1、 542762010 542762010II 27 2002.184-,1.02004 .1 -,()-,42 3 -27 2010.1109-4 ATM 168802 -(ASTM D 168802 Standard test methods for copper in water).-1.52004(3.5).-,5 -,-.().-,2011 ,-542762010 III1 .12 .13 .24 .25 .36 .3 -.37 .38 .39 .310 .411 .412 .413 .514 .515 .5 -.616 .617 .618 .619 .720 .721 .722 .8
2、23 .824 .9 -.1025 .1026 .1027 .1028 .1029 .1130 .1131 .1132 .1133 .1134 (QC).12 ()().151 201207011 1.1 -:-0,05 5/715 -50 500/1624 -5 100/25331.2 .0,45 (325)-.1.3,.-.1.4 ,.-,-.3,5,8 13.2 :858 (ASTM D 858,Test methods for manganese in water)1)1066 (ASTM D 1066,Practice for sampling steam)1)1068 (ASTM
3、D 1068,Test methods for iron in water)1)1129,(ASTM D 1129,Terminology relating to water)1)1192 -(ASTM D 1192,Specifi cation for equipment for sampling water and steam in closed conduits)1)1),11.01(Annual Book of ASTM Standards,Vol 11.01.)542762010 Water.Methods for determination of copper 5427620102
4、 1193 (ASTM D 1193,Specifi cation for reagent water)1)1687 (ASTM D 1687,Test methods for chromium in water)1)1691 (ASTM D 1691,Test methods for zinc in water)1)1886 (ASTM D 1886,Test methods for nickel in water)1)2777 ,-19 (ASTM D 2777,Practice for determination of precision and bias of appli-cable
5、methods of committee D-19 on water)1)3370 (ASTM D 3370,Practices for sampling water from closed conduits)1)3557 (ASTM D 3557,Test methods for cadmium in water)1)3558 (ASTM D 3558,Test methods for cobalt in water)1)3559 (ASTM D 3559,Test methods for lead in water)1)3919 -(ASTM D 3919,Practice for mea
6、suring trace elements in water by graphite furnace atomic absorption spectrophotometry)1)4841 ,-(ASTM D 4841,Practice for estimation of holding time for water samples containing organic and inorganic constituents)1)5810 (ASTM D 5810,Guide for spiking into aqueous samples)1)5847 (QC)(ASTM D 5847,Prac
7、tice for writing quality control specifi cations for standard test methods for water analysis)2)3 3.1 ,1129.4 4.1 ,-.0,01%,(CuFeS2).4.2 -;-.,-.,.4.3 ,-,.1),11.01(Annual Book of ASTM Standards,Vol 11.01.).2),11.02(Annual Book of ASTM Standards,Vol 11.02.).542762010 35 5.1 (.).-,-(),.,.5.2 (),(.)I 119
8、3.-,-,()-.II.6 6.1 1066,1192 3370.6.2 (HNO3)1,42 -,2 ,2/.,0,45 (325).48.-7 7.1 ,.7.2 0,05 5/.-5/.7.3 ,-,-.-.8 8.1 -.-().,(3557),(1687),(3558),(1068),(3559),(858),(1886)(1691).9 9.1,(8000/),(5000/-),(2000/),(1000/),(10/).9.2 -().1 -.542762010410 10.1-,324,7.2 -.,324,7,.10.1.1 .-.10.2 .11.6.10.3 .11.7
