1、 D 412806(2012)C -STANDARD GUIDE FOR IDENTIFICATION AND QUANTITATION OF ORGANIC COMPOUNDS IN WATER BY COMBINED GAS CHROMATOGRAPHY AND ELECTRON IMPACT MASS SPECTROMETRY 2014 ():2260-14/ASTM :03.02.2014 -,.9,-49,-1,119991.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/
2、(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Mat
3、erials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduct
4、ion of the specified translations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D 4128-06(2012)1 D 412806(2012)-1 D 4128;,.()1.1.1 /-(GC-MS)(),.,1 .,(),(b),1 ASTM D19 D 19.06 .15 2012.2012.
5、D 4128-82.2006.D 4128-06.DOI:10.1520/D4128-06R12.ASTM D 4128-06(2012)2 (GC).,.,.1.2 ,D 3871,D 3973 GC-MS /,.2 1 .,GC-MS,.(SIM).(IDE)(IQE),D 6091 D 6512.1.3 ,.,.1.4 ,.2 624 8360()U.S.EPA 625 8270()U.S.EPA .ASTM D 4128-06(2012)3 1.5 ,.2.2.1 ASTM:3 D 1066 D 1129 D 1192 D 1193 D 2908 -D 3370 D 3694 ,D 3
6、871 ,D 3973 D 5175 D 5316 1,2-1,2-3-4 3 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.ASTM D 4128-06(2012)4 D 5317 D 5789 (2002.)4 D 6091 99a?%/95a?%-D 6512 260 ()355 2.2 :SW-846 8270c (GC-MS)5,6 SW-846 8260b (GC-MS)5,6 I,EPA/600/4-90/020,19905 II,EPA/600/R-90/129,19905 3.3.
7、1 ,.3.1.1 ,4 www.astm.org.5 (NTIS),5285 Port Royal Road,Springfield,VA 22161.6 SW 846 http:/www/epa.gov/epaoswer/hazwaste/test/main.htm.ASTM D 4128-06(2012)5 GC,.3.1.2 ,-,.3.1.3 ,-.(,).3.1.4 :(1),(2)-.,.,-10%(100%);ASTM D 4128-06(2012)6 20%.(,50%,30%70%).-,-.3.1.5 ,GC,-,.3.1.6 (.1)(RGC)RGC ,.,-.1.RG
8、C .:,.3.1.7 ,-,.,.ASTM D 4128-06(2012)7 .3.1.8-(.2)-,-,.RGC,.-.2.,-.:-,-.3.1.9 -,.-,.3.2:3.2.1 ,.D 1129.,.355.4.4.1 GC-MS -.-,.ASTM D 4128-06(2012)8 .-.,-.5.5.1 ,.6.6.1 ,GC-MS.:,.,GC-MS .6.2 ,.,.6.3 ,GC,GC,.ASTM D 4128-06(2012)9 6.4 GC,-.,.6.5 ,-.,-.-,.,.7.7.1 GC-MS/DS.,-,.7 GC-MS .GC-MS ,.7.2,7 GC-
9、MS GC-MS/DS.ASTM D 4128-06(2012)10 .2 1-(Kuderna-Danish).-,D 3973.7.3 GC-MS -.D 3871 524.2.7.4,10.8.8.1 .,8.-,-,.9 (),.,8 ,DC.,.,BDH Ltd,Poole,Inc.(USPC),MD.9 .ASTM D 4128-06(2012)11 ,.8.2 ,I II,D 1193.,.8.3 ;.8.4 -,EPA/NIST/NIH -.10 GC-MS/DS ,.,.,.,-.10 -(-,2-.,1978),P.O.Box 1508,East Lashing,MI 48
