1、 D598796(2015.)STANDARD TEST METHOD FOR TOTAL FLUORINE IN COAL AND COKE BY PYROHYDROLYTIC EXTRACTION AND ION SELECTIVE ELECTRODE OR ION CHROMATOGRAPH METHODS 2018 ():17.09.2018:3541-18/ASTM -,.9,119049.:(499)236-54-49:(499)230-13-72 E-mail:interstgost.ru http:/www.interstandart.ru/(ASTM Internationa
2、l)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International ,ASTM International.-,ASTM International ,.This translation is executed by FBU“CIC“Interstandard”of Federal Agency on Technical Regulating and Metrology under the license of American Society for Testing and Materials(ASTM Intern
3、ational)100 rr Harbor Drive,West Conshohocken,PA 19428,USA.ASTM International does not approve and does not confirm these translations and in any cases only the English version published with a sign of ASTM International copyright can be considered as the original version.Reproduction of the specifi
4、ed translations by any Party,except for ASTM International or FBU“CIC“Interstandard”,is strictly forbidden according to the USA legislation and international copyright.ASTM D5987-96(2015)1 D598796(2015.)1 D5987;,.()1.1.1 .1.2 ,37%(.AS 1038.10.4 Conrad2).1.3,.1.4 ,.1 ASTM D05 D05.29 .1 2015.2015.1996
5、.2007.D5987-96(2007).DOI:10.1520/D5987-96R15.2 Conrad,V.B.,and Brownlee,W.D.,Hydropyrolytic Ion Chromatographic Determination of Fluoride in Coal and Geological Materials,(),60,4,1988.,.365-369.ASTM D5987-96(2015)2 ,.4.1.5 ,D4621,.2.2.1 ASTM:3 D346 D1193 .D2013 D2234/D2234M ()D3174 D3180 D4621 ,(201
6、0.)4 D5142 (2010.)4 2.2 :5 3 ASTM,ASTM www.astm.org ASTM serviceastm.org.ASTM.Document Summary ASTM.4 www.astm.org.5 (ANSI):25 W.43-.,4-,.-,.-10036.ASTM D5987-96(2015)3 AS 1038.10.4 ,3.3.1 :,/.,.4.4.1 .,.5.5.1 ,.,-,.5.2 ,10-30,.5.3 ,125,.ASTM D5987-96(2015)4 5.4 ,70,.5.5 ,250,(6.3.1),600 (6.3.3)(6.3
7、.5).5.6 ,0,1 2,0.250-(5.5),.5.7 -30 .5.8 ,0,1.5.9 (.1):5.9.1 :5.9.1.1 (25 20),.,7.1 .5.9.1.2 20,(5.9.1.1).5.9.1.3 ,971612,1000C 1.ASTM D5987-96(2015)5 5.9.1.4 -5 50,10-12 ,.T-50 10 (5.9.1.1)(5.9.1.2).-.5.9.1.5 1100C.5.9.1.6 .5.9.2 (.1):5.9.2.1 ,2.5.9.2.2 (5.9.1.1).5.9.2.3 ,10.5.9.2.4 .5.9.2.5 .5.9.2
8、.6 1000/.5.9.3 :5.9.3.1 ,125,24/40 .5.9.3.2 ,24/40 .300.ASTM D5987-96(2015)6 1.(5.9.le)2.(5.9.1a)3.(5.9.3a)4.(5.9.1f)5.(5.9.1f)6.(5.9.1b)7.8.(5.9,2a)9.(5.9.2b)10.-(5.9.1d)11.(5.9.2e)12.(5.9.2e)13.(5.9.2c)14.15.(5.9.1c)16.(5.9.3b)17.(5.9.3c)18.(5.9.2f).1.5.9.3.3 250,c ,.5.10 ():5.10.1 pH-0,1,ASTM D59
9、87-96(2015)7 .6 5.10.2 ,.2 .5.10.3 ().5.11 ()AS-3 3250 .7 6.6.1 .,.8 ,.6.2 .,IV D1193,.(,.6 Midgley,D.,and Torrance,K.,Potentiometric Water Analysis,(),John Wiley and Sons,1978.7 Rice,T.D.,Analytica Chimica Acta,1983.,151,.383-389.8 ,.,.,.,BDH Ltd.,.,.,Inc.(USPC),.,.ASTM D5987-96(2015)8 ,.)6.3 :6.3.
