1、 D 658112 ,STANDARD TEST METHODS FOR BROMATE,BROMIDE,CHLORATE,AND CHLORITE IN DRINKING WATER BY SUPPRESSED ION CHROMATOGRAPHY ():2193-13/ASTM :19.11.2013 2013 (ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This tra
2、nslation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these t
3、ranslations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the
4、 USA legislation and international copyright.-,.9,-49,-1,119991.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/ASTM D 6581-12 D 658112 ,1 D 6581;,.()1.1.1 ,(),().:1 ASTM D19 ,D19.05 .01 2012.2012.2000.2008.D 6581-08.DOI:10.1520/D6581-12.1ASTM D 6581-12 A:,/8 20 5 500
5、 1 25 5 250 5 500 B:21 31 20 1000 1 30 20 200 20 1000 1.1.1 .,.1.3 300.1 EPA U.S.()2 .1.4,.1.5 ,.,.2 U.S.EPA 300.1,1997.2ASTM D 6581-12 2.2.1 ASTM:3 D 1129,D 1193 D 2777 ,D19 D 3370 D 3856 ,D 5810 D 5847 3.3.1 ,.D 1129.3.2 ,:3.2.1 ,.3.2.2 ,.3 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document
6、 Summary ASTM.3ASTM D 6581-12 .3.2.3 ,.3.2.4 ,.3.2.5 ,().3.2.6 .3.2.7 -,.3.2.7.1 ().3.2.7.2 ()-,.4ASTM D 6581-12 4.4.1 ,(DBP),.,.,().5.5.1 .,.4 ,.5.2 ,I D 1193.,.4 ,DC.,.,by BDH Ltd.,Poole,.5ASTM D 6581-12 6.6.1 .,.7.7.1 D 3370.7.2 (,)5 ,.1,00 EDA(.15.3)1,000 ,.,14 4 C.5 8.8.1 ,-(),5 Hautman D.P.,Bo
7、lyard M.,Journal of Chromatography,.602,1992,.65.6ASTM D 6581-12():,/5 500 1 25 5 250 5 500 8.1.1 .,.8.2 ,.8.3 300.1 EPA U.S.().8.4 ,.,.9.A 9.1 (,),7ASTM D 6581-12 .200 ,(),(,).9.1.1 ,.,.,.9.2 .10.10.1 (),.,.,.15.3.,200/,8ASTM D 6581-12 .11.11.1 ,.11.1.1 0,10 5,0/4000 .(27600).11.1.2 ,.50 -,.11.1.3
8、-,.11.1.4 -,.,1.1 (.3.2.2)50,(,)200/.9ASTM D 6581-12 11.1.5 .,.11.1.6 ,0 15 000/.11.1.7 ,.12.1 12.1.1,2 1.13.2 13.1 ,.CRD-300 IonPac AS23 .,CRD-300,CRD-300.,10ASTM D 6581-12 10/.A CRD-300 :IonPac AS23(4 250)IonPac AG23(4 50):4,5 M K2CO3/0,8 M KHCO3 :1.0/:,ASRS-300,4 ,CRD-300,4 :200/,300/,.,SPE-H+Ag+
9、.,OnGuard-H OnGuard-Ag6,().15.5 ,3,00 (1,84)4,000 ,.15.6 (1,00 =1,00):15.6.1 (BrO3-)(1,00 =1,00 BrO3-)1,180 (NaBrO3)1,000.6 Joyce,R.I,and Dhillon,H.I,Chromatography,.671,1994,.165.14ASTM D 6581-12 1 :,1.(0,1/)5.(0,3/)8.(0,5/)2.(0,3/)6.(0.5/)9.(0,8/)3.(0,6/)7.(0.5/)10.(0,6/)4.(0,2/)3 ,CRD-300(A)(B)15
