1、 D 262216 STANDARD TEST METHOD FOR SULFUR IN PETROLEUM PRODUCTS BY WAVELENGTH DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY 2016.():2848-16/ASTM :14.03.2016 -,.9,-49,-1,119991.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)100 rr Harbor Drive,West Co
2、nshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)100 rr Harbor Drive,W
3、est Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,
4、except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D 2622-16 1 D 262216 1 D 2622;,.().1.*1.1 ,.,1 ASTM D02 ,D02.03 .1 2016.2016.1967.2010.D2622-10.DOI:10.1520/D2622-16.*ASTM D 2622-16 2 ,.1.2 PLOQ(D 6259)3/,
5、4,6%.1 ,.3/WDXRF,.1.2.1 (LOQ)(),.1.3,4,6%,.,14 .1.4 ()-.1.5 ,(.12.2).C/H (.1).ASTM D 2622-16 3 1.%0,3 0,6 0,8 0,9 1 3 2,8 FAME(.16)25 (.16)8,6 (.16)6 1.6,.1.7 ,.,.2.2.1 ASTM:2D 4057 D 4177 D 4294 2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.ASTM D 2622-16 4 D 4927 ,D 6259
6、 D 6299 D 7343 ,E 29 3.3.1 -K 0,5373.,0,5190 (0,5437 Rh),.(/),(.12).4.4.1 .1 2 .ASTM D 2622-16 5 4.2 .,.4.3 ,.4.4 ,5.2 ,D 2622,D 4294.ASTM.5.5.1 (),.,-.1.,.1 ,.ASTM D 2622-16 6 3 .1 .,3%0,5%.FAME,.16.5.2,(.1),K-.,(),.11.5.5.3,9.1,.,.,.5.4 D 4927 100/,D 4927 .D 2622 ,.ASTM D 2622-16 7 6.6.1 (WDXRF),0
7、,52 0,55 (0,537).:6.1.1,.6.1.2 .6.1.3,(0,52 0,55).6.1.4-,K-.(PET).,.6.1.5 ,K-.,.4 ,.,.,.6.2 ,0,1 100.ASTM D 2622-16 8 7.7.1 .,37.2-(DBS),.(.9.1).(-.).,.5 -,.,NIST().7.3()(),.,.,.,3 ,American Chemical Society,Washington,DC.,(Analar Standards for Laboratory Chemicals,BDH Ltd.,Poole,Dorset,U.K.)(United
8、 States Pharmacopeia and National Formulary,U.S.Pharmacopeial Convention,Inc.(USPC),Rockville,MD).ASTM D 2622-16 9 ,.,.1%.(.9.4)(.10.1).(.11.1).7.3.1 ,.,.7.4 ,.(.)6 ,50%.,.,NIST().7.5 (MOW),ACS,2/,2/.(200/),ASTM D 2622-16 10 ,(.9.1).,.C/H(.12 .1).1 7.6,.,.7.7 ,99,9%.7.8 ,.,.7.9 ,.(50/).I-/ASTM D 262
9、2-16 11 7.10 ,(,-,.).(.9.5).7.11 ,(.13).7 .,.8 ,.8.8.1 ,D 4057 D 4177 ,.8.2 .,(),.ASTM D 2622-16 12 .,.,.,.8.3 ,.,.8.4 ,.,.8.5 .D 7343.9.9.1 -,(.7.5).2.0,02%(200/),1:ASTM D 2622-16 13 S=(DBS SDBS)+(WO SWO(1)/(DBS+WO):S-,DBS-DBS,SDBSWO-,-DBS,21,91%,SWO -.2 0-1000/0,10-1,00%1,0-5,0%0,0A,0,100 1,0 5B 0
