1、 545502011 27 2002.184-1 -,(),-4,-()2 160 3 29 2011.634-4 ATM 57742009 .(ASTM D 57742009 Standard test methods for rubber Chemical nalysis of xtractables).,-/,.-1.52004(3.5).-,-,5 1.02012(8).(1 ),-.().,-(gost.ru),2013 ,-II 5455020111 .12 .13 .24 .25 .26 .27 .28 .39 .310 .411 .412 ().513 .514.615.616
2、 .617 .618 .819 .920 ().1021 .1022 .1023 .1024 .1025.1126 .1127 (,).1228 .1229 .1230 .1231 .1332 .1333.1334 .1335 (,-).1336 .1437 .1438 .1439 .1440 .1441.1442 .14 ()-,.15.16III 545502011 Synthetic rubbers.Determination of the mass fraction of extractables 201307011 (A,B,C,D),-(SBR).-,.,1.,.,-.2 :572
3、5-12002 ()-.1.532282008 .1.-.545542011 .,7452003 .177074(104283,478880).,.260379.311877.432877.578978.1830087 .2533682 .,-2710986 .2916991(64877).2925191(385-184).1.-,1 -1 545502011 ,-.,.,().-,-,-.,.3 ,.,2.4 ()100 3 10,20,40 .5 100 3 .,.5 .,.100 ,(,).6 6.1 400500 3.6.2 .6.3 .6.4 .745 100?75?8.6.5 ()
4、,105 3,0.-,(100?3).6.6 2-140 2-190,2-250 25336.6.7 54554.27109.6.8 53228.6.9 .7 7.1 7.1.1 (ETA)ETA 70 (18300)30-.4 2 545502011,.1.-,3.7.1.2 (H-ITM)75 25 (5789),92 .7.1.3 2603.8 8.1 8.2 8.3.8.2 450 0,1.(100?5)(0,25?0,05),.,.4 -0,1.0,1,.(0,1).8.3 250 (0,25?0,05),32.0,1 -,(100?5),.(0,1).0,1%1.8.4 0,5.6
5、 -10 50.,-(,),-:-),1,51,7 8994 -0,177,-,.,.-,;-b)56 38?38,50?50,-.9 9.1 6 .9.2 100 3 (ETA H-ITM),3 545502011.,.-,8.4.9.3 10 (-1).,20 3-,100 3.9.4 20 (-1).,20 3-,100 3.9.5 40 (-1).100 3.6,0 ,2?2?2,-,100 3-(.7).10 (1).,20 3-,.100 3 20 (1).,20 3,-.100 3 40 (1).100 3.9.6 5 ,.9.7 -.1 (105?3)3,0.,(100?3)0
6、,0002.(100?3),.10 ,%,=()ABA?100,(1),;,.11 11.1 ,3 ,3.-,3.3.,-5725-1.4 54550201111.2,11.3.-,-.11.3 1 ,.-.1.1 1 ,%Srr(r)SRR(R)630,050,1120,3171,050,1370,391,29532,450,0820,2320,720,4581,304,01339,730,1320,3740,940,2890,822,06 34,080,1110,3140,920,3220,912,29 :Sr ;r ();(r)();SR ;R ();(R)().11.4 ().-,.1
7、2 ()8.1 8.4,6.250 3-.100 3 0,1 NaOH,.-.13 ,-.:,-,.-,.-.5 54550201114 53228.-1-250-29/32 25336.-1-100(250)-29/32 25336 -,(10001200),(1012).-2-250 25336.1-2-2-1-0,01;1-2-2-5-0,02 29251.1-100-2,1-1000-2 1770.2-2-100 29169.15 15.1 15.1.1 (ETA)7.1.1.,.15.1.2 (H-ITM)7.1.2 -.,.15.2 15.2.1-(0,1%-)0,1 26,2 3
8、 c(NaOH)=0,01/3 .,.15.2.2 (0,2%-)0,066,453c(NaOH)=0,02/3 50 3(H-ITM).15.3 (NaOH)=0,1/3 (NaOH)=0,1/3.4328,(NaOH)=0,1/3(0,1)(NaOH)=0,01/3(0,01),(NaOH)=0,02/3(0,02).16 8.1 8.4.17 17.1 ,17.1.1 6 0,0001.17.1.2 100 3 (.15.1)-,-,.,.,8.4.17.1.3 10 (-1).250 3,-6 545502011 20 3,.100 3.17.1.4 20 (-1).,20 3,.-2
