1、 542912010 27 2002.184-,1.02004 .1 -(),42 31 3-272010.1132-4 ATM 530797(2007)(STM D 530797(2007)Standard testmethodfordeterminationofboilingrangedistributionofcrudepetroleumbygaschromatography).-1.52004(3.5).-,5 ,-.().-,2011 ,-II 5429120101 .12 .13 .14 .25 .26.27 .48 .59 .510 .611 .712 .913 .1114 .1
2、2 1().13 ()().14III 542912010 Crude petroleum.Gas chromatographymethod for determination of components boiling temperature range distribution 201207011 1.1 538 (1000 F).,538,.,-.1.2,.(,),.1.3 ,.,.,.7.2,7.5,7.67.9.2:2.1 ATM1):ATM2892(15-)ASTMD2892,Testmethodfordistillationofcrudepetroleum(15-theoreti
3、calplatecolumn)4057(ASTMD4057,Practiceformanualsamplingofpetroleumandpetroleumproducts)3 3.1:3.1.1(areaslice):,-.1)ATM www.astm.org ATM -serviceastm.org.,ATM,-c ,ATM.1 542912010 (6.2.2)-.3.1.2 (corrected area slice):-,().-.3.1.3(cumulativecorrectedarea):-,(,).3.1.4 ;(initial boiling point,IBP):(-),0
4、,5%-.3.1.5 (residue,RES):,538(1000F).3.1.6 T(theoreticaltotalarea,):,-,.,12.3.3.2 3.2.1 .,(,n-C10;i-C14).4 4.1 ,-.,.,-538 (1000 F).,538,.,.5 5.1-.-,.5.2,-ATM2892(I).5.3 ATM2892,-,.538,ATM2892400.6 6.1,-,10.6.1.1-().2 542912010 .,.6.1.2 ,1 -538(1000F),.6.1.3 90(194F),.-.1.1 123,(),(),-,/-,/,457(18)3,
5、17(1/8)10%UCW-982 PA)-AW 303801025400380610(24)3,17(1/8)3%OV-1 WA)-HP 303501020380375457(18)3,17(1/8)10%SE-30 PA)-AW 403601028400400A)8 5.6.1.4.6.1.4.1-,.,.6.1.4.2 -.,-,.6.1.5 ,-?1%.-,-,.,550(80psig),1.6.2 6.2.1-01 2.6.2.2 .-3 542912010 ().-,().1,12.-,.,-.6.3 ,-10.1.6.4 510.7 7.1.,-,.,.7.2(.).,-.7.3
6、(CaCl2).7.4 -,(.7.5,),538(1000F).,-.,1 3 -,.-(),.7.5(CS2)99%.-,-.,.7.6-,.7.7 .,-16-18 1%.,-,-.-.4 5429120107.8 .6-,1044.-CS2(CS2,).7.9().-.7.10 .-14-17.,/.7.11.-3%10%.7.12 .().60/8080/100.8 8.1 4057.8.2.9 9.1 ,-,10.9.2,.9.2.1,.9.2.2-.9.2.3-.9.2.4().9.2.5 46,.9.2.6.9.2.7 .9.2.8 -.9.3 ()-1216-.5%.9.4
7、.-1.9.4.1 -,.-,-,6.1.3.5 5429120109.4.2.-,-.9.4.3,.-,0,76(0,030).10 10.1 (7.7),.-16-18(.-1)R=22121()()ttYY?1,699,(1)R ;t2-18,;t1-16,;Y2-18,;Y1-16,.10.2-.6.10.3 (7.8),-.-Fn=(Cn/An)/(C10/A10),(2)Fn-;Cn-;An-;10-;A10-.1 6 54291201010.3.1Fn-10%.10.3.2 ,-(-20-44),.-.-(10.3.1),.11 11.1 (),-.11.1.1 ,-,-,10.
8、11.1.2 ,3.,().11.1.3(6.2.2),-.,.11.1.4.1 ,-.-,.2 -().-,-,.,.11.2 11.2.1,-(11.1),-(7.4).,().11.2.1.1 ,.-(.).-.11.2.2,-(),2.-2.11.2.3 -.,-,-,.(538),-.-7 542912010 ,.,.2 2 1)FF12345678910111213141516171819202122 162 89 420366998126151174196216235254271287302316330344356369 259 127 443297156209258303345
9、38542145548952054957660162665167468523242526272829303132333435363738394041424344380391402412422431440449458466474481489496503509516522528534540545716736756774792808825840856871885898912925937948961972982993100410131)Green,L.E.,Chromatograph Gives Boiling Point,HydrocarbonProcessing,May 1976,p.205.8
10、54291201011.2.4 .11.3 11.3.1,0 5.4(-).11.3.2 (1003).11.3.3 ,-.11.3.4 ,-().50 3 23 ,-,.11.3.5 10 0,1 253.11.3.6 1 .0,1.11.3.7.11.3.8 ,3 ,().(11.4.1).11.3.9 ,11.3.5,.-(11.4.4).11.4 11.4.1 ,(11.1 11.2),(11.1),1 .-().11.4.2 ,538(1000F).11.4.3 ,.-.11.4.4.,11.4.1,-1 (11.3.9).().11.4.5 (11.4.1),(11.4.4).12
11、 12.1 12.1.1 (11.4.1 11.4.4),(11.1),(2).12.1.2,-.12.2(3)12.2.1 (11.2.1),5%-14,5%-17.9 542912010 ,-.(11.4.1)(IS,3).(11.4.4)(IS,3b).12.2.2 ,-538(1000F).1 14;2 15;3 16;4 17;5 ;538 (1000 F);,;IS -;IS ,3 3 10 54291201012.2.3 W W=I/(S+I),(3)I ,;S ,.12.2.4 r ,538 (1000 F),r=(B BIS)/(A AIS),(4)B 538(1000F);
12、BIS ;538(1000F)-;AIS .12.2.5 (+,3b)=(AIS?r)BIS(I W)/W,(5)AIS ;r 538(1000F)(-)(4);BIS ;W (3).12.2.6 RES538(1000F),%.,RES=100 (B/T?100),(6)B 538C(1000F);(5).12.3 12.3.1 ,0,5%(5).,-,.12.3.2 100 (5).(%.).12.3.3 (%.).12.3.4,-,1%,538(1000F).12.3.5 1%-(11.2.2).13 13.1:13.1.1 0,5 (1 F)-1%.13.1.2 538 0,1%.11
13、 54291201014 14.1 85.14.1.1 ,3 .14.1.2 ,3 .3%,5102030405060708085903,74,76,96,87,69,310,611,817,624,818,820,72,6%.10,614,811,315,420,424,630,325,939,238,838,844,98,1%.3 ,3%30%.,.14.2 ,-.14.2.1 -,(,).,-,-,.-,.12 542912010 1()1.1 ATM 2892 .1.2-2892.2892 ,-400.1.3 1),-ATM 2892.-.1)Ceballo,C.D.,et al Rev.Tee.INTEVEP,7(1),pp.8183.13 542912010()().1 ATM 2892*ATM 4057MOD 251785 .526592006 .*.-.-:MOD .14 542912010 662.753.1:006.354 75.04029 0209:,15 542912010.31.10.2011.12.12.2011.60?8418.2,32.-.1,95.146.1230.,123995,.,4.www.gostinfo.ruinfogostinfo.ru .,105062,.,6.