10、1 (1 =200 ):6.3.1.1 0,2210 0,0002 (110C 1)400 500-.500-.1.3 .6.3.1.2 0,2210 0,0002 (110C 1)500-,150 250 (.6.3.3).500-.1 (.3).6.3.2 (0,025-M NaOH)2,0 500 .2,0-,.6.3.3 (pH 6,5)10,0 ,2,0 115 1700 .pH 6,5 .2,0-,.6.3.4,(pH 6,5)10,0 115 350 .ASTM D5987-96(2015)9 pH 6,5 .500-,.6.3.5 20,0 ,20,0 (6.3.2)10,0
11、(6.3.4)(5.2).200 (6.3.1.1).6.4 :6.4.1 (1000/)2,2110 0.0002 (105C 1)250-,150 .1,0-.(.3).6.4.2 (1,0/)1,0 (6.4.1)1,0-;(.3).6.4.3 ,(2,5)71 (H2SO4,.1,834-1,836)1 .6.4.4 ,(0,025).10,0 2,5-H2SO4(6.4.3)1 .6.4.5 (0,0015 M),.0,2520 (105C 1)NaHCO3 2,0.ASTM D5987-96(2015)10 6.4.6 (0,02 M).1,6801 (105C 1)NaHCO3
12、1,0.6.5 99,5%.6.6 .7.7.1 D2013 D346 250 (60).75 (200 ).7.2 D3174 D5142,.,105-110C 2 .,10.8.8.1 :8.1.1 T .1 0,1 (5.9.1.1).8.1.2 (),.8.2 :8.2.1 (5.9.2.1),1600 ,ASTM D5987-96(2015)11 .(5.9.3.3).1100C,1000/15.8.2.2:8.2.2.1 (5.9.3)50 1 (6.3.2),65 1 (6.4.5).,.8.2.2.2 750/.,300C.30 400,500,750 1000C,.8.2.2
13、.3 15,.8.2.3 :8.2.3.1 .4 .8.2.3.2 5-(5.9.3.1).8.2.3.3 (5.3).ASTM D5987-96(2015)12 5 750/,100.8.2.3.4 0,75 (6.3.1.1).8.2.3.5 100 0,1 .8.2.3.6 40,0 (5.4).10,0 (6.3.4),20%().8.2.4 :8.2.4.1 (.4).8.2.4.2 50-0,0015-M NaHCO3(6.4.5)(5.9.3.1).8.2.4.3 200-0,0015-M NaHCO3(6.4.5).8.2.4.4 ,0,0015-M NaHCO3(6.4.5)
14、(.3).9.9.1 :9.1.1 50,0 1 (6.3.2)125-(5.3).ASTM D5987-96(2015)13 9.1.2 500,1000,1500 2000 (6.3.1.1).100,0 0,05 .S1,S2,S3 S4.100,200,300 400 100 .(6.3.4)40,0 ,(.8.2.3.5).9.1.3 (6.3.5)20.9.1.4 .(5.10.2)5-10 ,20 .5-10-.0,1 2-3.6 0,1 2 ,.9.1.5 ,(6.4.5)30 ,9.1.4.9.1.6 ,.,ASTM D5987-96(2015)14 S2 -.S1,S3,S
15、4,S2.S2 ,./.9.2 :9.2.1 (6.3.5).9.2.2 ,11.4.1.9.2.3 9.1.3.2-3 0,1 (E1).9.2.4 (5.5),0,5-3,0 (6.3.1.2),0,1,20 30.2-3 0,1 (E2).9.2.5 ,(6.3.5)30 ,9.1.3.0,2C.10.10.1-.ASTM D5987-96(2015)15 10.1.1 .11.11.1 ,.:=()()(1):Fad-,/;mf-,;ms-,.11.2 (50,.40 +10 ;4:1).,().:(2):mf-,;c2-(mn),;ma-,;ASTM D5987-96(2015)16
16、 mb-,;mp-,;mn-+,+50 ();c1-(6.3.1.1),/,=200/();m1-(6.3.1.1),.11.3 :(3):mf-,;c-(6.3.1.2),/;mp-,;m2-(6.3.1.2),E2,;ma-,;mb-,;E1-,;E2-(6.3.1.2),;S-.25C (.11.4),T-,K;m1-(6.3.1.2).11.4 :ASTM D5987-96(2015)17 11.4.1 50 c1 150-.11.4.2 pH 5,0-5,5 H2SO4.11.4.3 5,0 .11.4.4 ,E1.11.4.5 .11.4.1 c2.,c2=10c1 2c1.11.4.6 11.4.2 11.4.4,E2.11.4.7 S,58 20C,:(4)11.5 ,-(,).,/200 .(5):mf-,;c2-,/200 ;mp-,;mn-,-200 .ASTM D5987-96(2015)18 12.12.1 ,.12.2 ,D3174 D5142,60(250).12.3 ,D3180.,/500 5 500 10 13.13.1 .7 20 120/,:13
