1、 D139476(2014.)STANDARD TEST METHODS FOR CHEMICAL ANALYSIS OF WHITE TITANIUM PIGMENTS 2018 ():18.06.2018:3470-18/ASTM -,.9,119049.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International
2、,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM Internat
3、ional does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,except for ASTM International or FBU“CIC“In
4、terstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D1394-76(2014)1 D139476(2014.)1 D1394;,.()1.1.1 .1.2 :4 5 6 7 :8 12 13 17 18 22 23 29 1 ASTM D01 ,D01.31 .1 2014.2014.1956.2009.D1394-76(2009).DOI:10.1520/D1394-76R14.ASTM D1394-76(2014)2 1.3,.1.4 ,.
5、,.19.2.2.1 ASTM:2 D280 ,D1193 E50 ,3.3.1 .,.3 2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.3 ,.,.,.,BDH Ltd.,.,.,Inc.(USPC),.,.ASTM D1394-76(2014)3 ,.3.2 ,IV D1193.4.4.1 .5.5.1 (.0,90)(NH4OH).5.2 (NH4)2SO4).5.3 (.1,19)(HCl).5.4 (30%)(H2O2).5.5 (H2S).5.6 (.1,84)(H2SO4).5.7
6、 (1+19)1 H2SO4(.1,84)19 .5.8 .5.9 .ASTM D1394-76(2014)4 6.6.1 0,5 250-,4 20 H2SO4(.1,84)7-8 (NH4)2SO4.;(SiO2).,100 ,H2SO4(1+19),.6.2 ,.5 5 ,H2S .30 ,.,HCl,.H2O2(-),(-).,.7.7.1 4 .5 Treadwell,F.P.,Hall,William T.,John Wiley&Sons,Inc.,.-,.-,1,9-,1937.ASTM D1394-76(2014)5 D280.8.8.1 ,(13-17).9.9.1 6,45
7、0 19 (1 2).,(),.(0,1-1,0%),.,20 1 1-HCl ,0,25 3.,HCl.,.6 Hillebrand,W.F.,John Wiley&Sons,Inc.,.-,.-,2-.,1953.,.108.ASTM D1394-76(2014)6 .1.10.10.1 (.0,90)(NH4OH).10.2 (NH4)2SO4).10.3 .10.4 (1 =0,02 Fe)20 HCl,12 HNO3,80 H2SO4 .,1,.0,1-KMnO4 ,-100 (2)500 (4)100 (2)40(1,5)20 (1)8 (0.5)ASTM D1394-76(201
8、4)7 5.-Ferric(FeNH4(SO4)212H2O)(.15.4).10.5 (.1,19)(HCl).10.6 .10.7 (.1,42)(HNO3).10.8 40-(Na2C2O4).10.9 ,(0,1-,1 =0,008 TiO2)3,16 KMnO4 1.8-14,()40-(Na2C2O4):400-250-300 Na2C2O4 250 (80-90C)15 H2SO4(1+1).KMnO4,.KMnO4 ,10-15/,0,5-1 ,.60C .(,.)KMnO4 ,.ASTM D1394-76(2014)8 .2.TiO2-TiO2 KMnO4 :TiO2-=(W
9、 1,192)/V :W=Na2C2O4,;V=KMnO4,.10.10 (.1,84)(H2SO4).10.11 (1+1)1 H2SO4(.1,84)1 .10.12 (1+19)1 H2SO4(.1,84)19 .ASTM D1394-76(2014)9 11.11.1 0,1.300-350 0,1.11.2 2 105-110C.,.11.3 250-,4 20 H2SO4(.1,84)7-8 (NH4)2SO4.,(5 ),SiO2 .,100 ,.11.4 H2SO4(1+19),.200 5 NH4OH,10-15%H2SO4().H2SO4(1+19),.(-0,1-KMnO
