1、 D 550412 STANDARD TEST METHOD FOR DETERMINATION OF SULFUR COMPOUNDS IN NATURAL GAS AND GASEOUS FUELS BY GAS CHROMATOGRAPHY AND CHEMILUMINESCENCE 2013.():2113-13/ASTM :16.09.2013 -,.9,-49,-1,119991.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM International)10
2、0 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM Internatio
3、nal)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specified t
4、ranslations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D 5504-12 1 D 550412 1 D 5504;,.().1.1.1 ,.,.,(10)(1 000 000).0,01 1 000/3,1 3.1 ASTM D03 D03.05 .1 2012.2012.1994.2008.D 5504-08.D
5、OI:10.1520/D5504-12.ASTM D 5504-12 2 1.2 .1 .1.3 .,.(1.1).,.1.4,.,-.1.5 ,.,.2.2.1 ASTM:2 D 1072 2 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.ASTM D 5504-12 3 D 1945 D 3609 D 4468 E 177 ASTM E 594 -,E 691 3.3.1 -.,.,3,4 .4 .,.3.2 3(),.3 Restek Corporation,110 Benner Circle
6、 Bellefonte,PA,16823.4 DuPont.ASTM D 5504-12 4 3.3 ,-(FID).(SCD).,-.3.3.1 SCD SCD .,SCD SCD,-.301 (USEPA).3.3.2 ,.SCD.4.4.1 ,.ASTM D 5504-12 5 4.2 ().,.,.4.3 ,.,.,.,.,.4.4 ()(D 1945).ASTM D 1072 D 4468 ASTM D 5504-12 6 D 4010 D 4884 .5.5.1 ,.0,05 (3).5.1.1 ,./,10:1 50:1 ,.5.1.2 .,1%,.5.1.3 ,ASTM D 5
7、504-12 7-(FID),.(SCD).5.1.3.1-(FID),.1 E594 .-.-SCD ,-.,.,.,-.,.5.1.3.2 (SCD):(1)105,(2)5 S/,(3)106 ,(4),(5).5.1.3.3 ,ASTM D 5504-12 8 -,.(),(480)(260).5.1.3.4 SCD (),-.()(20).(480),.,.5.2 .,60 0,54 ,5 .,.2 .1.,SCD,200C.ASTM D 5504-12 9 1 4 (30 0,32).2 .,.,1,458?S 16,363 1,730-16,423 1,733?S 16,425
8、2,053?S 16,592 2,550?S 16,692 2,586?-16,983 2,679?S 17,183 2,815?S 17,319 i-4,422?S 17,631-1 5,263?S 17,754-5,578q-p-17,788 5,804?S 17,913-2 5,938?S 18,063 2,2-DMO3 6,009?S 18,139 c-2 6,409 o-18,279 3-Me-1 7,463-18,448 i-8,035?S 18,450-1 8,500?S 18,567 8,583?S 18,642 2-Me-1 8,717 18,767 n-8,860?S 18
9、,911 8,983?S 19,008 t-2 9,096?S 19,125 9,117?S 19,292 o-2 9,321?S 19,979 2-Me-2 9,463 2,2,4-20,227 9,617-20,308 2,2-DMO4 9,898?S 20,550 i-10,222?S 21,396 10,392?S 21,733 3-Me 10,525?S 21,808 CP/2,3-DMO4 10,733-22,033 2-MO5 10,883?S 22,208 3-MO5 11,269?S 23,046 t-11,278?S 22,417-1 11,392-23,631 n-11,