9、50 3.-.6,0 ,2?2?2,-,100 3-(.15.1).1.250 3,20 3,.100 3 1.20 3-,.,.17.1.5 250 3 100 3.100 3 (.2026).100 3 -250 3.100 3 (.2026).17.1.6 100 3 -(NaOH)=0,1/3 .-,100 3,.NaOH,.100 3 -(NaOH)=0,1/3 .(-),-,.17.2 ,17.2.1 6 .17.2.2 100 3 H-ITM(.9.2).-,8.4.,.17.2.3 10 (-1).250 3,-20 3,.100 3.17.2.4 20 (-1).,20 3,
10、.250 3.6,0 ,2?2?2,-,100 3-(.15.1).1.250 3,20 3,.100 3 1.7 545502011 20 3-,.,.17.2.5 100 3.15 (1).-250 3(250 3)-20 3,.1.17.2.6 100 3 .15 (1).250 3(250 3)20 3,.2.17.2.7 250 3(250 3)100 3 17.2.4.17.2.8 100 3 -.(NaOH)=0,1/3 .,100 3 -.NaOH,.100 3 -(NaOH)=0,1/3 .(),.2 0,1%,17.2.6.18 18.1 1,%,1=0 25,JKLA,(
11、2)J NaOH,100 3,-250 3(),3;NaOH;L .-,:284 ,346 ,315 -50:50;,.18.2 1,%,1=0 250404,(,)JXY KLA?,(3)J NaOH,100 3,-250 3(),3;X NaOH,-1(),3;8 545502011Y NaOH,-2(),3;NaOH;L .,:284 ,346 ;315 50:50;,.19 19.1 3.-3.,-5725-1.19.2,19.3.-,-.19.3 1().-.-.,-.19.4 1 2 .2 1 ,%Srr(r)SRR(R)63,210,04570,1294,00,0800,2267
12、,154,650,06210,1763,80,1450,4108,846,160,08040,2283,70,1910,5418,834,990,07010,1984,00,1820,51510,3 :Sr ;r ();(r)();SR ;R ();(R)().19.5 ,r,R,(r)(R)-.r R,2,-.9 54550201119.6 ,2,26.626.9.20 ()100 3,-(.17.1.5),HCl 0,05/3 -.21 .,.,-,.22 22.1 ,(0,05)3118,(HCl)=0,05/3(0,05).22.2 22.2.1 -,0,1%-(.15.2.1).22
13、.2.2 ,0,1%-.22.2.3 ,0,1%-.22.2.4 ,.15.2.2(H-ITM).23 8.1 8.2.,(.17.1.5).24 100 3,(.17.1.5),c(HCl)=0,05/3(0,05).,100 3 (.17.1.217.1.5),(.).HCl,-,HCl,.10 3 ()c(HCl)=0,05/3(0,05).(),-.-,.-H-ITM.10 54550201125 2,%,2=0 25,MNPA,(4)HCl,(),3;N HCl;.,-:306 ,322 ,368 ,384 ,337 50:50,353 50:50,345 50:50;,.26 26
14、.1 3.-3.,-5725-1.26.2,-,26.3.-,-,.26.3 1().-.-.-,.26.4 3 -.3 1 ,%Srr(r)SRR(R)30,0440,00850,024154,70,04480,127290,040,0130,00560,0158122,00,03150,0891690,050,0190,00930,0263139,00,03260,0923490,060,0360,00970,027576,30,06260,177490,0 :Sr ;r ();(r)();SR ;R ();(R)().11 54550201126.5 ,r,R,(r)(R).r R,2,
15、-.26.6 ()r ,3.,-r,3(),-,.26.7 ()R ,3.,-R,3(),.26.8 (r)(R),26.6 26.7 r R.(r)(R)-.,-.26.9 ,-()-.,.27 (,)-411.,.28 -.-,-.29 6.30 7.12 54550201131 8.32 9.33 3,%,3=100()AA?I(+D),(5),;I ,;,%;,%;D (),%.()D ,D=EF100,(6),(100-);F :=100+-.34 34.1(),0,28%.,-().34.2,0,34%(.34.1).34.3 ,H-ITM.35 (,-)1 ,-.,-,.-.13
16、 54550201136 -,-,.-,.-,.37 37.1 6.16.4.37.2 ,(130?3).38 7.39 8.40 40.1 1 .40.2 150 3 400 3,.40.3 10(1).,10 3-.40.4 150 3 ,-15.40.5 .15 -(130?3).41 33.42 .14 545502011(),.1,5721-12002IDT 5725-1:1994 ().1.532282008MOD 76(1):2006.1.-.545542011MOD 31822007 .,-7452003 177074MOD 1042:1983 .-1)MOD 4788:1980 .-2)260379 311877 432877 578978 1830087 2533682MOD 1773:1976 .()MOD 3819:1985 .MOD 479:1981 .-2710986 2916991MOD 648:1997 .-2925191MOD 385-1:1984 .1.1)1042:1998.2)4788:2005.-:-IDT ;-MOD .15 54550201
