1、 D530319 STANDARD TEST METHOD FOR TRACE CARBONYL SULFIDE IN PROPYLENE BY GAS CHROMATOGRAPHY 2020 ():07.05.2020:3872-20/ASTM -,.9,119049.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM Internat
2、ional ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM In
3、ternational does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,except for ASTM International or FBU“
4、CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D530319 1 D530319 1 D5303;,.().1.1.1 ().0,5/4,0/().1.1 ,0,1/,.0,5 4,0,.1.2,.1 ASTM D02 ,D02.D0.03 .1 2019.2019.1992.2012.D5303-92(2012).DOI:10.1520/D5303-19.ASTM D530319 2 1.3 ,.,.8.1.4 -,(TT).
5、2.2.1 ASTM:2 D3609 D4468 E840 3.3.1 ,2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.ASTM D530319 3 .3.2 ,10 C 50 C,.3.3 ,.3.4 .4.4.1 C3 ,.,.4.2 .,.4.3 ,.ASTM D530319 4 ,.5.5.1 (H2S)(SO2)(.2).2 H2S SO2 Carbopack BHT 100 Chromosil 300.6.6.1 (),/(),.6.2./,.6.2 ,.(.6.5).0,1/.E8
6、40.,10-12 A 1 ,.3 ,.0,04/(30 ppbMol /).6.3 ,ASTM D530319 5 .,1.6.4 -,5,0 .6.5 c 1,2 0,5/.1 A ,B ,C 1 0,9 3,78.Porapak R,80/100;47 2 1,4 3,78 C Carbopack BHT 100,40/60;25,40D 3 1,8 3,78 Carbopack BHT 100;25,30D 4 1,8 3,78 Porapak Q,AW,50/80 2,4 3,78 ();74 5 2,4 3,78.Carbopack BHT 100;47 6 2,8 3,78 Ca
7、rbopack BHT 100,40/60;50 7 3,6 3,78 Carbopack BHT 100,40/60;50 8 4,3 3,78 Chromosil 300;50E 9 6,1 3,78 Hayes Sep Q,80/100;65 A .B 316 .C .D ,.E ().6.6 ,(uVs).ASTM D530319 6 ,.6.7 ,300 ,DOT 3E,12409 (1800 .).7.7.1,.7.2 (),97,5%.(!.8 .)7.3 ,1/10/,/.-,X1 D4468.7.4 ,0,1,1,0 5,0.7.5-,316.B 1.7.6 ,125.7.7
8、,99,9%.7.8 (2,2,4-),99.%.(!).7.9 ,99,999%.7.10-.8.8.1 .ASTM D530319 7 .9.9.1 ,-,.9.2 .4 ,.9.3 .9.3.1 -316 ,.,.5/10/,(.5).-15.5 ,.9.3.2 .ASTM D530319 8 ,.10.10.1 ,.6.3.:10.1.1 ,10.1.2,100 C 200 C,10.1.3,100 C 150 C.11.11.1 :(.11.2),(.11.3)(.11.4).,.,.12.1 12.4,.11.5.11.2 10/,/.,.,.,1,0,0,5/5/.,10/,AS
9、TM D530319 9 .1,0 :,/0,05 0,5 0,10 1,0 0,20 2,0 0,30 3,0 0,40 4,0 0,50 5,0 11.3 .D3609.11.4 X1 X2.,D4468.,.11.5 ,./,.,F,1:F=C/A(1):F-,C-,/,A-(uVs).ASTM D530319 10 F 2 .13.1.1.,.11.5.1 .11.5.2:11.5.1 (),X3,(1n)1n(),2 .1.11.5.2 ,/.12.12.1 -,.9.3,.12.2 .12.3,.12.4 .2 Carbopack BHT-100.ASTM D530319 11 2
10、 A 1 (3,00 S/3).(3)(S)yB()3,0 9,0 53 3,0 9,0 51 2,5 7,5 39 2,5 7,5 38 2,0 6,0 25 2,0 6,0 23 1,5 4,5 18 1,5 4,5 16 1,0 3,0 10 1,0 3,0 9 0,5 1,5 3 0,5 1,5 4 A (r)=0,9952:m ()=1,4920,y ,z ,b ,=1,8394.B :y=bzm.1 ()()ASTM D530319 12 1 Carbopack BHT-100.2 13.13.1 (.11).13.1.1 ,2:,/=F S(2):F-1,S-(uVs).13.1
11、.2 ln 1n()(.11.5.1),X1.(0,9/)ASTM D530319 13 13.1.3 log (.11.5.2),:13.1.3.1 log .13.1.3.2 ,log .13.1.3.1.6 ,3/3(ppm ),D4468,/:,/=B M1/M2(3):B-,3/3,M1-=60,1,M2-=42,1.14.4.1 :3 14.1.1 ,(.14.1.2):=0,15 X(4):X-/.3 ASTM International RR:D02-1298.serviceastm.org.ASTM D530319 14 14.1.2 ,(.):=1,0 X(5):X-/./
12、0,5 0,11 0,7 1,0 0,15 1,0 2,0 0,21 1,4 3,0 0,26 1,7 4,0 0,30 2,0 14.2 ,(D5303).15.15.1;ASTM D530319 15 ()X1.X1.1 :X1.1.1 100 (iCr).0,5 .6,3 S/,:X1.1.2 ,P1V1/T1=P2V2/T2.:30 C,740 ./iCr=69,2:V2=P1V1T2=760 .22400 303 =25533/(X1.1)P2T1 740 .273 60 1 0,5 =1,175 10-3 =0,63 10-3 S(X1.2)25533 0,63 10-3 S=9,
13、1 10-6 S (X1.3)69,2 9,1 10-6 S=0,6919 10-3 iCr=6,30 10-9 S=6,3 n S/(X1.4)iCr X1.1.3 ,.X2.X2.1 X2.1.1,980.X2.1.2 ,.X2.1.3 .X2.1.4.ASTM D530319 16 X2.1.5 .X2.1.6 .X2.2 X2.2.1.X2.2.2.X2.2.3,.X2.3 X2.3.1 980-,20 500/.X2.3.2 10 .X2.3.3 ,()1 .5.X2.3.4 ,.X2.3.1 X2.3.3,1 .0,527/.X2.3.5 ,.X3.X3.1 S/:y=1,8394
14、 z(X3.1)y 3 53(.2)5 29.:ASTM D530319 17 29=1,8394 z(X3.2):z=6,35 S/5 =1,27 S/.X3.2 1,44/(),:,=42,1/:740 .,30 C :1,27 S/=2,38 /:1 (X3.3):PV-nRT=(/)RT P-,V-,MW-/,R-=82,05 /K,T-K=303,=PV(MV):(X3.4)RT =(740 .)(1)(42,1/)=1,65 10-3 760 (82,05 )(303)/=2,38 10-9 =1,44 10-6 106=1,44(X3.5)1,65 10-3 D02.D0 (D5303-92(2012),.(1 2019.)(1)3.ASTM D530319 18 ASTM International -,.,.,.-ASTM International.,.,.ASTM International,100 Barr Harbor Drive,West Conshohocken,PA 19428.610-832-9585,610-832-9555 E-mail:serviceastm.org ASTM:(www.astm.org).,222 Rosewood Drive,Danvers,MA 01923,Tel:(978)646-2600;http:/.
