1、Manual on Chlorosilane Emergency Response Guidelines John T.HIgglns,Wilmuth E.Hubbs,Robert A.Kayser,Paul Kremer,Stephen W.McMahan,Lee Patrick,and Michael Strong,editors ASTM Manual Series:MNL33 ASTM Stock#:MNL33 m 100 Barr Harbor Drive,West Conshohocken,PA 19428-2959 Library of Congress Cataloging-i
2、n-Publication Data Manual on chlorosilane emergency response guidelines/John T.Higgins.et al.(ASTM manual series;MNL 33)Includes bibliographical references and index.ASTM Stock#:MNL33.ISBN 0-8031-2076-1 1.Hazardous substancesAccidentsHandbooks,manuals,etc.2.Hazardous substancesSafety measuresHandboo
3、ks,manuals,etc.3.ChlorosilanesAccidentsHandbooks,manuals,etc.4.ChlorosilanesSafety measuresHandbooks,manuals,etc.I.Higgins,John T.,1937-.II.Series.T55.3.H3M2438 1998 628.92dc21 98-9980 CIP Copyright 1998 AMERICAN SOCIETY FOR TESTING AND MATERIALS,West Conshohocken,PA.All rights reserved.This materia
4、l may not be reproduced or copied,in whole or in part,in any printed,mechanical,electronic,film,or other distribution and storage media,without the written consent of the publisher Photocopy Rights Authorization to photocopy items for internal,personal,or educational classroom use,or the internal,pe
5、rsonal,or educational classroom use of specific clients,is granted by the American Society for Testing and Materials(ASTM)provided that the appropriate fee is paid to the Copyright Clearance Center,222 Rosewood Drive,Danvers,MA 01923;Tel:508-750-8400;online:http:/ manual does not purport to address(
6、all of)the safety problems associated with its use.It is the responsibility of the user of this manual to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.Printed in Philadelphia March 1998 Foreword THIS PUBLICATION.Manual on Ch
7、lorosilane Emergency Response Guidelines,was spon-sored by Committee F-20 on Hazardous Substances and Oil Spill Response and by the Institute for Standards Research(ISR).This is Manual 33 in ASTMs manual series.The editors,all members of the Operating Safety Committee of the Silicones Environ-mental
8、,Health and Safety Council,were the following:John T.Higgins,coordinator,Emergency Response and Process Safety,Dow Coming Corporation,Corporate Safety and Loss Department,3901 S.Saginaw Rd.,Midland,MI 48686;Wilmuth E.Hubbs,manager.Distribution/Emergency Response,Rhone-Poulenc,2 TW Alexander Drive,Re
9、search Triangle Park,NC 27709;Robert A.Kayser,senior development scientist,Witco Corporation,State Route 2 South,P.O.Box 180,Sistersville,WV 26175;Paul Kremer,manager.Technical Services,PCR,Inc.,P.O.Box 1466,Gainesville,FL 32602;Stephen W.McMahan,senior distribution engineer,Witco Corporation,State
10、Route 2 South,P.O.Box 180,Sistersville,WV 26175;Lee Patrick,environmental manager,Creanova Inc.,Mobile Plant,Chemical Division,Rangeline Road,Theodore,AL 36582;and Michael Strong,industrial hygienist,Wacker Silicones Corporation,3301 Sutton Road,Adrian,MI 49211-9397.I l l Contents chapter 1:Introduc
11、tion 1 Chapter 2:Initial Emergency Response Guides 2 A.Guide SEHSC-001 2 B.Guide SEHSC-002 3 C.Guide SEHSC-003 4 D.Guide SEHSC-004 5 E.Reference Guide for Selected Chlorosilanes 6 Chapter 3:Emergency Response Decision Trees 7 Chapter 4:Foam Applications 15 A.Purpose 15 B.Philosophy 15 C.Spill Contro
12、l 15 D.Fire Control 15 E.Foam Systems 16 Chapter 5:Transfer Procedures 17 A.Bulk Containers(Cargo Tanks,Intermodal Containers,Tank Cars,Fixed Tanks)17 1.Purpose 17 2.Philosophy 17 3.Receiving Container 17 4.Transfer Equipment 17 5.Closed-Loop Transfer Procedure 17 6.Vented Transfer Procedure 17 B.Dr
13、um Transfer 18 1.Purpose 18 2.Philosophy 18 3.Transfer Equipment 18 4.Gravity Transfer Procedure 19 5.Pump Closed-Loop Transfer Procedure 19 6.Pump Vent Transfer Procedure 20 C.Transferring Chlorosilanes from Containers 21 1.Purpose 21 2.Philosophy 21 3.Cylinder Descriptions 22 4.Receiving Container
14、 22 5.Transfer Equipment 22 6.Closed-Loop Transfer Procedure 23 7.Vented Transfer Procedure 23 D.Liquid Nitrogen Purging Procedure 24 1.Purpose 24 2.Philosophy 24 3.Procedure 24 vi CONTENTS E.Purge,Scrub,and Vent Procedure 25 1.Purpose 25 2.Philosophy 25 3.Materials Required 25 a.Water Scrubbing/Neu
15、tralizing Equipment Setup 25 b.Ice Tower Scrubbing Equipment Setup 26 4.Venting Procedure 27 Chapter 6:Hydrolysis of Chlorosilanes 29 A.Purpose 29 B.Philosophy 29 C.Pipe Line Reactor 29 1.Equipment 29 2.Procedure 29 D.Neutralization in Place Procedure 31 E.Hydrolysis in Place Procedure 31 Chapter 7:
16、Cloud Dispersal Procedures 32 A.Purpose 32 B.Philosophy 32 C.Procedure 32 Chapter 8:Small Fire and Spill Handling Procedures 33 A.Purpose 33 B.Philosophy 33 C.Procedure 33 Chapter 9:Fire Impingement/Radiant Heat on Other Vessels 34 A.Purpose 34 B.Philosophy 34 C.Procedure 34 Chapter 10:Personal Protective Equipment Requirements 35 A.Purpose 35 B.Philosophy 35 C.Procedure 35 1.Non-Flammable Situations 35 2.Potentially Flammable Situatiom 35 Chapter 11:Decontamination of E/R Personnel and Equipmen
