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1、STP 1277 Electrochemical Noise Measurement for Corrosion Applications Jeffery R.Kearns,John R.Scully,Pierre R.Roberge,David L.Reichert,and John L.Dawson,Eds.ASTM Publication Code Number(PCN)04-012770-27 ASTM 100 Barr Harbor Drive West Conshohocken,PA 19428-2959 Printed in the U.S.A.Copyright by ASTM

2、 Intl(all rights reserved);Sat Dec 26 19:08:01 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Library of Congress Cataloging-in-Publication Data Electrochemical noise measurement for corrosion applicati

3、ons/Jeffery R.Kearns.et al.,edso p.cm.-(STP 1277)ASTM Publication Code Number(PCN)04-012770-27.Proceedings of the First International Symposium on Electrochemical Noise Measurement for Corrosion Applications,held in Montreal,Quebec,15-16 1994;sponsored by ASTM Committee G-1 on Corrosion of Metals.In

4、cludes bibliographical references and index.ISBN 0-8031-2032-X 1.Corrosion and anti-corrosives-Testing-Congresses.2.Electrolytic corrosion-Testing-Congresses.3.Potentiometry-Congresses.4.Electronic measurements-Congresses.I.Kearns,Jeffery R.II.ASTM Committee G-1 on Corrosion of Metals.II1.Internatio

5、nal Symposium on Electrochemical Noise Measurement for Corrosion Applications(1st:1994:Montreal,Quebec)IV.Series:ASTM special technical publication:1277.TA462.E535 1996 620.1 1223-dc20 96-23890 CIP Copyright?9 1996 AMERICAN SOCIETY FOR TESTING AND MATERIALS,West Conshohocken,PA.All rights reserved.T

6、his material may not be reproduced or copied,in whole or in part,in any printed,mechanical,electronic,film,or other distribution and storage media,without the written consent of the publisher.Photocopy Rights Authorization to photocopy items for internal,personal,or educational classroom use,or the

7、internal,personal,or educational classroom use of specific clients,is granted by the American Society for Testing and Materials(ASTM)provided that the appropriate fee is paid to the Copyright Clearance Center,222 Rosewood Drive,Danvers,MA 01923,Tel:508-750-8400;online:http:/ Review Policy Each paper

8、 published in this volume was evaluated by three peer reviewers.The authors addressed all of the reviewers comments to the satisfaction of both the technical editor(s)and the ASTM Committee on Publications.The quality of the papers in this publication reflects not only the obvious efforts of the aut

9、hors and the technical editors,but also the work of these peer reviewers.The ASTM Committee on Publications acknowledges with appreciation their dedication and their contribution of time and ef-fort on behalf of ASTM.Printed in Philadelphia,PA September 1996 Copyright by ASTM Intl(all rights reserve

10、d);Sat Dec 26 19:08:01 EST 2015Downloaded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Foreword This First International Symposium on Electrochemical Noise Measurement for Corrosion Applications was held in Montreal,Que

11、bec,Canada on 15-16 May 1994.ASTM Committee G-1 on Corrosion of Metals sponsored the symposium.Jeffery R.Kearns,Alcoa Technical Center,Alcoa Center,PAL,served as chairman of the symposium and was principal editor of this publication.John R.Scully,University of Virginia,Charlottesville,VA;Pierre R.Ro

12、b-erge,Royal Military College of Canada,Kingston,Ontario;David L.Reichert,DuPont Ex-perimental Station,Wilmington,DE;and John L.Dawson,CAPCIS Ltd.,Manchester,United Kingdom,served as symposium vice-chairmen and co-editors.Copyright by ASTM Intl(all rights reserved);Sat Dec 26 19:08:01 EST 2015Downlo

13、aded/printed byUniversity of Washington(University of Washington)pursuant to License Agreement.No further reproductions authorized.Contents Overview ix KEYNOTE ADDRESS Electrochemical Noise Measurement:The Definitive In-Situ Technique for Corrosion Applications?-JOHN L.DAWSON CORRELATIONS TO OTHER E

14、LECTROCHEMICAL TECHNIQUES A Comparison of Electrochemical Noise and Impedance Spectroscopy for the Detection of Corrosion in Reinforced Concrete-uco BERTOCCI Electrochemical Noise and Impedance Analysis of Iron in Chloride Media-FLORIAN MANSFELD AND HONG XIAO Electrochemical Noise Measurement for De

15、termining Corrosion Rates-DAVID L.REICHERT 39 59 79 DATA ANALYSIS The Effects of Solution Resistance on Electrochemical Noise Resistance Measurements:A Theoretical Analysis-R.A.cOTrlS,S.TUROOSE,AND J.MENDOZA-FLORES Analysis of Electrochemical Noise for Type 410 Stainless Steel in Chloride Solutions-

16、ROBERT G.KELLY,MARIA E.INMAN,AND JOHN L.HUDSON Comparison of Spectral Analysis with Fast Fourier Transform and Maximum Entropy Method.Application to the Role of Molybdenum Implantation on Localized Corrosion of Type 304 Stainless Steel-LUC BEAUNIER,JOEL FRYDMAN,CLAUDE GABRIELL,FRAN(OIS HUET,AND MICHEL KEDDAM 93 101 114 A Comparison of Spectral and Chaotic Analysis of Electrochemical Noise-ANDRAZ LEGAT AND EDVARD GOVEKAR 129 Copyright by ASTM Intl(all rights reserved);Sat Dec 26 19:08:01 EST 2015

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