHocqwagc K aKTnBpo-BaHHoMy yrno)ASTM D 2854 Test Method for Apparent Density of Activated Carbon(MeTog onpegeneHA HacbinHoinnoTHocT aKTBpoBaHHoro yrng)ASTM D 2867 Test Methods for Moisture in Activated Carbon(MeTogbi onpegeneHnA Bnarn B aKTnBn-poBaHHoM yrne)ASTM D 3467 Test Methods for Carbon Te
18、trachloride Activity of Activated Carbon(MeTogi onpege-neHg aKtBHoct aktuBpoBaHHoro yrng no yetbipexxnopucToMy yrnepogy)ASTM E 300 Practice for Sampling Industrial Chemicals(paKTnka oT6opa npo6 npoMbIWNeHHbIXXnMM4ecknx npoAyKTOB).1)YTOHNTb cCHInkn Ha cTaHgapTb ASTM MOKHO Ha caite ASTM:www.astm.org n
19、w B cnyx6e nogepxknknneHTOB ASTM:serviceastm.org.B nHpopMaynOHHOM ToMe exerogHoro c6opHnKa craHgapToB(Annual Book of ASTMStandards)cneAyer o6paw,aTbca K cBoAKe cTaHgapToB exeroAHoro copHnKa cTaHAapToB Ha cTpaHnue cavTa.M3aHne onunanbHoeFOCT 33586-20153 TepMHbI n onpeAeneHng3.1 OnpeeneH:3.1.1 npockok
20、(breakthrough):oABneHne B appnioeHTe agcop6npyeMoro BewecTBa B oroBopeHHo3apaHee KoHueHTpaunn.3.1.2 OcTanbHble TepMnHbi,ncnonb3oBaHHble B HacToAweM cTaHgapte,onpegeneHbi B ASTM D 2652.4 CyHOCTb MeToAa4.1 Yepe3 cno aKtuBnpoBaHHoro yrng,KonnectBo kotoporo n3BectHo,nponyckaiot ra3oBbi notoK,cogepxauu a
21、ncop6npyemoe BewectBo(acop6at).YcnoBn ncnbitaHnA,a nMeHHO:ckopOctb notoka ra3a,KOHLeHTpayng agcop6npyemoro BeecTBa B 3Tom notoke,TeMnepatypa,gaBneHMe,oTHOcnTenbHagBnakhoctb ra3oBo cpeAbi,yctaHaBnBaloTcA n KoHTponupyiotcA onepaTopoM.V3MepAot BpeMg,npoweA-wee o haana ucnbiTaHn go npockoka bitaHne noBt
22、opiot B Tex xe ycnoBnAx,Ho np ApyroMkonn4ecTBe aktuBupoBaHHoro yrng.An 6onbworo konn4ectBa npakTn4ecknx ccTeM 3aBnCMOCTb BPeMeHMnpockoka of konnuectBa agcop6eHta oTo6paxaetc npAmou nnHne.HaknoH 3to npaMo,a taoke 3Ha-eHng,onpegengeMble Ha ocn aocuncc,ncnonb3yioT Ang BbicneHng TaKnX xapakTepncTnK aKTB
23、poBaHHo-to yrng B ycnoBngx ncnbitahng,kak gnHamnyeckag aKtnBHOctb N,(BbipaxeHHag B rpamMax agcop6ata Ha 1 ragcop6eHta nnn B rpamMax agcop6ata Ha 1 cm3 agcop6eHta)u npegenbHag AnnHa cnog aKtBpoBaHHoroyrna de5 Ha3HaeHe n npuMeHeHne5.1 AKTuBnpoBahHbin yron wnpoko ncnonb3yetcA An o4nctkn Bo3gyxa n Apyrn
