1、 D 5017 96(2009)1 ()-13 STANDARD TEST METHOD FOR DETERMINATION OF LINEAR LOW DENSITY POLYETHYLENE(LLLDPE)COMPOSITION BY CARBON-13 NUCLEAR MAGNETIC RESONANCE :1237-10/ASTM :22.06.2010 2010 (ASTM International),100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-
2、,ASTM International ,.This translation is executed by FGU“CIC“Interstandard”Federal Agency on Technical Regulating and Metrology under the license American Society for Testing and Materials(ASTM International),100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and
3、 does not confirm these translations,and in any case only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,except for ASTM International or FGU“CIC“Interstandard”,is strictly fo
4、rbidden according to the USA legislation and international copyright.-,.9,-49,-1,119991.:(495)236-54-49:(499)230-13-72 E-mail:interstgost.ruhttp:/www.interstandart.ru ASTM D 5017-96(2009)1 D 5017 96(2009)1 ()-131 D 5357;,.().1 2009.1.1.1 ,()-1.,-1,-1,-1 4-1.1.2 ,EEXEE,EXEXE,EXXE,EXXXE EEE,E ,X -1.,1
5、 ASTM D20 D20.70 .1 2009.2009.1991.2003.D 5017-96(2003)1.DOI:10.1520/D5017-96R09E01.3ASTM D 5017-96(2009)1 -1(,XXX),.1.3 ,.,.8.1 ISO .2.2.1 ASTM:2E 177 ASTM E 386 ,-()E 691 3IEEE/ASTM SI-10 :3 3.3.1 ,IEEE/ASTM SI-10 E 386.:2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.3 -A
6、STM,100 Barr Harbor Drive,C700,West Conshohocken,PA 19428.4ASTM D 5017-96(2009)1 3.2:3.2.1 13C -13,3.2.2 ,3.2.3 T1 3.2.4 TR .3.3 :3.3.1 ,4.CH,1.,1.3.3.2 ,.,-,8+-,4-.4.4.1 -13.4.2 ,.co .4 Carman,.J.,Harrington,R.A.,Wilkes,.1977,10,.536.5ASTM D 5017-96(2009)1 1 (P)M1-1(B)E1-E2-1(H)B1-B4 4-1(MP)IB1-IB3
7、-1(O)H1-H6 5.5.1 .,-1,-1,-1 4-1.6.6.1-,13C ,2,35 T.2 32 50 0,5 .6.2 5 10.3 .,10.1,9.4 -7.7.1 1,2,4-,7.2 -p-.20%,5 Wilmad .6ASTM D 5017-96(2009)1 7.1 .8.8.1!.9.9.1 ,90 9.2 ,10 9.3 ,130C 4 -(/)6.9.4 -,5000:1 5 -2,5 30,0-1(),50 70-1.-.9.5 ,175-19.6 (F1),50 55-19.7,2()Hz 9.8 ,4 ,19.9 ,6 ,4,6,7.6 Vidrime
8、,D.W.,Peterson,P.E.,48,1976,.1301.7 Randall,J.C,9,247,1984.7ASTM D 5017-96(2009)1 10.10.1 1,2 10-.1,5 (7.1)1,3 (7.2).7 9.4 -.10.2 150C 3 4.10.3 9.10.4 -10 15 130C.10.5 ,9.10.6 10 50-1.,50%.,.8 ,9.4 -,.13.1 .8ASTM D 5017-96(2009)1 11.11.1 1.11.2 ,A2,-1.11.3 A3 -11.1 11.2.9 (10)(90),(1),2.50 8,9.A4 ()
9、(TR),4.TR A2.T1 ,50.11.4 -1(%)1000 (:Br/1000C)A5.12.12.1 11.2 1000 11.4,.8 Farrar,T.C,Becker,E.D.,2,Academic Press,New York,1971.9 Cheng,H.N.,Bennet,M.A.,188,1987,.2665-2677.9ASTM D 5017-96(2009)1 13.10 13.1 2 (1988 E691),9-6-.,.(!:r R(13.2-13.2.3).2 .,.,.,E 691,.,13.2-13.2.3,.)13.2 r R Sr SR 1)2),:
10、13.2.1 ,r .r ,10 -ASTM.RR:D-20-1192.10ASTM D 5017-96(2009)1 ,.2 -13%Co ,%ArV BRV Cr DR A 4,72 11,1 11,5 31,1 32,2 B 4,22 11,9 11,9 33,3 33,3 C 3,64 17,1 18,2 47,9 51,0 D 4,03 14,3 14,3 40,0 40,0 E 5,18 10,3 10,3 28,8 28,8 F 0,76 27,5 40,6 77,0 113,7 G 4-5,00 14,0 14,8 39,2 41,4 H 4-1,26 37,4 38,2 10
11、4,7 107,0 I 15,96 7,3 7,6 20,4 21,3 A Vr .:Sr=(s1)2+(s2)2.+(sn)2/n1/2Vr=100 (Sr,).B VR ,.C r =2,8 Vr.D R =2,8 VR.13.2.2 R(,),R .13.2.3 ,13.2.1 11ASTM D 5017-96(2009)1 13.2.2,95%(0,95).13.3 ,.14.14.1 -13;.12ASTM D 5017-96(2009)1 ()A1.,A2.A2.1 -A2.1.1 :Pl=:(2+B)/2(A2.1)(2.1)P2=CH-:2A+H(2.1)P=:(Pl+P2)/
12、2(2.1)A2.1.2 :E=(C+D+E+F A)/2(2.2)=100%(P+E)(A2.2)(2.2)A2.2 -1 A2.2.1 -1:B(2.3)B1=:(2+B)/2 (A2.1)B(2.3)B2=CH-:(A+2C+2B)/4 B=-1:(B(2.3)B1+B2B)/2 A2.2.2 :E=(2D+2E+2F A B)/4(2.4)-1=100%B/(B+E)(A2.2)(2.4)13ASTM D 5017-96(2009)1 A1.1 ,-1-A 47,5 44,5 39,8 36,8 35,5 32,5 C+D+E 35,5 25,8 F 25,8 23,8 G 22,5
13、18,5 H 21,6-1 A 41,5 38,5 A 39,4 37,8 36,8 36,0 33,2 D+E 33,2 25,5 F 25,2 24,0-1 A 41,5 40,5 40,5 39,5 39,5 37,0 D 35,8 D+E 36,8 33,2 F+G 33,2 25,5 G 28,5 26,5 H 24,9 24,1-1 A 41,5 40,5 40,5 39,5 39,5 37,0 D Peak at 35,8 D+E 36,8 33,2 F+G+H 33,2 25,5 H 28,5 26,5 I 25,0 24,0 P 24,0 22,0-4-1 A 46,5 43
14、,5 43,0 41,8 41,8 40,5 D 37,5 34,2 E 33,7 F+G 33,2 25,2 G 28,0 25,2 H 24,1 30,0-1.A2.3 -1 A2.3.1 -1:H1=:1,5A+2B+(D+E)D/3(A2.1)(2.5)H2=CH :(A+2C+2D)/2(2.5)14ASTM D 5017-96(2009)1(2.5)=-1:(H1+2)/2 A2.3.2 :E=(F+G)3 3 G /2+(2.6)-1=100%H/(E+)(A2.2)(2.6)A2.4 -1 A2.4.1 -1:O1=:(A+2C+2D)/2 (A2.1)(2.7)O2=CH-:
15、1,5+2B+(D+E)D)/3(2.7)O=-1=(O1+O2)/2(2.7)A2.4.2 :E=(F+G+)(3+3+I)/2+(2.8)-1=100%O/(O+E)(A2.3)(2.8)A2.5 -4-1 A2.5.1 4-1:MP1=+CH :=(2B+D+1,5E)/3(2.9)MP2=CH2-:A(2.9)MP=4-1=(MP1+MP2)/2(2.9)A2.5.2 :E=(F+G)(2B+1,5E+G+H)/2+1,5MP(2.10)5 4-1=100%MP/(MP+E)(2.10)A2.1 -CH ,-CH-.A2.2 .:15ASTM D 5017-96(2009)1 =(4
16、1400)/Mn Mn=.A2.3 -1 =(6 1400)/Mn.A3.-A3.1 A-1 A0,0 0,2 8,1 D 0,6 D+E 26,8 F+G+H 343,6 H 24,8 I 0,6 P 7,9 A3.1 (3.1)A3.2 (3.2)A3.3 (3.3)A3.4 (3.4)A3.5 (3.5)16ASTM D 5017-96(2009)1 A3.6(100)O 898.0 1=O+E=173.11=5.19(A3.6)A3.7(1)(1000)5190 1000 C=2()+4()=2(94.81)+8(5.19)=22.41(A3.7)A4.-1 1000 A4.1 1000 =1000(co)2()+n(co)n .17ASTM D 5017-96(2009)1 ()X1.X1.1 -,-1 A 90 4.B .30,0-1.X1.2 -1 ,-1 A 90 4.B .30,0-1.X1.3 -1 ,-1 A .B 30,0-1.18ASTM D 5017-96(2009)1 X1.4 -1 ,-1 A .T1.B 30.0-1.X1.5 -4-1 ,-1 A .
