1、 D624608(2013.)1 STANDARD PRACTICE FOR EVALUATING THE PERFORMANCE OF DIFFUSIVE SAMPLERS 2018 ():12.09.2018:3536-18/ASTM -,.9,119049.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM Internationa
2、l ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM Intern
3、ational does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified translations by any Party,except for ASTM International or FBU“CIC“
4、Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D6246-08(2013)1 1 D624608(2013.)1 1 D6246;,.()1 2015.1.1.1 ,4 12 0,5/.0,1/,.1 ASTM D22 D22.04 .1 2013.2013.1998.2008.D6246-08.DOI:10.1520/D6246-08R13E01.ASTM D6246-08(2013)1 2 .,.(.3.2.1),.,.,.,.,.
5、1.2 (1-14)2,D4597,D4598,D4599 MDHS 27.,.1.3,.,.(9).,2 ,.ASTM D6246-08(2013)1 3 ,.,.1.4,.1.5 ,.,.2.2.1 ASTM:3 D1356,D4597 .D4598 .(1995.)4 D4599 ,2.2 :3 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.4 www.astm.org.ASTM D6246-08(2013)1 4 CEN EN 838 ,5 MDHS 27 ,6 MDHS 80 ,6 3.3
6、.1:3.1.1 ,.D1356.3.2 :3.2.1 A ,c,95%(14-19).()RSD(TRSD),A (19):(1)3.2.1.1 ,95%-A (20).5 CEN :rue de Stassart 36,B-1050,.6 HMSO Books,/276,.,SW8 5DT.ASTM D6246-08(2013)1 5 (14),(20)(),.,(),(95%)(95%).(,),.3.2.2 ,.,.3.3 :A-,-A A95%-95%-A c(/3)-(/3)-()(p T),h-()n-,p-ASTM D6246-08(2013)1 6 RSD-()(),RSDr
7、un-,RSDs-()-RSDs RSDt-,-RSD -95%-RSD s-,t0.95(v)-,95%,t-v T-v(/)-ax-x(T,h,v c).-c -A -95%-t-,v-RSDs veff-RSD ASTM D6246-08(2013)1 7 c-h-T-v-4.4.1 ,:4.1.1 :T,h(),v (.4.7 )c.,(T0,h0,v0 c0).c0 ,c0/2.,.(4.6).4.1.2 (),T,h,v c()T,h,v c,p T().ASTM D6246-08(2013)1 8 A ().,(4.2.5).4.1.3 T,h,v c RSDs RSDrun.-
8、.RSDs 7 3=21 (15 ,(1.3)./,RSDrun ,.,RSDs,A1.1 .(12),5%.,.(12),2%.,(3)(,)ASTM D6246-08(2013)1 9 .EN 838 ,10%.4.1.3.1 ,v,.,.4.2 :4.2.1 ().,(6).,.4.2.2 .(4-12),.4.2.3 .,.,.,ASTM D6246-08(2013)1 10 .,0,5-.4.2.4 0,5-,NIOSH(3)CEN(EN 838).4.2.5,t(0)0,5-,.(.(6),0,5-,8-,-t +t.RSDt2,0,5-,:(2)4.3;:4.3.1 .,80%3
9、0C.,.4.3.2 (,-),10%.,90%95%.ASTM D6246-08(2013)1 11 4.3.3 .,s,.,95%-95%():(3)c ,n=8,v=n 1=7.95%-10%c,c ,.4.3.4 ,RSDs=5%,(4),93,3%.2 ,.4.4 :4.4.1 (,),.,.,ASTM D6246-08(2013)1 12 ,.4.5 :4.5.1 .(3)75%.,.,.4.5.2 95%.(MDHS 80)4.6 :4.6.1 .,.(/),.,.3 ,(ppm),(/).4.6.2 ,ASTM D6246-08(2013)1 13 .4.7 :4.7.1 ,.