10、826,(44),1220 L St.,N.W.,DC 20005,MD 20899,Willey Interscience,John Willey and Sons,605 Third Ave.,-,NY 10158.ASTM D 4128-06(2012)12 8.5 .GC .(.3).ASTM,D 5175,D 5316,D 5317 US EPA.GC,D 2908.3.8.6 :8.6.1.8.6.2 11.8.6.3-().8.6.4 (DFTPP).8.6.5 (BFB)/8.6.6 .8.6.7.8.6.8.8.6.9-2-.9.9.1:,.,./-11 American C
11、yanamid,P.O.Box 400,NJ 08540.ASTM D 4128-06(2012)13 .,.,.10.,10.1 D 1066,D 1192,D 3370,D 3694.10.2 :10.2.1 .,.12 :10.2.1.1 (.D 2908).10.2.1.2 -(,).1 ,2-,1-.-(.D 3871).10.2.1.3 ,.GC(.D 3973 524.2).10.3 .,;12 Analytical Chemistry,.ASTM D 4128-06(2012)14,D 3694.10.4 ,260.11.GC-MS 11.1 ()11.1.1 11.1.2 ,
12、GC-MS,.RGC,GC,4:1.-,GC,.,(1).13 25/.2 .11.1.1 ,-(),.11.1.2 ,-2-.25/.2 .11.2 :11.2.1 125 :,-()100-13 ,.ASTM D 4128-06(2012)15,0,0001.11.2.2 2 .25/.11.2.3 120 ,4.,4 .1 ,25/,.1-.11.3 :11.3.1 1 .11.3.2 .11.3.3 40 .11.3.4 25 :-2-,.11.3.5 10.11.3.6 .11.3.7 ,:-2-=25,7/=22,1/=19,6/11.3.8 ,ASTM D 4128-06(201
13、2)16 4.11.4 ,-,D 3973 .11.5 ,.12.12.1 (),.,.,.12.2.GC-MS .-(,.),-.-,.,.,(DFTPP).ASTM D 4128-06(2012)17 .,.12.3 :12.3.1 .12.3.2 .,.12.4 GC-MS:12.4.1 ,.-(UHP).12.4.2 GC-MS.,-.20 .12.4.3 -.70 (5-10).13.13.1 .GC MS ASTM D 4128-06(2012)18 GC-MS,-.-,GC.,.13.2 ,GC-MS,-GC ,./,.13.2.1 .RGC .,RGC.,.13.2.2 .RG
14、C .,.13.2.3 .ASTM D 4128-06(2012)19 ,.:(1),(2),.,.13.2.4.,(),.,GC ,.,.13.2.5 .GC-MS ,-,.13.3 :13.3.1 GC-MS ,ASTM D 4128-06(2012)20 ,.13.4 :13.4.1 .-(4).:,/(1).,.13.4.2 .,.,.,.,.12.2 .13.4.2.1 GC-MS/DS (),.,.ASTM D 4128-06(2012)21 ,.,.,.13.4.3 .-,.,.GC(7)-,.,(8)-,.,.,.13.5 :13.5.1 ,ASTM D 4128-06(201
15、2)22 ().,.13.5.2 ,.,GC.,.,RSD 15%.(RF):)()(xisisxCACARF(1):Ax-,Ais-,Cx-,Cis-.4.,;,30%,.,RF 1(,);,.,.13.5.3 RSD 15%,.R 0,99.ASTM D 4128-06(2012)23 13.5.4 :RFACAisisx)()(/,(2):-,is-,/,Ais-.13.6 :)()()()(/,RFVAVCAiisfisx(3):-,is-,/,Ais-?Vf-(),Vi-().14.14.1 ,.15./(/)15.1 /.D 5789.ASTM D 4128-06(2012)24
16、15.15.1 ;GC-MS,-;(1)McLafferty,F.W.,-,4-.,Mill Valley,CA,1993.(2)Eichelberger,J.W.,Harris,L.E.Budde,W.L.,47,1975,.995.(3)Hertz,H.,Hites,R.Biemann,K.,43,1971,.681.(4)Heller,S.,McGuire,J.Budde,W.,9,1975,.210.(5)-,4-.,-,1991.(6)Cornu,A.Massot,R.,-,2-.,Heyden,-,1975.(7)ASTM STP 356,-,Kuentzel,L.,.,ASTM,1973.(8)ASTM AMD 25A AMD 25A-S1,-,Schupp,O.Lewis,J.,.,ASTM,1971.(9)Stenhagen,E.,Abrahamsson,S.McLafferty,F.,-,John Wiley&Sons,-,1974.(10)-,Markey,S.,Urban,W.Levine,S.,.,USAEC TID-26533,Oak Ridge,TN.(1
