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ASTM_D_3120_-_08_rus.pdf

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1、 542882010 27 2002.184-,1.02004 .1 -()-,42 31 3 27 2010.1129-4 312008 -(ASTM D 312008 Standard test method for trace quantities of sulfur in liquid petroleum hydrocarbons byoxidative microcoulometry).-1.52004(3.5).-,5 -,-.().-,2012 ,-II 5428820101 .12 .13 .24 .25 .26 .37 .58 .79 .810 .811 .812 (QA).

2、1013 .1114.1115 .14 X1()(QC).14 X2(),14.15 ()().17 542882010III Light liquid petroleum hydrocarbons.Determination of trace quantities of sulfur by oxidative microcoulometry 201207011 1.1 3,0 1000/,-26 274 (80 F 525 F).,(4806),(4814),(Ed75-Ed85)(5798),10%.-.02.03 .1.2 ,1.1,1000/,-.,.1.3,.,-,.-(/).1.4

3、 -,.-,.79.2 :1193 -(ASTM D 1193,Specification for reagent water)1298 ,()API (ASTM D 1298,Test method fordensity,relative density(specific gravity),or crude petroleum and liquid petroleum products by hydrometermethod)4052 (ASTM D 4052,Test method for density and relative density of liquids by digital

4、 density meter)4057 (ASTM D 4057,Practice for manual sampling of petroleum and petroleum products)1 5428820104177(ASTM D 4177,Practice for automatic sampling of petroleum and petroleum products)4806 -,(ASTM D 4806,Specification for denatured fuel ethanol for blending with gasolines for use as automo

5、tive spark-ignition enginefuel)4814 (ASTM D 4814,Specification for automotive spark-ignition engine fuel)5798 (Ed75-Ed85)-(ASTM D 5798,Specification for fuel ethanol(Ed75-Ed85)for automotive spark-ignitionengines)6299 (ASTM D 6299,Practice for applying statistical quality assuranceand control charti

6、ng techniques to evaluate analytical measurement system performanc)OSHA 29 FR,1910.1000 1910.1200(OSHA Regulations 29 CFR,paragraphs1910.1000 and 1910.1200)3 3.1 ,900 1200 ,50%80%20%50%(,.).-,-,.,(I?t),c,-,.3.2 -I3?+SO2+H2O?SO3+3I+2H+.(1)3I?I3?+2.(2)3.3 SO2-,.4 4.1 -,.-,.5 5.1 ,-10 ,1000 .5.1.1 ,.5.

7、2 -(,Ni,V,Pb .)500/(ppm).2 5428820106 6.1 ,-.1 ,-.6.2 2.6.3,900 C1200,SO2.-.6.4 ,-3 5428820101 (100);2 ;3 ;4 ;5 ;6 ;7 -1 1 ;2 ;3 ;4 ;5 ;6 ;7 ;8 ;9 ;10 2 ,.,.-.6.5 :;:;.,Ag/AgCl,.,-.,-,.,.,.6.6 ,-.-.,.6.7 (),-(mV)-.6.8 .,-.6.9 .,-,SO2.-.,.6.10 .,5 80 3.80%.6.11 .6.11.1 .(-).-.,.(.6.11.2).6.11.1.1 ().

8、-,-.-,.6.11.1.2 ,-,-.4 5428820106.11.2 -.,-,.-,0,5 1,0 3/(.).,.-,(),.6.12?0,01.7 7.1 .,1).,.7.2 .,-,1193,II III.7.3 .7.4 (CH3COOH).,1,05/3(.-.).7.5 (85%.).(H3PO4)(.-.-).7.6 .(HP)(99,995%),-(.).7.7.(HP)(99,995%),-().7.8 .-.7.9 .0,5 (KI)0,6 (NaN3)500 3 ,6 3 -(CH3COOH)1000 3 .-.7.10 (NaN3),(.-.).7.11 (

9、KI),.7.12 (KCl),.,1M Ag/AgCl.7.13 (KNO3),.,1M Ag/AgCl.7.14 (I)20 .1),American Chemical Society,Washington DC.,Annual Standards for Laboratory Chemicals,BDH Ltd.,Poole,Dorset,U.K.,United States Pharmacopeia and National Formulary,U.S Pharmaceutical Convention,Inc.(USPC),Rockville,MD.5 5428820107.15,.