24、x ra3oB ot ra3oo6pa3-HbIx npnMecenapoB.progHoctb aKtnBnpoBaHHoro yrngn to n Ho yennB 3HayntenbHon cteneHonpegengetc ero 中u3n4ecknMn n XnMn4ecknMn cBoMcTBaMn.MeTog,pernaMeHTpyeMb HacTOAL(McTaHAapToM,no3BongeT onpegennTb AnHaMn4ecKne agcop6MOHHble XapaKTepcTnKn aKTBpoBaHHoroyrng no otHoweHnio k otgenb
25、Homy agcopoaty npn onpegeneHHbix ycnoBnAx.YcnoBg npoBegeHng ncnbiTa-huA Aoxhbi 6bitb pn6nxehbi k ycnoBnAM,B Kotopbix ncnoNb3yiot aktnBnpoBaHhbin yronb(cM.pa3gen9).5.2 HacTow ctaHgapt Moket 6bitb Takke cnonb3oBaH An 3y4eHnA BO3MOKHOCtn noBbiWeHng3ppeKtuBHoCT aKtnBnpoBaHHbix yrnen npu o4nctke oT nnoxo
26、 acop6npyeMbix ra3oB nyTeM Hacbi山eHnAaKTBpoBaHHbx yrnen ApyrM BeecTBaM.5.3 Hactogu ctaHgapt he npuMeHnm Ang oehkn katanntn4eckoro gectBng yrne ha npoueccbipa3noeH 030Ha n okncneH SO2 4o SO3.5.4 门pouegypbi,pernaMeHTpoBaHHble HacTouM cTaHgapToM,MoryT 6bITb ncnonb3oBaHbi B npo-Leccax BoccTaHoBneHng aKT
27、BHOcTn n pereHepaun aKTnBpoBaHHbix yrnen.5.5 Ha pucyHke 1 n3o6pakeH npounL KoHLeHTpaunn agcop6npyeMoro BeecTBa B cnoe aKTBnpo-BaHHoro yrng.B Ha4ane cnog cyectByeT 3oHa,B KoTopon KoHLeHTpaung ancoponpyeMoro BeecTBa paBHaero KoHeHTpann Bo Bxogauem notoke ra3a.B 3Ton 3oHe gOctrHyTo paBHoBecne npouecca
28、agcopounn.B ocTaBweMcA cnoe ancop6eHTa,BnnoTb go caMoro KoHLa,KOHLeHTpanA ancoponpyeMoro BeecTBaBngetcA KoHeHTpalen npockoka Ang gaHHoro ce4eHn cno agcop6eHTa.YeM kopo4e 3oHa MacconepeHo-ca(3oHa agcopou),TeM Bbiwe 3eKTBHOCTb cnonb3oBaHnA cnoA agcop6eHTa.Ecn AnHa cnogagcop6eHTa MeHbwe AnMHb 3oHb Macc
29、onepeHoca,To npockok agcoponpyeMoro BewecTBa Ha BbixogeHa6nogaeTc B nepBon e nopu 3noeHTa.5.6 Cto4kn 3peHng 3ppetuBHoctn ncnonb3oBahng Ang kaxkqbix ychoBn cnegyet nog6npatb aktnBn-poBahHbi yronb c 3oho MacconepeHoca HanMeHbwe Arnhbi.OAHako,Bo MHornx cny4agx 6onee BaxHbIMaKTopoM BngeTc Bbicokag agcop
30、onoHHag cnocoHoctb aKtBpoBaHHoro yrng,a He gnnHa 3oHb Mac-conepeHoca.out Bcerga pewaiowee 3Ha4eHe Meet nepenag gaBneHn B choe agcop6eHTa.5.7 B HeKoTopbix cny4agx,HanpnMep,npu ncnonb3oBaHnn aKtuBnpoBaHHbix yrneB pecnupatopax,Ang3aW(MTbI OT cBepXToKcn4HbiX ra3oB,TaknX kaK paAoaKTBHbi MetnnoAng,Manag qnnHa 3oHbi Macconepe-Hoca(T.e.Bbicokn ko3p中neHt ckopoctu agcop6yn)gBngeTcA 6onee BaKHbIM 中aKTOpoM,yeM MaKC-ManbHag agcop6ynoHHag cnoco6HocTb.B Apyrnx cny4agx,Hanpnmep,Ang pereHepaunn pactBopnteng,Hanonbwee 3Ha4eHne Meet Bbicokag HaMn4eckag aKtBHOctb acop6eHTa.2
