1、 1469-2004 I I (S D 2622-2003,IDT)4-2004 1469-2004 II 665.7.033.52:543.427.4(083.74)75.080 (09)IDT :,-,1 -()2 30 2004.20 3 ASTM D 2622-2003 Standard Test Method for Sulfur in Petroleum products by wavelength dispersive X-ray fluorescence spectrometry(ATM 2622-2003 c -),ASTM D02 ,D02.03.:2622-2003 .(
2、en).,.ASTM D,-,.(IDT)4 1469-2004 III 1 .1 2 .2 3 .2 4 .2 5 .4 6 .4 7 .4 8 .5 9 .6 10 .7 11 .8 12 .9 13 .10 14 .10 ASTM D,.12 1469-2004 1 I I Oil and oil products DETERMINATION OF SULFUR CONTENT BY WAVELENGTH DISPERSIVE X-RAY FLUORESCENCE SPECTROMETRY METHOD 2004-11-01 1 1.1 ,-.,-85 -100.1.2 3/5,3%.6
3、0/(Sr)1,5/.-3 Sr,-1 10 Sr.-,20/.1.3 5,0%,.1.4 ,-,-.1.5 -./(1 2)-(3).1.6,.1.7 ,-,.-,-.1 ,55,1983,.2210 2218.1469-2004 2 2 :40571 41771 42941 -49271 -,-ATM 292 3 3.1 -5,373.,5,190 (5,437 ),.-,.:.,-.,-.4 4.1 .1 2.4.2 .,.1 (RR)NIST ASTM NIST ,%,(NIST),%,(ASTM),(RR)/,%,%-1616 0,0146 0,0148 5,205 0,0002 1
4、,37 1617 0,1731 0,1776 5,205 0,0045 2,60 2724 0,0430 0,0417 5,986 0,0013 3,02 1623 0,3806 0,3661 7,504 0,0145 3,81 2717 3,0220 2,948 8,229 0,0736 2,44 1621 0,948 0,8973 8,553 0,0507 5,35 1624 0,3918 6,511 2723 0,0299 5,937 1 ATM,05.02.2 ,14.02.1469-2004 3 2 (RR)NIST ASTM ,XRF-11./.t -NIST 1 -.,S=S/(
5、1,086-0,01511 /),/=.NIST RR ID NIST RR c-,%,%1616 2 0,01460,0147 0,0001 0,68 1617 1 0,17310,1763 0,0032 1,85 2724 D2 0,04300,0419 0,0011 2,56 1623 R1 0,38060,3763 0,0043 1,13 2717 R4 3,02203,065 0,0430 1,42 1621 R3 0,948 0,9382 0,0098 1,03 1624 D3 0,397 2723 D4 0,0300 3 ,%0,3 0,6 0,8 0,9 1 3 (14)8,6
6、 (14)6 4.3 ,.4.4 ,-,5.1 ,.,4294.ATM1.1 ATM,00.01.1469-2004 4 5 5.1 (),.,.-3.5.2-85 -100 ,85 100%.,.-,(),.5.3,(9.1),-,.,-,.,-,.5.4 4927 ,.6 6.1 (WDXRF),5,37.-:6.1.1 .6.1.2 .6.1.3,.6.1.4 .,EDDT,ADP,.6.1.5 ,.-,.7 7.1 .,1.,.7.2-.(9.1)-.2 -,.1 ,-.Am.Chemical Soc.,Washington,DC.,.Analar ,BDH Ltd.,Poole,Do
7、rset,Inc.,(USPC),Rockville,MD.1469-2004 57.3 ().-.,-,-.,1%.(9.4)(10.1).(11.1).7.3.1 ,.3 .,-.7.4 2/2/.,(200/),(9.1).7.5 .,-,.,.7.6 99,9%.7.7 ,.7.8 ,.7.9 ,.(9.5).7.10 ,(13).4 .,-.5 .8 8.1 4057 4177 ,.8.2 -.,.,.,.,.,.1469-2004 6 8.3 ,.9 9.1 -(5.3).,4,.0,02%,.6 ,4.7 ,4.4 ,%,%,%0,0000*0,100 1,0 0,001 0,2