10、(,).-,(.).().7.16 FW()184,26;17,399%.S.().7.17-FW 146,29;21,92%.S.().7.18 ()FW 134,20;23,90%.S.1 ()-.2 ,.7.19,(1000 S/3);,-0,5748 0,4652 -0,4184 100 3.-(),13(.)S/3=ABC1010063,(3),;S ;(),%.1 ,.-3.2 /,.3,-,.1 ,S/3,S/3,3 ,3500100025505010005100105002100.6 542882010 2 -,S/,S/3 1 2 3 2,50,21,02,50,5 500,

11、25501,0 2500,5102502,5 5001,0255005,0 10002,5501000 3 ,S/3,3 ,3,S/31021000,21051000,55021001,05051002,550101005,050051002550010100501000A251002505005001000A1000AA().7.20,;,1,-.7.21 (QA).,-,-.(QA),11.-QA ,.8 8.1 .-.8.2 -,.7 5428820109 9.1 4057 4177.-,-.,.9.1.1(,-.,-).9.2 ,-.10 10.1 -.10.2 ,.10.3 .10.

12、4 ,.10.5.10.6 ().10.7 -.11 11.1 ,.,.11.2 2 .,3.-,S/3,=A B100,(4),S/3;,3.1 .-,.-,-.2 ,-.11.3 ,4.8 54288201011.4 .-,.11.5 .80%.4 ,S/,S 5,080 0,250,5 50600,03 1,51,0 250300,03 5,02,5 500200,05 5,05,0 1000100,05 1011.5.1 ,-,10%-,.,-10%-,.-,.11.5.2 ,-.,?0,01.11.5.3 ,.-.11.5.4 :,.-,(.).,-,-.(),.2 (.).1,-.

13、120.,.2 .,-,.11.5.4.1 ,-.9 542882010,-,.11.5.5 .().,.,.,-0,5 1,0/.11.5.5.1 ,-,.11.6 .11.6.1 ,-11.311.5.5.-,.(12).11.6.2 ,-11.311.5.5.-.,(y),(x).,.,SO2.,-SO3 .,-,.75%.75%,-.75%90%(3).11.7 ,SO2(),75%,-.,-.11.8 .-.-.12 (QA)12.1 ,-(Q).12.2 /(Q/QA),.12.3 /(Q/QA),1.10 54288201013 13.1 ,9,.-,.13.1.1 (/).13

14、.1.2 (/).13.2 .-11.311.5.5 .13.3 .13.3.1 ,.,.13.3.2 ,-,.13.3.3 .13.4 ,.13.5 ,(1298,4052 ),.,.14 14.1 ,/(ppm),-:=CMK1000(5)=CVD1000,(6),(-),;,-,V?D,;./-,/;V ,-,M/D,;D ,/3;1000 /(ppm).11 54288201015 15.1 ,.-(I)RR:D02-1036.(II)16 ,8.-(PLOQ),3/S,-5/S (.RR:D02-1546 RR:D02-1547).15.1.1 15.1.1.1 I.,-,X -r=

15、0,2802X(0,7901).(7)15.1.1.2 II.3 100/5 40/.:003194(X+7,4502)1,3226;:0,08520(X+0,65758),X ,/.15.1.2 15.1.2.1 I.,-,-12 542882010 3 (),X -R=0,5793 X(0,7901).(8)15.1.2.2 II.3 100/5 40/.:0,1470(X=7,4502)1,3226;:0,5152(X+0,65758),/.15.2 (SRM)(NIST).:SRM 2298(4,6/S)2299(13,6/S)SRM 2723(10/S).-SRM 2299 2723

16、 .SRM 2298 ,1,25.13 542882010 1()(QC)1.1 ,(QC).1.2 ()-QC(.6299 ASTM MNL 71).1.3 -QC (.6299 ASTM MNL 71).,.1.4 ,QC ,-.QC .QC ,.,QC.-QC -,.1.5 ,.QC .QC -.6299 ASTM MNL 71).1)ManualonPresentationofDataControlChartAnalysis,6thed.,ASTMInternational,W.Conshohocken,PA 19428.14 542882010 2(),142.1 2.1.1 ,14,(),(I3-+2e?3I-).-()Qt.2.1.2 ,i (-),Q(),.e.Q=iT.-Q/F,F ,96500.2.1.3 :=,?Q CFC()16;(2.1)S=A 2?0,1260101610 36R()?96500C A sCf,(2.2),2;0,1 ,/;2 ,/;60 ,/;10 3 ,/;16 -,/;R ,V/R=1():Q(A?s)=AR 0,12601032?()

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