10、,250 2,0 10B 0,500 3,0 100B 1,000 4,0 250 5,0 500 750 1000 A .9 ,.2,.9.1.1.9.1.1 (CRM),.49.1.2 ,(.6).4 Kelly,W.R.,MacDonald,B.S.,and Leigh,S.D.,A Method for the Preparation of NIST Traceable Fossil Fuel Standards with Concentrations Intermediate to SRM Values(NIST (SRM),Journal of ASTM International
11、,Vol 4,No.2,2007.ASTM D 2622-16 14 CRM,.,.,.,.,.10 ,.2.9.2 ,10 11.9.2.1,100/,.,.ASTM D 2622-16 15 ,10.12,12.1.1.9.3 ,.,(.):CS =a+bI(2)CS=(a+bI)(1+ijCj )(3)CS=a+bI(1+ijCj )(4)CS=a+bI+cI 2(5):CSI-,-.a,b c,-(),b-,-,aijC-(j)(i).,-,j 11 a-(j)ij9.3.1 .,(.2):0%0,10%,0,10%1,0%1,0%5,0%.,a-.ASTM D 2622-16 16
12、12 0,10%,.().9.4 ().7 11.1.9.5 (7.10).(.14.1.1).,.,13,.10.10.1 WDXRF ,.,.D 7343,7.10.2 ,.ASTM D 2622-16 17,(PHD).,PHD,PHD.PHD.K K 10%;.10.3 .,.PHD,.10.4 8 F,.,.10.5 ,.,.,.ASTM D 2622-16 18,.10.6 .10.7 K-0,5373,.13 ,1,0%-(%).,1,0%-,.10.8 ,CV,:CV=(100(Np+Nb)1/2)/(Np Nb(6):CV-,%,NpN-,0,5373,b-,Np10.9 ,
13、K.14 .0,5190,0,5437 .2,.3.10.10 ,11.ASTM D 2622-16 19 3.2 2d()S K(0,5373)2 (0,5190)2(0,5437)2 (002)0,8742 75,85 72,84 76,92 (111)0,6532 110,68 105,23 112,68 10.11 ,10.5 10.10,10.5 10.10.10.12 100/.10.5-10.10.,14.1.1.,.,.10.13 ,.1,.10.13.1 (.3),4-5%ASTM D 2622-16 20 .,.1 ,.15 .16 ,(),5%.,(),5%-.1 ,D
14、2622 FAME(),M-85 M-100,.10.13.2 ().10.13.3 ,10.5 10.9,11.11.11.1 ,7.3,:F=A/B(7):F-,ASTM D 2622-16 21 A-,(.9.4),B-,.11.2 :R=(Np/S1)(NbF/S2(8)F:R-,Np N-,0,5373,b S-a,10.8,1 S2-,Np NbF,F-(c.17).-()0,5373 (),17 F 8 .F .F ,SQC().11.2.1 F 8.,.18 F,8,.11.3 ,8 ASTM D 2622-16 22 9.11.4 ,:S=Sb(Ws+Wo)/Ws(9):S-
15、,SbW-,sW-,11.4.1 -,.11.5 ,FAME,(.1),11.3 (.16):,.FMS/=(10):SM-,.%,-,.%,F-,0,59 M-85 0,55 M-100 11.5.1 ,5.2.11.6 D 7343.ASTM D 2622-16 23 19 ,-WD-XRF.D02.SC 3,2014.,2(,.).,5.2.,.,12.2.1,/.,10.13,.12.12.1 ,11.3.,11.4.,0,1000%.0,1000%(1000/),1000/10/,/,10/.29.,D 2622.12.1.1 ,100/,12.1.12.2 11 (/),.1:AS
16、TM D 2622-16 24 SC/H1,195 0,0164(C/H)=S (11)1,195 0,0164(C/H):SC/H(C/H)-C/H,(C/H)-,-,5,7 .1,S 12.2.1 C/H ./S-,.,(C/H)/.C/H (.6).11,.13.13.1 ,.5 5 ASTM MNL 7,3,ASTM International,W.Conshohocken,PA.(.7.11).,D 6299.ASTM D 2622-16 25 13.2 (7.11),(,).13.2.1 2/(0,0002%).2/(0,0002%),().,.,1).6 (SRM)NIST.,(RR),C/H,.5.6 NIST ,C/H.,C/H=5,698(C22H4614.2.1 ,C/H,.1.).14.2.2 10 (SRM)NIST,-SRM (R),C/H(.5 6).ASTM D 2622-16 29 5.SRM NIST (RR)ASTM SRM NIST,/,NIST RR ,/ASTM RR ,/ASTM RR ,/,%2298 4,7 1 6,0 2,9 1,3