9、.10.4 .,-.11 11.1 ,(1,0 =1,0 Cu):1,000 250 15 (HNO3)(1,42)15 .4 (H2SO4,1,84)(1+1),(SO3).,1.11.2 ,(1,0 =0,1 Cu):100,0 1.11.3 (1,19).(HCl).3 ,HCl -.:HCl (HCl 6N).,HCl,.11.4 (1,42).(HNO3).4 ,HNO3 -.11.5 (1+499).1 HNO3(1,42)499 .11.6 11.6.1,.11.7 11.7.1.-.-50 p.s.i.g(345).5 ,-,.12 12.1 100 ,(11.2)c HNO3
10、(1+499).542762010 512.2 0,5 HNO3(1,42)13.213.4.13.5.12.3 ()-.HNO3(1+499).12.4 ,-.13 13.1 100,0 -125.6 ,13.5.13.2 5 HCl(1,19).13.3 -,1520,.7 ,.13.4 100 -,.-.13.5 -()-324,7.HNO3(1+499).14 14.1 ,-,(12.4).15 15.1 ,.15 -270.15.2 ,-,.15.3 277777,-,.,1.4 277798,19.15.4 :II SO=0,020 X+0,035;(1)ST=0,052 X+0,
11、123;(2)5427620106,SO=0,016 X+0,033;(3)ST=0,060 X+0,039,(4)SO ,;ST ;X ,/.15.5 1.1 Cu,/Cu,/,%,95%4,04,11+2,752,02,06+3,00,40,46+15,0(,)4,04,03+0,752,02,02+1,00,40,41+2,5 -16 16.1 ,.16.2 50 500/.500/.16.3 ,50%-,NaCl(50000/).-.17 17.1 -.-,.,.()-.8.1 .(3557),(3558),(1068),(3559),(1886)(1691).18 18.1.9.54
12、2762010 719 19.1 ,10.20 20.1 (1/):0,1 -100 50%-.20.2 (CHCl3).20.3 ,(1,0 =1,0 Cu):1,000 250 15 (HNO3)(1,42)15 .4 (H2SO4)(1,84)(1+1),(SO3).,1.20.4 ,(1,0 =10 Cu):10,0 -1 (HNO3)(1,42)1.20.5 ,(1,0 =1,0 Cu):10,0 100 .-.20.6 (1,19).(HCl)(.-3).20.7 (1+2).1 HCl(1,19)2 .20.8 (1+49).1 HCl(1,19)49 .20.9 (1,42).
13、(HNO3)(.4).20.10 :36 -1 (CHCl3).30 (CS2)-,CS2.CHCl3 2.8 .:-.20.11 (100/):100 (NaOH)1.20.12 .11.6.20.13 .11.7.21 21.1 ,0,0 50,0 0,0 50,0 (20.5)100 .21.2 125,0,5 (HNO3)(1,42)22.2 22.15.250 22.5 22.15.21.3 ,.542762010822 22.1 ,50,0 (100),125 100 .9 -,50,0 (100),250 ,22.5.22.2 5 (HCl)(1,19).22.3 -,1520,
14、.10 ,-,.22.4 ,-,250.100 .22.5 2 -.22.6 NaOH(1+49)-,2,5 HCl(1+49),2,3.11 -.22.7 10 -2 (.8).22.8 ,CHCl3 100.22.9 10 (CHCl3)CHCl3 .12 CHCl3,-,CHCl3 .22.10 ,-.13 .22.11 45 2 HNO3(1,42),-.22.11.1 ,-,.22.12 .-.22.13 2 HCl(1+2),1.22.14 ,10 -.22.15 ()-324,7 12.4.23 23.1 ,-10 (21.3).,/,542762010 9 =(1000)/,(
15、5),;,.24 24.1 -,.120.24.2 ,-,50%-NaCl(50000/).24.3 277777,-.1.4 277798 -19.24.4 :II SO=0,119 X+9;(6)ST=0,247 X+47;(7),SO=27;(8)ST=0,270 X+42,(9)SO,/;ST ,/;X ,/.24.5 2.2 Cu,/Cu,/,%,95%3002903,3100112+12,0 20 65+225(,)30023422,0100 937,0 20 49+145 54276201010 -25 25.1 .25.2 5 100/.,()-(.).25.3 ,(-),.-
16、.26 26.1 -.,()().,;-.,.3919.26.2 .26.3 .-,-.,.27 27.1 ,-,3919.28 28.1-,324,7 .14 ,324,7,.,.15 .28.2 .-,.28.3 ,-,.28.4 ,.,.28.5 .1 100.28.6 ,.-542762010 11 ,(,.).28.7 .29 29.1 ,(1,0 =1,0 Cu).20.3.29.2 ,(1,0 =10 Cu).20.4.29.3 ,(1,0 =0,10 Cu):10,0 -(29.2)1 (HNO3)(1,42)1.29.4 (1,42).(HNO3)(.4).29.5,.,.30 30.1 .,3919.31 31.1 ,-,HNO3(1+1).HNO3(1+1).31.2 100,0 125.31.3 HNO3(1,42)-,31.431.6.-,0,45 ,HNO3(1,42)5/,31.6.31.4 95 -,1520,(.7).31.5 ,-,100.(.16).0,5%HNO3.16 ,-,100.31.6 ,.3919.32 32.1 3919.33 33.
