1、 D6047-17 5-(ENB)(DCPD)-(EPDM)STANDARD TEST METHODS FOR RUBBER,RAW DETERMINATION OF 5-ETHYLIDENENORBORNENE(ENB)OR DICYCLOPENTADIENE(DCPD)IN ETHYLENE-PROPYLENE-DIENE(EPDM)TERPOLYMERS 2018 ():23.04.2018:3413-18/ASTM -,.9,119049.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstanda
2、rt.ru/(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing a
3、nd Materials(ASTM International)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Rep
4、roduction of the specified translations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D6047-17 1 D6047-17 5-(ENB)(DCPD)-(EPDM)1 D6047;,.().1.1.1 5-(ENB)(DCPD)-(EPDM).0,1 10%.1.2 ENB DCPD ,.
5、,(FTIR).1%ENB%DCPD 1 ASTM D11 ,D11.11 .1 2017.2017.1996.2015.D 6047-15.DOI:10.1520/D6047-17.ASTM D6047-17 2 ().1.3,.1.4 ,.,.1.5 -,(TBT).2.2.1 ASTM:2D297 D1416 (1996.)3D3568 EPDM(-),D3900 -(EPM)-(EPDM)2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM 3 .www.astm.org.ASTM D6047-
6、17 3 D4483 ,E168 E932 E1421 ,(FT-MIR):2.2 ANCHA:4 3.3.1 .ENB -1681-1690-1,ENB.DCPD -1605-1610-13.2 .ENB 1690,DCPD.-1 ENB EPDM.DCPD 1610-1 4 ,ANCHA,47,11,.94a.DCPD ASTM D6047-17 4 EPDM.3.3 :.3.4 .D1416,67 74,D297.4.4.1,150C 10 .4.1.1 -()400,4.4(,22).-,.4.1.2 -;,.:127 (0,005)15 35 (D3900).4.1.3 -EPDM
7、EPDM 22 16 (7/8 5/8 .),400 (NaBr,NaCl).,.4.2 ,36 .ASTM D6047-17 5 4.3 ,.,.4.4 ,400-6000-1 ()1%T .2-14.4.1 ,.,.,-,(.6).,.,.X1.(.).(DTGS).E168.E932 E1421.ASTM D6047-17 6 5.5.1 -(,0,2 0,5).-,125 5C,10 60 10.2 .5.1.1 .,.5.2 -,4.1.2,(0,04-0,06)-5.1.-,.,-.5.3 (4.1.3).(0,3)EPDM ,.1 2 3 .(.).,ASTM D6047-17
8、7 .,.6.6.1 :6.1.1 :6.1.1.1:2-16.1.1.2 :,90.6.1.2 ,(P)(P06.1.3 ,log).().10A=-log ,:10(P/P0(1)6.2 :6.2.1 :6.2.1.1:2-16.2.1.2 :32,20;:32,20.6.2.2 (P06.2.3 .(P)(A),6.1.3.).ASTM D6047-17 8 7.7.1 ,0-10%.,.1H(NMR),.,1H NMR(,-120C;ENB ENB).0%(),2%,5%10%.57.2 6,5 ,7.1.7.3 8,.7.4 (),.5 ENB,ExxonMobil Chemical
9、 Polymer Laboratories,P.O.Box 5200,Baytown,TX 77520.DCPD,UniRoyal Chemical Company,Chemical Characterization Lab,Benson Road,Middlebury,CT 06749.,-ASTM International.1,.ASTM D6047-17 9 8.8.1 ,5.8.2 6.8.3 :8.3.1 ().8.3.2 ,2703-1 2750-1.,1,2(.1).1 FT-IR 0 1()-1 0 2()ASTM D6047-17 10 .2 FT-IR 1 .3 FT-I