10、4 .)25 .:11.4.1 50 H2SO4(1+19),5-10.ASTM D1394-76(2014)10 11.4.2 ,10.11.4.3 100 H2SO4(1+19).11.4.4 100 .,.11.5 ,0,1-KMnO4.,.12.12.1 TiO2 :V1-KMnO4,;B-KMnO4,;T-TiO2-KMnO4,/;S-,.12.2,.12.1,.ASTM D1394-76(2014)11 13.13.1 ,(8-12).14.14.1 ,4,6 (152)3 (76)6 .14.2,.15.15.1 ,.15.2 (NH4)2SO4).15.3 ,24,5 (NH4
11、CNS)80 ,100.15.4 -(1 =0,005 TiO2)30,16 -(FeNH4(SO4)212H2O)800 ,15 H2SO4(.1,84).5 3%-H2O2 15,.1 .,.ASTM D1394-76(2014)12 ,190-210 -154 (),16.TiO2-TiO2 ,:TiO 2-=(W1 P)/(V2 100):W1-TiO2 ;P-TiO2 ;V2-,.15.5 (.1,19)(HCl).15.6 3%.15.7 .10 (NaHCO3)90 .15.8 (.1,84)(H2SO4).15.9 (TiO2)154 .16.16.1 .190-210 0,1
12、.16.2 2 105-110C.,.ASTM D1394-76(2014)13 16.3 500-.7-9 (NH4)2SO4 20 H2SO4.,(5 ),SiO2 .120 20 HCl.16.4 ,.,.1 ,.0 150C,.,250-,150 NaHCO3.16.5 ,3-5,NaHCO3.60C,.NaHCO3 ,CO2 .,.ASTM D1394-76(2014)14 16.6 2 NH4CNS -(.15.4)-.-,.17.17.1 TiO2 :TiO2,%=(V3 T1 100)/S :V3-,;T1-TiO2-,/;S-,.17.2,.17.1,.18.18.1 .19
13、.1 :.19.1 ,.ASTM D1394-76(2014)15 19.2 ()77 ,10 1.19.3 (1+4)1 (.0,90)4 .19.4 ,150 (NH4)2HPO4 700 .pH 5,5 HCl(1+1).1.19.5 (0,02)7,45 1.19.6 (1+1)1 (.1,19)1 .19.7,0,1 100 E50.19.8 (NaHSO4H2O).19.9 (NaF).19.10 (6,25)500 (NaOH)2.19.11 (1+1)1 1 H2SO4.19.12 ,0,2 100 .19.13 ,(0,01)2,90 (ZnSO47H2O)1.:19.13.
14、1 0,50 (99,8%),0,1,20 ASTM D1394-76(2014)16 HCl.1-.19.13.2 10-500-,90 3 HCl.1 .20.4.19.13.3 ZnSO4 :A=(18,8955 W1)/V4 A-Al2O3 ZnSO4,;W1-,.19.13.2,;V4-ZnSO4,;18,8955=Al2O3 10 2 Al 20.20.1 1 ,0,1,10 NaHSO4H2O 250-,.250-.,.,.SO3,.,.,.25 H2SO4(1+1).,.(,ASTM D1394-76(2014)17 .)120 .20.2 200 6,25M NaOH.65
15、NaOH .NaOH 500-.NaOH.,.(2,).5,100.20.3 100-500-,1 HCl(1+1),;3.20.4 25 .(,:4%Al2O3+5=0,02M.)NH4OH(1+4),-.10 10 (NH4)2HPO4,5 .3 .,-,pH 5,3-5,7 .pH,;,.20.3 50 .20.4.ASTM D1394-76(2014)18 20.5 ZnSO4 -.,0,2 ,.5-10,.,.8 ZnSO4.10-15 ZnSO4.20.6 2 NaF,2-5 .,ZnSO4 ,.20.5.21.21.1 :A=(Z T)/(2 S):A-Al2O3;Z-ZnSO4
16、,;T-Al2O3 ZnSO4,;S-,.22.22.1 95%:ASTM D1394-76(2014)19 22.1.1 ,0,22%.22.1.2 ,0,62%.23.23.1 (TiO2).24.24.1 TiO2 ,.,.25.25.1 ,250-,.25.2 ,.25.3 .25.4,120C.25.5 ,1000 25C.ASTM D1394-76(2014)20 26.26.1 (.1,15)(HF).26.2 (NaHSO4H2O).26.3 (.1,84)(H2SO4).26.4 (1+1)1 1 H2SO4.26.5 (1+9)9 1 H2SO4.27.27.1 1 ,0,1,250-,10 NaHSO4H2O.SiO2 5%,0,5-,10 NaHSO4H2O.27.2 ,(SiO2).27.3 25 H2SO4(1+1),.H2SO4.27.4 150 .,.,60-.ASTM D1394-76(2014)21 27.5 H2SO4(1+9).27.6 120C.,.,1000C 30 .27.7 2 H2SO4(1+1)5 HF(.1,15).,HF,H2SO