10、625 23,717 n-11,720-25,134 11,779 25,225 MeCyC5 12,457 25,328 13,154 25,433-13,154 25,550 5.3 :5.3.1 ASTM D 5504-12 10 c 0 1 2 .5.3.2 .-,SCD .:5.3.2.1 .5.3.2.2 .5.3.2.3 .2 ,:150C 0,5 3,:150C 100%-(FID):250C H2:200 3/Air:400 3/(He):20 3/(HCZ):800C H2:100 3/:40 3/SCD:0-1 6,0 :1,5 30C 15,0/200C 200C -(
11、)1,10 :11 3/5.3.2.4 .5.3.2.5 .6.2 :,ASTM D 5504-12 11 .,.6.1 .,.1:6.1.1 ,.,./(SCD).()ASTM D 5504-12 12 6.1.1.1 0,1C.6.1.1.2 2.6.1.1.3 0,01,NIST S .,D3609.,(10).6.2 ,.,.,.,NIST NMi.6.2.1 ,.6.2.2 .(H2S)(COS)(CH3SH)ASTM D 5504-12 13 6.2.3 .(CH3CH2SH)1-(CH3CH2CH2SH)2-(CH3CHSHCH3)(CH3SCH3)6.2.4 -.(CS2)(C
12、H3SSCH3)6.2.5 ,.6.2.6 ,SCD ,-().(ACS Grade)160 ,1 10-,.6.2.7-.,.,(.5.1.2).6.2.8 -,.6.2.9 ASTM D 5504-12 14 -,.6.2.10 SCD.7.7.1 .,.,:7.1.1 ,.7.1.2 .2 ()ASTM D 5504-12 15 7.1.3 .7.1.4 ,.1,.1 ,.2.2 3 .3 7.2 SCD().-(FID),FID/.,/.,()ASTM D 5504-12 16 H2S(.4).,.,90%110%,.,10%.,.4 7.2.1 -SCD.,ASTM D 5504-1
13、2 17.,(.5 6).5 .7.2.2 ./.SCD.,2,4 H2S CH4 10/18/96 2,4 H2S ASTM D 5504-12 18.,.,.7.2.3 FID FID ,.,.6 8.8.1 ,2,4 H2S CH4 10/18/96 2,4 H2S ASTM D 5504-12 19,.,.10 .8.2 SCD ,;.SCD.8.2.1 ,.,(3)5%.,.,5%.8.2.2 .,().8.2.3 ,(3)5%.8.2.4 SCD ;,5%.ASTM D 5504-12 20 ,SCD-(FID),.8.2.5 :Fn=(Cn/An)(1):Fn-,Cn-,An-.
14、(Fn)5%o Fn .1 ,.4 .3 ,.3 .C%S()/3 (H2S)34,08 1,1857 94,08 1,39 (COS)60,08 1,24 53,37 2,46 (MeSH)48,110 0,8665 6,2 66,65 1,97 (EtSH)62,134 0,8391 35,0 51,61 2,54 (DMS)62,134 0,8483 37,3 51,61 2,54 (CS2)76,14 84,23 3,11 2-(iPrSH)76,160 0,8143 52,6 42,10 3,11 t-(tBSH)64,220 0,8002 65,0 49,93 2,62 1-(nP
15、rSH)76,160 0,8415 67,0 42,10 3,11 (MES)76,160 0,8422 67,0 42,10 3,11 (TP)84,14 1,07 84,16 38,03 3,44-(-BuSH)90,186 0,8299 85,0 35,56 3,69-(-BuSH)90,186 0,8343 88,7 35,56 3,69 (DES)90,190 0,8362 92,0 35,55 3,69-(n-BuSH)90,186 0,8416 98,5 35,56 3,69 (DMDS)94,200 1,0625 109,7 68,08 3,85 (DEDS)122,252 0
16、,9931 154,0 52,46 5,00 ASTM D 5504-12 21 4 SIEVERS 8 PTUBES NEW DET MEGABORE/20PSIG He 5/6/91 SPLITLESS :DATA:SVPT.Q :24 1991 17 37.:5,00%.:5,00%.:0,000 RF:60,00e-6:1,000 ./.cvl.1,461 1 GC Signal 1 0,9100 1 59,60e-6 1 H2S 1,595 2 GC Signal 1 0,2610 1 36,92e-6 1 COS 2,861 3 GC Signal 1 0,3570 1 50,11e-6 1 MTM 3,529 4 GC Signal 1 0,4150 1 50,28e-6 1 ETM 3,809 5 GC Signal 1 0,4943 1 49,02e-6 1 DMS 4,185 6 GC Signal 1 0,2289 1 0001001 1 CS2 4,481 7 GC Signal 1 0,3904 1 50,04e-6 1 1PM 5,179 8 GC Sign
