1、 D 741913 (HPLC)STANDARD TEST METHOD FOR DETERMINATION OF TOTAL AROMATICS AND TOTAL SATURATES IN LUBE BASESTOCKS BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY(HPLC)WITH REFRACTIVE INDEX DETECTION 2014 ():2358-14/ASTM:23.05.2014 -,.9,-49,-1,119991.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http
2、:/www.interstandart.ru/(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Soci
3、ety for Testing and Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the ori
4、ginal version.Reproduction of the specified translations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D 7419-13 1 D 741913 (HPLC)1 D 7419;,.()1.1.1 (HPLC)(RI).,0,2 46%.1.1.1 ().1 D02 ,D02.
5、04.0C .01 2013.2013.2007.2007.D 7419-07.DOI:10.1520/D7419-13.ASTM D 7419-13 2 1,0%.1.2,.1.3 ,.,.2.2.1 ASTM:2 D 4057 D 4177 D 6299 3.3.1:3.1.1 ()(),2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.ASTM D 7419-13 3 .3.1.1.1 1 4.3.1.2 HPLC-(-).3.1.2.1 +().3.1.3 HPLC-.3.1.3.1 -,.
6、3.1.4 ,.3.1.4.1 HPLC-.,1,5.6.9 0,0001.7.7.1,HPLC.7.2,HPLC UV.7.3,97%.7.4,98%.ASTM D 7419-13 78.8.1 D 4057,D 4177 .9.9.1 ,UV-,RI-(.1).,(.1).(-).,.1 ,A Varian,50,7,7,Si60(5)Varian,50,7,7,Si60(CP28526)Phenomenex,2 Si60,10 250 (5)CN-Alltech/YMC,100 10(10)Waters/YMC,100 12 (5)YMC,10 100 (5)RI-Agilent 120
7、0 Hewlett Packard RI,HP1047A Shimadzu RID-10A (/)3,5/3,0 3,0 5 5-6 10,3 ()10 10 10 ASTM D 7419-13 8 1 9.2 /.,().,.,.,.,Si60 ,.(,0,1/).CN-CN-UV-UV-RI-RI-/ASTM D 7419-13 99.2.1 3,0-3,5/RI-.9.2.2 RI-,(1)(),(2).,.9.3 :9.3.1 (SPS),1,0 0,1 1,0 0,1 10,.,.,.9.3.2 (RI-)(=OFF)10 SPS-,/.2 SPS-.9.3.3 ,ASTM D 74
8、19-13 10 :=(1):t1-,t2-,y1-,y2-,.,.,RI-.-5,.,Si60 .1 ,.,.,MS 5,HPLC-0,45.ASTM D 7419-13 11 2 SPS-,9.3.4 k (.9.3.2):=k=(2):t1-,t2-,.,0,4.9.3.5 .9.3.2 ,B():(3):t1-,t2-,.9.4 B SPS-,SPS-:10%-10%-ASTM D 7419-13 12 .,3().,.UV-.3 SPS-9.5 .12.3.2 ,().9.6 (DLS)0,01 5,00 .(0,2%).9.6.1 DLS-,/(S/N)8.4 /.9.6.1.1
9、,SPS-:10%-10%-ASTM D 7419-13 13 RI-,.20 ,9.20 ,.10 .9.7 .10.1.,.:9.7.1 0,1%0,01 10,0 (,.9.3.5).9.7.2 5 .9.7.3%13 ,0,15%.10.10.1 (A,B,C,D E),2,(0,0001)10 .10.2 ,10 .ASTM D 7419-13 14 .10.3 .10.2 B,C,D E.,(.6 8).10.4 (/10).,r2 0,999.13.,Excel ,/.9 .()1,67 1,80.11.11.1 +:11.2 0,5 1,5 ,0,5 .(,2),/,.11.2
10、.1 ,ASTM D 7419-13 15(),(,0,75/0,25)(,0,25/0,75)().4 /(0,2%).()5 (0,1%),(.9.7)18,75 1,5 /=18,75 =12,5 1,5 ASTM D 7419-13 16 2 ,/10 ,/10 A 0,01 0,01 0,1 0,1 1 0,5 D 2 1 E 5 3 11.2.2 ,(.10.1),10 .(.9.3.5)(.3).(),.,.11.2.3 .10 11 .11.2.4 UV-,254.UV-.12 UV-.11.2.5 ,+,ASTM D 7419-13 17(A 10),(B 10),(C 10
11、),(D 10).3 ,.().12.12.1 ,:12.1.1 .9.3.3.,.12.2 .9.6 .12.3 ,0,6%.12.4 +8 10%,ASTM D 7419-13 18 (SQC),D 6299.,/,.12.5 +.,45%,+45%.+5%3 5%.,().6 ASTM D 7419-13 1913.13.1 ,.10.4.,.(ARF):(ARF)=(4)13.1.1 ()ARF 1,67 1,80.ARF .13.2 (%),+(%):(%)=100(5)+(%)=100(6):Ana-,Aar-+,ARF-.14.14.1 +0,1%.ASTM D 7419-13
12、20 8 (/10)9-10 1:2.8%,10.000 +ASTM D 7419-13 21 11 2:7.8%12 UV-15.3 15.1 22 (3 -ASTM International RR:D02-1632.+ASTM D 7419-13 22 )+0,2 46%.+46%,/.(95%-)+:15.1.1 ,3 .3 (%)(R)(r)ASTM D 7419-13 23=0,022*(X+4),%(7)X-%,.15.1.2 ,3 .=0,11*(X+4),%(8)X-%,.15.1.3 -.16.16.1 ;HPLC;+;ASTM D 7419-13 24 D02.04 ,(D 7419-07),.(1).10.4.(2)12.(3).13.1.1.ASTM International -,.,.,.-ASTM International.,.,.ASTM International,100 Barr Harbor Drive,PO Box C700,West Conshohocken,PA 19428-2959,United States.610-832-9585,610-832-9555 E-mail:serviceastm.org ASTM:(www.astm.org).ASTM(www.astm.org/COPYRIGHT/).