10、R 2 1:OD=2708-1 -1 2:OD=2688-1 -1 ASTM D6047-17 11 8.3.2.1 1:2708-1()2450-18.3.2.2 2:2668 ()(.2).-1()2450-18.4 :()(.3).8.4.1 (OD),1/A,A .8.4.2 ENB (OD)(9 )1681 1690-1 Ht=:1681 (0,751688+0,251689(2)ENB .4 EPDM .4 V 5600 1688-1()()ASTM D6047-17 12 8.4.3 ,8.4.2,ENB ,().ENB,8.4.5,ENB ENB ,ENB .8.4.4 DCP
11、D (OD)(9 )1601 1620-1 Ht=(:1601 1610(3)DCPD .8.4.5 ,8.4.4,DCPD ,().DCPD,8.4.5,DCPD DCPD ,DCPD .9.9.1 :9.1.1 ENB DCP :ENB=xx,x%DCPD=xx,x%10.ENB6 10.1 ,6 -ASTM International RR:D11-1081.ASTM D6047-17 13 ,D4483.,.10.2 (.),(ITP),10.5 10.8.-,.10.3 ITP 1 1996.()ENB ;2 .ENB.10.4 ,.,-,.,-.10.5 .1;.,r R (r)(
12、R),ASTM D6047-17 14 ,.10.6 ,r,(%ENB ),.1.,r(),.10.7 ,R,(%ENB ),.1.,R(),.10.8 (r)(R)3,0 11,0%ENB,2,6 11,0%(.1.)10.9 ,().,().10.10 DCPD .ASTM D6047-17 15 1.(1)%ENB 1 ITP.2 Sr .SR .r .R .(r),%.(R),%.Sr r(r)SR R(R)ENB003 0,08 0,110 0,311 A 0,137 0,388 A ENB005 3,70 0,030 0,083 2,26 0,167 0,473 12,77 ENB
13、002 4,99 0,059 0,168 3,36 0,171 0,484 9,70 ENB004 6,78 0,062 0,177 2,60 0,259 0,733 10,81 ENB001 10,92 0,066 0,186 1,70 0,404 1,143 10,47 0,159 2,6 0,758 11,0 A ENB.ENB003.11.DCPD7 11.1 ,D4483.,.11.2 (.),ITP,.-,.11.3 ITP 1 1998.(,)DCPD.ITP ,2 .7 -ASTM International RR:D11-1081.ASTM D6047-17 16 .D448
14、3 .,.,95%.11.4 ,r,.2 .,r(),.11.5 ,R,.2 .,R,.11.6 ,(r)(R),.2.,10.6 10.7.11.7 ,().,().ASTM D6047-17 17 2.(1)DCPD 1 ITP.2 Sr .SR .r .R .(r),%.(R),%.Sr r SR R 2,67 0,012 0,033 0,076 0,213 A 3,20 0,034 0,096 0,102 0,288 9,57 0,046 0,129 0,063 0,178 12.12.1 (DCPD)(DCP);-(EPDM);(ENB)()X1.X1.1 ,.(),.,D6047
15、,(),.,ASTM D6047-17 18 ,.X1.2 FTIR,.,.X1.3 ,(,),.,.,.X1.3.1 .X1.3.1.1 (P0X1.3.1.2 (P).wX1.3.1.3 :)().Aw=-log10(Pw/P0(X.1.1)X1.4 ,(.X1.3.1.1).,(,4),FTIR.ASTM D6047-17 19 X1.5 ,.,.(15)X1.6 (A),(X1.4).X1.7 .,(),(),.:X1.7.1 ,.,.1.1 .X1.7.2 (X1.3.1.3)S.X1.7.3 ,*:A*=A(1 SAw(X.1.2)(A*)(A),6.2,.ASTM D6047-17 20 ASTM International -,.,.,.-ASTM International.,.,.ASTM International,100 Barr Harbor Drive,West Conshohocken,PA 19428.610-832-9585,610-832-9555 :serviceastm.org ASTM:(www.astm.org).,222 Rosewood Drive,Danvers,MA 01923,Tel:(978)646-2600;http:/.