8、50 2,0 0,010 0,500 3,0 0,025 4,0 0,050 5,0 0,075 *.9.2 ,10 11.9.3 :9.3.1 ,.9.3.2 :S%=(D+ER)(1+S)(1)S%=aR+bR2+,(2)S ,%;D ;R ;,;,b .8 (1).9.3.3 ,.9 ,0,10%.1469-2004 79.4 -().(4),11.1.9.5 (7.9).:.,.-.10 10.1 ,.(4),11.1.10.1.1 F (5)(11)-,.,.10.2 .,.,.,.10.3 ,.10.4 5,373,.10 ,1,0%-(%rsd).,1,0%-,-,.:,%=(1
9、00NS+Nb)/(NS Nb),(3)NS ;Nb ,NS .10.5 ,.11 -.5,190,5,437 .2 5.10.6 11.10.7 ,10.2 10.6,10.3 10.6.1469-2004 8 10.8 ,3,5.12 3 -.,3%0,5%.5 2 2d()S K(5,373)(5,190)(5,437)NaCI(200)5,6406 144,56 133,89 149,12 EDDT(020)8,806 75,18 72,21 76,24 ADP(101)10,640 60,65 58,39 61,46 (002)8,742 75,85 72,84 76,92 (101
10、)6,5872 106,93 101,81 106,97 Ge(111)6,532 110,68 105,23 112,68 (002)6,706 106,45 101,38 106,29 (002)(PG)6,74 105,72 100,71 107,55 10.8.1 ,-4 5%-.,.3 ,.13 .-.14 -,(),-5%.,(),-5%-.3 ,(-85 -100).10.8.2 .10.8.3 ,10.2 10.6,11.11 11.1 ,7.3,F=A/B,(4),(9.4);,(10.1).15 (5)-.F,.F ,SQC.1469-2004 911.2 :R=(CK/S
11、1)(CBF/S2)F,(5),5,373;B ,10.5;S1 S2 ,/;R ;F (/5,373)/(/,10.5 ,).11.2.1 F (5)(15).11.2.2 F (5).-,-.16 F,(5),.11.3 ,-,(5),9.11.4 ,S,%=Sb (Ws+Wo)/Ws,(6)Sb ,%;Ws ,;Wo ,.12 12.1 ,11.3.,11.4.0,0100%,0,0010 0,0099%0,0010%.29.,-.12.2 -85 -100 ,-,11.3,(14):S(-85),%=S,%/0,59;(7)S(-100),%=S,%/0,55.(8),5.2.17 -
12、85,-100 1.1 XRF-11,Criss,Largo,MD.1469-2004 10 13 13.1 ,-,-.-1 (7.10).,.14 14.1 ,-.(I)2 ,.(II)2 ,21 .-85 -100 .(III)3 16,-,28.(PLOQ),20/,.,PLOQ ,14/,.-14.1.1 14.1.2.18 ,-(III),(II).,0,0024 0,0080%,III.14.1.1 ,-,:,%I 0,006 5,3 0,02651 0,9 II 0,0003 0,093 0,00736(+0,0002)0,4 III 0,0024 0,0080 0,02438(
13、+0,012469),%.14.1.2 ,-,:,%I 0,006 5,3 0,0913 0,9 II 0,0003 0,093 0,0105(+0,0002)0,4 III 0,0024 0,0080 0,04795(+0,012469),%.1 ASTM MNL 7,3,.2 ATM.RR:D02-1428.3 ATM.RR:D02-1547.1469-2004 1114.2 (I)NIST.,(RR),/,1.2 NIST ,/.,/=5,698(2246).14.2.1 -/1.1 14.2.2 NIST ,(III),-,PLOQ,.:SRM 2298(4,7/S),SRM 2299(13,6/S).SRM 2723(10/S).1469-2004 12 (),4294-1998 -IDT 1420-2003 .1469-2004 1 .16.06.2004.04.08.2004.6084/8.1,03.-.0,95 .()02330/0133084 30.04.2004.220113,.,.,3.