10、,.5.5.1 ,.,.,.5.2 .,.,-,.ASTM D6246-08(2013)1 14 6.6.1 :6.1.1 5%.6.1.2 12.6.1.3 ,.6.1.4 .6.1.5 ,.6.1.6 ,6.2,.6.2 :6.2.1 0,5/,.6.2.2 ,25 5%,50 5%80 5%,20C.ASTM D6246-08(2013)1 15 6.2.3 ,10 3C,20 3C 30 3C.,.6.2.4 1%.6.3 RSDrun .,16 4,.(12),RSDrun 3%.4 ,6.1 6.2,.7.7.1 ().7.2 ().7.3 ,.8.8.1 ASTM D6246-0
11、8(2013)1 16 (4.6).8.2 ,().8.3 (1-5 A1(,v).8.4 (6-7 A1)80%().,(,7,5).,.(%)(.2 t),4.2.,8.3,.8.5 ,(4.3)().8.6 (12).8.7 ,(3,12)EN 838 ASTM D6246-08(2013)1 17 .8.8 ,(3)EN 838 .9.9.1 .,.9.2 ,A(.1),:(5)RSDT,RSDh,RSDv RSDc (),(4.1.2).9.3 ,.:T=5C T0=25C(6)h=5 .h0=10 .v=0,25/v0=0,50/RSDc=30%ASTM D6246-08(2013
12、)1 18 ,T=5C (95%)15 35C.,v=0,25/(0,5/),95%,(21).5 ,.6,.,.10.10.1 ,.,.95%-.10.2 A95%,Smith Satterthwaite(22,23),.,-.1 :(7)|100%.95%-:(10)95%.GUM()()(,|RSD/1.645|RSD/1.645 ASTM D6246-08(2013)1 20 ,).11.11.1 ,.,EN 838,.,NIOSH()(14-18)/,25%()95%,10%.,.,.,.11.2,.11.3 ()(),.11.4 .11.5 95%-.11.6 ,ASTM D624
13、6-08(2013)1 21 .11.7 ,.11.8 ,10%.6 ,(9.3),.,.12.12.1;ASTM D6246-08(2013)1 22 ()A1.:A1.1 A1.1 (24)/(A1.2),.A1.1 ,1 2 3 4 5 6 7 ASTM D6246-08(2013)1 23 A1.2 :(4)/:1 (ppm)(C)=(.)=(/)=(ppm)=25 19,40 0,11 123 139,2 138,2 138,6 145 2 (C)=(.)=(/)=(ppm)=25,1 3,60 0,11 101,1 (ppm)108,3 110 110,7 112,8 3 (C)=
14、(.)=(/)=(ppm)=25,1 3,60 0,11 12,7 (ppm)14,2 15,2 12,9 14,6 4 (C)=(.)=(/)=(ppm)=26,7 11,90 0,5 11,5 (ppm)14,9 14,6 15,3 15 5 (C)=(.)=(/)=(ppm)=39 2,50 0,11 91,3 (ppm)109 109,2 107,1 105 6 (ppm):7,5 (ppm)=135 139 140 140 140 7 (ppm):0,0 (ppm)=135 144 145 138 139 (ppm)=50 RSDrun=0,008693183 ASTM D6246-
15、08(2013)1 24 :=95%-=28,65%31,03%=18,12%=6,40%RSDs=2,86%:88,90%2,21%0,03%2,61%0,84%5,33%0,07%ASTM D6246-08(2013)1 25 (1)Brown,R.H.,Charlton,J.,Saunders,K.J.,The Development of an Improved Diffusive Sampler(),.42,1981.,.865-869.(2)Bartley,D.L.,Doemeny,L.J.,Taylor,D.J.,Diffusive Monitoring of Fluctuati
16、ng Concentrations(),.44,1983.,.241-247.(3)Cassinelli,M.E.,Hull,R.D,Crable,J.V.,Teass,A.W.,Protocol for the Evaluation of Passive Monitors in Diffusive Sampling(),.,1987.,.190-202.(4)Kennedy,E.R.,Hull,R.D.,Performance of the DuPont Pro-TekR Formaldehyde Badge and the 3M Formaldehyde Monitor,(DuPont Pro-TekR 3),.47,1987.,.94-105.(5)van den Hoed,N.,Halmans,M.T.H.,Sampling and Thermal Desorption of Tube-Type Diffusive Samplers:Selection and Performance of Adsorbents,(:),.48,1987,.364-373.(6)Bartley,