10、.6.2 (Br-)(1,00 =1,00 Br-)1,288 (NaBr)1,000.15.6.3 (lO3-)(1,00 =1,00 ClO3)1,275 (NaClO3)1,000.15ASTM D 6581-12 1 :,1.(0,5/)4.(50/)6.2.(10,20 40/)5.(10,20 40/)7.(100/)3.(10,20 40/)4 ,CRD-300(A)(B)15.6.4 (ClO2)(1,00 =1,00 ClO2)1,680 (NaClO2)1,000.,80%-,1,680.16ASTM D 6581-12 (NaClO2 .2,7 2 ,CRD-300(A)
11、(B)R-(%):A 3 99.996199.9748 3 100.0000 99.9986 3 99.9995 99.9637 3 A(/)(/)1 11.0 1.52 5.33 ND 2 10.9 1.55 6.23 ND 3 10.9 1.35 5.02 ND 4 10.1 1.91 6.25 ND 5 11.3 1.48 5.89 ND 10.8 1.56 5.74 RSD 4.34 13.42 9.61 4 ,CRD-300(A)(B)A(/)(/)NDA 10.83 1.56 ND 5.74 ND ()10 10 10 10 10 10 9.88 20.51 12.02 8.58
12、15.30 8.50 RSD 2.39 1.60 2.45 2.39 1.60 2.45%98.8 98.5 104 85.8 97.2 85.0 A ND .B .7 4500-ClO2C,.A.E.Greenberg,L.S.Clesceri,A.D.Eaton,18-.,APHA,DC,1992.17ASTM D 6581-12 15.7 ()1,00 EDA(.15.3)1,000 .16.16.1 ,(),().:5 30/,20 200/,20 500/20 500/.16.2 ()(.15.6).()EDA 50/(1,00 EDA(.15.3)1,000 ).,.16.3 ,1
13、7,200 (4),50 (2).(r2)0,995.18ASTM D 6581-12 ,(.20.4 20.5).17.17.1 ,.(5 ).200 (4),50 (2).1,2.18.18.1 ,.16.3,(/):(1),/,/=A F:A-,(/),F-,.18.1.1 .19ASTM D 6581-12 18.2 ,.,.19.19.1 ,D 2777-98,.,.1.4 D 2777-06,D19.-ASTM.8 19.2 ,().,(Youden),(So).().,(18)1,0,A1-2(3),1-2(3),1-2(3),18 ,EDA 50/(.8 -ASTM Inter
14、national RR:D19-1164.20ASTM D 6581-12.7.2)100 (6),(6)(6),.19.2.1 (QC).(MDL)MDL.QC-QC-1,0 ,EDA 50/100 .MDL-MDL-1,0 ,EDA 50/100 .19.3 IonPac AS9-HC(.1).19.4 ,5 8.19.5 (.9 ,10 ).19.6 ,(.5 8),MDL-.MDL-t-():(2)MDL=(t)(S)21ASTM D 6581-12:t-t 99%-(n-1)t=3,14 ,S-.8 19.6.1 ,MDL-(10 7)11.20.20.1 D 3856 .20.2
15、,(IDP).IDP-,EDA 50/(.15.3).5 ,%,/,/(/)(/)22ASTM D 6581-12 6 7 8 ,/,/,/,/,/,/,%(/)(/),%(/)(/),%(/)(/)23ASTM D 6581-12 9 10 10 10 10 20-450/5-25/20-180/20-450/=0.9805x+0.5261 =0.9432x+0.6272 =0.9629x+1.7475 =0.9809x+0.8245 So =0.0465x 1.4801 =0.0878+0.1281 =0.0282x+1.3087 =0.0389x+2.7278 St =0.0332x+0
16、.3294 =0.046x+0.721 =0.0246x+1.6352 =0.0226x+1.8244 10 10 10 10 10 20-450/5-25/20-180/20-450/=0.9872x 1.0243 =0.9432x+0.6272 =0.9583x+1.2113 =0.9868x 0.7347 So =0.0068+2.2164 =0.1721 0.5532 =0.0022x+2.6 =0.0066+3.0956 St =0.0289x+5.8552 =0.1934+0.3866 =0.0357+3.1189 =0.03+3.3368 11-MDL-,/,/MDL,/3.0 3.32 2.39 4.0 3.98 2.73 4.0 3.96 2.91 4.0 3.74 3.49 IPD-.IPD-3.20.2.1 D 5847,(),24ASTM D 6581-12 .:IDP-,/So,/IDP-(n=7),/180 4.4 11.8 10 0.66 1.67 75 3.8 9.6 180 12.0 32.1 ,/IDP-,/IDP-,/178.3 164.6 191
